116912-64-2

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SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Highly flammable.

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3 - Composition/Information on Ingredients

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Product NameCAS #EC noAnnex I
Index Number
(3-(TRI(ETHOXY/METHOXY)SILYL)PROPY 116912-64-2 NoneNone
L)UREA,50 WT. % SOLUTION IN
METHYL ALCOHOL
FormulaC9H22N2O4Si
Molecular Weight 250,4000 AMU

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4 - First Aid Measures

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AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER EYE CONTACT
Assure adequate flushing of the eyes by separating the eyelids
with fingers.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.

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5 - Fire Fighting Measures

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EXTINGUISHING MEDIA
Suitable: For small (incipient) fires, use media such as
"alcohol" foam, dry chemical, or carbon dioxide. For large
ALDRICHwww.molbase.com
fires, apply water from as far as possible. Use very large
quantities (flooding) of water applied as a mist or spray; solid
streams of water may be ineffective. Cool all affected
containers with flooding quantities of water.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
Vapor may travel considerable distance to source of ignition and
flash back. Flammable liquid.
Explosion Hazards: Vapor may travel considerable distance to
source of ignition and flash back. Container explosion may occur
under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
SPECIFIC METHOD(S) OF FIRE FIGHTING
Keep down vapors with water spray.

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6 - Accidental Release Measures

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PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with dry-lime, sand, or soda ash. Place in covered
containers using non-sparking tools and transport outdoors.
Ventilate area and wash spill site after material pickup is
complete.

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7 - Handling and Storage

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HANDLING
Directions for Safe Handling: Do not breathe vapor. Avoid
contact with eyes, skin, and clothing. Avoid prolonged or
repeated exposure. Do not use if skin is cut or scratched. Wash
thoroughly after handling.
STORAGE
Conditions of Storage: Keep tightly closed. Keep away from heat,
sparks, and open flame. Store in a cool dry place. Store under
nitrogen.
SPECIAL REQUIREMENTS: Moisture sensitive.

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8 - Exposure Controls / Personal Protection

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ENGINEERING CONTROLS
Mechanical exhaust required. Safety shower and eye bath.
GENERAL HYGIENE MEASURES
Discard contaminated clothing and shoes.
PERSONAL PROTECTIVE EQUIPMENT
Special Protective Measures: Wear appropriate government approved
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respirator, chemical-resistant gloves, safety goggles, other
protective clothing.

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9 - Physical and Chemical Properties

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pH N/A
BP/BP RangeN/A
MP/MP RangeN/A
Flash Point14,000 °CMethod: closed cup
FlammabilityN/A
Autoignition TempN/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion LimitsN/A
Vapor PressureN/A
SG/Density0,9100 g/cm3
Partition Coefficient N/A
ViscosityN/A
Vapor DensityN/A
Saturated Vapor Conc. N/A
Evaporation RateN/A
Bulk DensityN/A
Decomposition Temp.N/A
Solvent ContentN/A
Water ContentN/A
Surface TensionN/A
ConductivityN/A
Miscellaneous DataN/A
SolubilityN/A

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10 - Stability and Reactivity

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STABILITY
Stable: Stable.
Conditions to Avoid: Moisture.
Materials to Avoid: Acids, Acid chlorides, Acid anhydrides,
Oxidizing agents, Reducing agents, Alkali metals.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Nitrogen oxides, Silicon oxide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur

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11 - Toxicological Information

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SIGNS AND SYMPTOMS OF EXPOSURE
Damage to the eyes. Nausea, headache, and vomiting.
Gastrointestinal disturbances. Damage to the heart. Dizziness.
Irregular breathing. Weakness. Confusion. Drowsiness. Exposure
can cause: Warning: contains methanol. May be fatal or cause
blindness if swallowed. Cannot be made nonpoisonous.
Unconsciousness. Symptoms may be delayed. To the best of our
knowledge, the chemical, physical, and toxicological properties
have not been thoroughly investigated.
ROUTE OF EXPOSURE
Skin Contact: Causes skin irritation.
Eye Contact: Can cause blindness.
ALDRICHwww.molbase.com
Ingestion: May be fatal if swallowed.
Multiple Routes: Vapor or mist is irritating to the eyes, mucous
membranes, and upper respiratory tract. Harmful if inhaled or
absorbed through skin.
TARGET ORGAN INFORMATION
Kidneys. Nerves. Eyes. Liver. Damage to the eyes. Damage to the
heart.

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12 - Ecological Information

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No data available.

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13 - Disposal Considerations

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SUBSTANCE DISPOSAL
Burn in a chemical incinerator equipped with an afterburner and
scrubber but exert extra care in igniting as this material is
highly flammable. Observe all federal, state, and local
environmental regulations.

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14 - Transport Information

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RID/ADR
UN#: 1866
Class: 3
PG: II
Proper Shipping Name: Resin solution, flammable
IMDG
UN#: 1866
Class: 3
PG: II
Proper Shipping Name: RESIN SOLUTION
Marine Pollutant: No
Severe Marine Pollutant: No
IATA
UN#: 1866
Class: 3
PG: II
Proper Shipping Name: RESIN SOLUTION
Inhalation Packing Group I: No

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15 - Regulatory Information

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CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: F-T
Highly Flammable. Toxic.
R-PHRASES: 11
Highly flammable.
S-PHRASES: 16-23-45
Keep away from sources of ignition - no smoking. Do not breathe
vapor. In case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible).
Caution: Substance not yet fully tested (EU).

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16 - Other Information

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ALDRICHwww.molbase.com
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
ALDRICHwww.molbase.com

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SECTION 16 - ADDITIONAL INFORMATION
N/A