115298-63-0

115298-63-0 structure
115298-63-0 structure
  • Name: (4-METHOXYPHENYL)PHENYLIODONIUM TRIFLATE
  • Chemical Name: (4-methoxyphenyl)-phenyliodanium,trifluoromethanesulfonate
  • CAS Number: 115298-63-0
  • Molecular Formula: C14H12F3IO4S
  • Molecular Weight: 460.20700
  • Create Date: 2018-06-15 16:20:35
  • Modify Date: 2024-01-01 19:38:49

Name (4-methoxyphenyl)-phenyliodanium,trifluoromethanesulfonate
Synonyms 4-methoxyphenyl.phenyliodonium trifluoromethanesulfonate
(4-Methoxyphenyl)phenyliodonium triflate
p-anisylphenyliodonium trifluoromethanesulfonate
Melting Point 109-111ºC
Molecular Formula C14H12F3IO4S
Molecular Weight 460.20700
Exact Mass 459.94500
PSA 74.81000
LogP 0.95580
Name: (4-Methoxyphenyl)phenyliodonium triflate Material Safety Data Sheet
Synonym:
CAS: 115298-63-0
Section 1 - Chemical Product MSDS Name:(4-Methoxyphenyl)phenyliodonium triflate Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
115298-63-0 (4-Methoxyphenyl)phenyliodonium trifla unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 115298-63-0: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 109 - 111 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C13H12IO.CF3O3S
Molecular Weight: 460.21

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, alkalies.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas, hydrogen iodide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 115298-63-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(4-Methoxyphenyl)phenyliodonium triflate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 115298-63-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 115298-63-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 115298-63-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
HS Code 2909309090

~85%

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Literature: Bielawski, Marcin; Olofsson, Berit; Kraemer, Katja; Lautens, Mark Organic Syntheses, 2009 , vol. 86, p. 308 - 314

~87%

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Literature: Malmgren, Joel; Santoro, Stefano; Jalalian, Nazli; Himo, Fahmi; Olofsson, Berit Chemistry - A European Journal, 2013 , vol. 19, # 31 p. 10334 - 10342

~96%

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115298-63-0

Literature: Carroll, Michael A.; Pike, Victor W.; Widdowson, David A. Tetrahedron Letters, 2000 , vol. 41, # 28 p. 5393 - 5396

~98%

115298-63-0 structure

115298-63-0

Literature: Malmgren, Joel; Santoro, Stefano; Jalalian, Nazli; Himo, Fahmi; Olofsson, Berit Chemistry - A European Journal, 2013 , vol. 19, # 31 p. 10334 - 10342

~72%

115298-63-0 structure

115298-63-0

Literature: Wang, Bijia; Cerny, Ronald L.; Uppaluri, Shriharsha; Kempinger, Jayson J.; Dimagno, Stephen G. Journal of Fluorine Chemistry, 2010 , vol. 131, # 11 p. 1113 - 1121

~%

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115298-63-0

Literature: Malmgren, Joel; Santoro, Stefano; Jalalian, Nazli; Himo, Fahmi; Olofsson, Berit Chemistry - A European Journal, 2013 , vol. 19, # 31 p. 10334 - 10342

~%

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Literature: Jalalian, Nazli; Petersen, Tue B.; Olofsson, Berit Chemistry--A European Journal, 2012 , vol. 18, # 44 p. 14140 - 14149,10

~%

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115298-63-0

Literature: Malmgren, Joel; Santoro, Stefano; Jalalian, Nazli; Himo, Fahmi; Olofsson, Berit Chemistry - A European Journal, 2013 , vol. 19, # 31 p. 10334 - 10342

~%

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Literature: Kitamura; Matsuyuki; Nagata; Furuki; Taniguchi Synthesis, 1992 , # 10 p. 945 - 946
HS Code 2909309090
Summary 2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%