60627-09-0

Synonym:Cerium tetrafluoride hydrate

---

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound60627-09-0100%2.5mg/m3 (as F)2.5mg/m3 (as F)

---

Section 3: Hazards Identification
Irritating to eyes, skin and respiratory tract. If inhaled or swallowed, this compound may cause fluoride
Emergency Overview:
poisoning.
Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust.
Eye Contact:Causes severe irritation of the eyes and blindness.
Skin Contact:Prolonged contact with skin causes severe irritation.
Inhalation:Causes severe irritation to the respiratory tract.
Ingestion:If ingested, irritation to the gastrointestinal tract may occur.
Causes severe irritation to eyes, skin and respiratory tract. Fluoride poisoning may cause nausea, vomiting,
Acute Health Affects:
diarrhea, weakness, coma, respiratory failure and cardiovascular collapse.
Product contains fluorine which, under certain conditions of use, decomposition or metabolism, may generate
Chronic Health Affects:fluoride ion causing nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth
structure and kidney and liver damage.
NTP:No
IARC:No
OSHA:No

---

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Apply calcium gluconate jelly
Skin Exposure:
or water soluble calcium salts as antidote. Seek medical assistance.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

---

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:None. Material is non-flammable.
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit corrosive fumes of hydrofluoric acid.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

---

SECTION 6: Accidental Release Measures
Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Avoid
Spill and Leak Procedures:raising dust. Spillage in areas not adequately ventilated may require an evacuation of area. Emergency
response teams will require self-contained breathing apparatus.

---

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed non-glass container away from moisture.

---

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:The solid may form corrosive vapors. It should be handled in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:The solid may form corrosive vapors. It should be handled in an efficient fume hood.
Additional Protection:No additional protection required.

---

SECTION 9: Physical and Chemical Properties
Color and Form:white pwdr.
Molecular Weight:216.13
Melting Point:-H2O @ 100°, 650° dec.
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:pungent odor
Solubility in Water:insoluble

---

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:Contact with acids liberates very toxic gas.
Incompatibility:active metals and strong mineral acids
Decomposition Products:Water, hydrofluoric acid, metal fluorides and metal oxyfluorides

---

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

---

SECTION 12: Ecological Information
Ecological Information:No information available

---

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

---

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

---

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none

---

SECTION 16 - ADDITIONAL INFORMATION
N/A