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14977-61-8

14977-61-8 structure
14977-61-8 structure

Name chromyl dichloride
Synonyms Chromyl chloride
chromium chloride
MFCD00010951
CHROMOUS CHLORIDE
chromium dichloride
chromylchloride
EINECS 239-056-8
chromium oxychloride
Density 1.91
Boiling Point 117ºC
Melting Point -96.5ºC
Molecular Formula Cl2CrO2
Molecular Weight 154.90100
Flash Point 117ºC
Exact Mass 153.86800
PSA 34.14000
LogP 1.14140

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GB5775000
CHEMICAL NAME :
Chromium, dichlorodioxo-
CAS REGISTRY NUMBER :
14977-61-8
LAST UPDATED :
199712
DATA ITEMS CITED :
18
MOLECULAR FORMULA :
Cl2-Cr-O2
MOLECULAR WEIGHT :
154.90
WISWESSER LINE NOTATION :
CR G2 O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
REFERENCE :
CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1980- Volume(issue)/page/year: 1,583,1980 *** REVIEWS *** ACGIH TLV-TWA 0.16 mg/m3 (0.025 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Human Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 49,49,1990 IARC Cancer Review:Group 1 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 49,49,1990 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-BELGIUM:TWA 0.025 ppm (0.16 mg/m3) JAN 1993 OEL-FINLAND;Carcinogen JAN 1993 OEL-GERMANY;Carcinogen JAN 1993 OEL-THE NETHERLANDS:TWA 0.025 ppm (0.15 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 0.05 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO CHROMYL CHLORIDE-air:10H CA TWA 0.001 mg(Cr)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4593 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 35 (estimated)
Symbol GHS03 GHS05 GHS07 GHS08 GHS09
GHS03, GHS05, GHS07, GHS08, GHS09
Signal Word Danger
Hazard Statements H271-H314-H317-H340-H350i-H410
Precautionary Statements P201-P210-P273-P280-P303 + P361 + P353-P305 + P351 + P338
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes O:Oxidizing;T:Toxic;N:Dangerousfortheenvironment;
Risk Phrases R35;R43;R46;R49;R50/53;R8
Safety Phrases S45-S53-S60-S61
RIDADR UN 3244 8/PG 2
WGK Germany 3
RTECS GB5775000
Packaging Group I
Hazard Class 8
HS Code 2914700090

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Literature: Inorganic Chemistry, , vol. 29, p. 1807 - 1811

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Literature: Moissan, H. Ann. Chim. Phys., 1880 , vol. 21, p. 199 - 255 Full Text Show Details Moissan, H. Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1880 , vol. 90, p. 1357 - 1360 Full Text Show Details Gmelin Handbook: Cr: MVol.B, 108, page 222 - 225

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Literature: Journal of the American Chemical Society, , vol. 80, p. 3189 - 3191

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Literature: Chemische Berichte, , vol. 26, p. 1992

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Literature: Journal of the Chemical Society, Faraday Transactions, , vol. 86, # 3 p. 525 - 530

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Literature: Journal of the American Chemical Society, , vol. 42, p. 607

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Literature: Chemische Berichte, , vol. 26, p. 1992 Justus Liebigs Annalen der Chemie, , vol. Suppl.7, p. 103 Chemische Berichte, , vol. 2, p. 547
HS Code 2914700090
Summary HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%