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22428-87-1

22428-87-1 structure
22428-87-1 structure
  • Name: 1,4-Dioxaspiro[4.5]decan-8-ol
  • Chemical Name: 1,4-dioxaspiro[4.5]decan-8-ol
  • CAS Number: 22428-87-1
  • Molecular Formula: C8H14O3
  • Molecular Weight: 158.195
  • Create Date: 2018-09-19 08:04:52
  • Modify Date: 2024-01-02 21:31:36


Name 1,4-dioxaspiro[4.5]decan-8-ol
Synonyms 1,4-dioxaspiro[4.5]-decan-8-ol
4-Hydroxycyclohexanone monoethylene ketal
MFCD00067003
1,4-Dioxaspiro[4.5]decan-8-ol
4-Hydroxycyclohexanone ethylene acetal
1-hydroxy-4-cyclohexanone ethylene ketal
4-hydroxycyclohexanone ethylene ketal
4,4-ethylenedioxycyclohexan-1-ol
8-hydroxy-1,4-dioxaspiro[4.5]decane
4,4-Ethylenedioxycyclohexanol
Density 1.2±0.1 g/cm3
Boiling Point 269.0±40.0 °C at 760 mmHg
Molecular Formula C8H14O3
Molecular Weight 158.195
Flash Point 116.5±27.3 °C
Exact Mass 158.094299
PSA 38.69000
LogP -0.01
Vapour Pressure 0.0±1.2 mmHg at 25°C
Index of Refraction 1.506
Storage condition 2-8°C
Name: 1 4-Dioxaspiro[4.5]decan-8-ol 98+% Material Safety Data Sheet
Synonym: None known
CAS: 22428-87-1
Section 1 - Chemical Product MSDS Name:1 4-Dioxaspiro[4.5]decan-8-ol 98+% Material Safety Data Sheet
Synonym:None known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
22428-87-1 1,4-Dioxaspiro[4.5]decan-8-ol 98+ unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective Equipment section. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as sawdust. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 22428-87-1: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Viscous liquid
Color: clear colorless
Odor: alcohol-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H14O3
Molecular Weight: 158.18

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 22428-87-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,4-Dioxaspiro[4.5]decan-8-ol - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 22428-87-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 22428-87-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 22428-87-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi: Irritant;
Safety Phrases S24/25
HS Code 2932999099

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Literature: CRYPTOPHARMA PTY LTD Patent: WO2008/124878 A1, 2008 ; Location in patent: Page/Page column 82-83 ;

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Literature: US4366172 S1, ;

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Literature: US5808146 A1, ;

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Literature: US5691321 A1, ;

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Literature: Hwu; Leopold Journal of the Chemical Society - Series Chemical Communications, 1984 , vol. NO. 11, p. 721 - 723

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Literature: Helvetica Chimica Acta, , vol. 40, p. 1621,1625

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Literature: Journal of the Chemical Society. Perkin Transactions 2, , # 6 p. 1221 - 1234

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Literature: Chemische Berichte, , vol. 90, p. 1973,1944


HS Code 2932999099
Summary 2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%