{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde structure
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Common Name | {[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde | ||
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CAS Number | 102191-92-4 | Molecular Weight | 174.313 | |
Density | 0.9±0.1 g/cm3 | Boiling Point | 161.0±23.0 °C at 760 mmHg | |
Molecular Formula | C8H18O2Si | Melting Point | 165-167ºC | |
MSDS | Chinese USA | Flash Point | 42.7±18.2 °C | |
Symbol |
GHS02, GHS07 |
Signal Word | Warning |
Name | (tert-butyldimethylsilyloxy)acetaldehyde |
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Synonym | More Synonyms |
Density | 0.9±0.1 g/cm3 |
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Boiling Point | 161.0±23.0 °C at 760 mmHg |
Melting Point | 165-167ºC |
Molecular Formula | C8H18O2Si |
Molecular Weight | 174.313 |
Flash Point | 42.7±18.2 °C |
Exact Mass | 174.107605 |
PSA | 26.30000 |
LogP | 2.61 |
Vapour Pressure | 2.3±0.3 mmHg at 25°C |
Index of Refraction | 1.412 |
Storage condition | below 5° C |
Symbol |
GHS02, GHS07 |
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Signal Word | Warning |
Hazard Statements | H226-H315-H319-H335 |
Precautionary Statements | P261-P305 + P351 + P338 |
Personal Protective Equipment | Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
Hazard Codes | Xi: Irritant; |
Risk Phrases | R36/37/38 |
Safety Phrases | S26-S36 |
RIDADR | UN 1989 |
WGK Germany | 3 |
HS Code | 2931900090 |
Precursor 9 | |
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DownStream 7 | |
HS Code | 2931900090 |
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Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
Enantioselective total synthesis of (-)-dactylolide.
Org. Lett. 8(6) , 1117-1120, (2006) [reaction: see text] The enantioselective total synthesis of (-)-dactylolide is reported. The absolute stereochemistry of the tetrahydropyran was established by catalytic asymmetric Jacobsen hetero-Di... |
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One-pot enantioselective syntheses of iminosugar derivatives using organocatalytic anti-michael-anti-aza-Henry reactions.
Org. Lett. 12(22) , 5250-3, (2010) Organocatalyst-controlled asymmetric anti-Michael reactions of (tert-butyldimethylsilyloxy)acetaldehyde with a range of nitroolefins, followed by an intermolecular aza-Henry reaction with imine, provi... |
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Organocatalytic asymmetric assembly reactions for the syntheses of carbohydrate derivatives by intermolecular Michael-Henry reactions.
Proc. Natl. Acad. Sci. U. S. A. 107(48) , 20672-7, (2010) Given the significance of carbohydrates in life, medicine, and industry, the development of simple and efficient de novo methods to synthesize carbohydrates are highly desirable. Organocatalytic asymm... |
MFCD01321229 |
Acetaldehyde, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]- |
2-[tert-butyl(dimethyl)silyl]oxyacetaldehyde |
{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde |
(tert-Butyldimethylsiloxy)acetaldehyde |