Name | 4-Vinylbenzyl acetate |
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Synonyms | (4-ethenylphenyl)methyl acetate |
Density | 1.047g/cm3 |
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Boiling Point | 252.3ºC at 760mmHg |
Molecular Formula | C11H12O2 |
Molecular Weight | 176.21200 |
Flash Point | 110.7ºC |
Exact Mass | 176.08400 |
PSA | 26.30000 |
LogP | 2.39270 |
Appearance | Crystals or Crystalline Powder | White |
Vapour Pressure | 0.0194mmHg at 25°C |
Index of Refraction | 1.535-1.538 |
Storage condition | Refrigerator (+4°C) |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a tightly closed container. Store in a dry area. Keep refrigerated. (Store below 4C/39F.) Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1592-12-7: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Clear liquid Color: slightly yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: > 93 deg C (> 199.40 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C11H12O2 Molecular Weight: 176.22 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Not available. Incompatibilities with Other Materials: Not available. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1592-12-7 unlisted. LD50/LC50: Not available. Carcinogenicity: 4-Vinylbenzyl acetate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 1592-12-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 1592-12-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1592-12-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Safety Phrases | S24/25 |
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HS Code | 2915390090 |
~97% 1592-12-7 |
Literature: Zhao, Lin-Jing; Kwong, Cathy Kar-Wing; Shi, Min; Toy, Patrick H. Tetrahedron, 2005 , vol. 61, # 51 p. 12026 - 12032 Title/Abstract Full Text View citing articles Show Details Kwong, Cathy Kar-Wing; Huang, Rui; Zhang, Minjuan; Shi, Min; Toy, Patrick H. Chemistry - A European Journal, 2007 , vol. 13, # 8 p. 2369 - 2376 |
~% 1592-12-7 |
Literature: Journal of the American Chemical Society, , vol. 69, p. 1905 |
~92% 1592-12-7 |
Literature: Mitsumori, Teruyuki; Craig, Ian M.; Martini, Ignacio B.; Schwartz, Benjamin J.; Wudl, Fred Macromolecules, 2005 , vol. 38, # 11 p. 4698 - 4704 |
HS Code | 2915390090 |
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Summary | 2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0% |