Methyl laurate

Modify Date: 2024-01-02 08:44:32

Methyl laurate Structure
Methyl laurate structure
 Common Name Methyl laurate
CAS Number 111-82-0 Molecular Weight 214.344
Density 0.9±0.1 g/cm3 Boiling Point 263.0±3.0 °C at 760 mmHg
Molecular Formula C13H26O2 Melting Point 4-5 °C(lit.)
MSDS Chinese USA Flash Point 114.6±6.9 °C
Symbol GHS09
GHS09		 Signal Word Warning

 Use of Methyl laurate


Methyl laurate, a 12-carbon saturated fatty acid, is an esterified version of lauric acid[1].

 Names

Name methyl laurate
Synonym More Synonyms

 Methyl laurate Biological Activity

Description Methyl laurate, a 12-carbon saturated fatty acid, is an esterified version of lauric acid[1].
Related Catalog
References

[1]. YongWang, et al. Comparison of two different processes to synthesize biodiesel by waste cooking oil. Journal of Molecular Catalysis A: Chemical. Volume 252, Issues 1–2, 1 June 2006, Pages 107-112

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 263.0±3.0 °C at 760 mmHg
Melting Point 4-5 °C(lit.)
Molecular Formula C13H26O2
Molecular Weight 214.344
Flash Point 114.6±6.9 °C
Exact Mass 214.193283
PSA 26.30000
LogP 5.49
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.433
Storage condition 2-8°C

 MSDS

Name: Methyl laurate 96% Material Safety Data Sheet
Synonym: Methyl dodecanoate; Lauric acid methyl este
CAS: 111-82-0
Section 1 - Chemical Product MSDS Name:Methyl laurate 96% Material Safety Data Sheet
Synonym:Methyl dodecanoate; Lauric acid methyl este
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
111-82-0 METHYL LAURATE 96% 203-911-3
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 111-82-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: clear, colorless
Odor: Oil,winey,fatty odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 262 deg C @ 766.00mm Hg
Freezing/Melting Point: 4.8 deg C
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: .8700g/cm3
Molecular Formula: C13H26O2
Molecular Weight: 214.35
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 111-82-0: OF0670000 LD50/LC50:
Not available.
Carcinogenicity:
METHYL LAURATE - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 111-82-0: 1
Canada
CAS# 111-82-0 is listed on Canada's DSL List.
CAS# 111-82-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-82-0 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OF0670000
CHEMICAL NAME :
Lauric acid, methyl ester
CAS REGISTRY NUMBER :
111-82-0
BEILSTEIN REFERENCE NO. :
1767780
LAST UPDATED :
199710
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C13-H26-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
48 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
RESJAS Journal of the Reticuloendothelial Society. (1964) (Res: Journal of the Reticuloendothelial Society, New York) V.1(1)-14(6), 1964-73. Volume(issue)/page/year: 3,250,1966 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M3860 No. of Facilities: 129 (estimated) No. of Industries: 4 No. of Occupations: 11 No. of Employees: 2692 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M3860 No. of Facilities: 1543 (estimated) No. of Industries: 22 No. of Occupations: 23 No. of Employees: 34131 (estimated) No. of Female Employees: 75 (estimated)

 Safety Information

Symbol GHS09
GHS09
Signal Word Warning
Hazard Statements H410
Precautionary Statements P273
Personal Protective Equipment Eyeshields;Gloves
Hazard Codes N
Risk Phrases 50
Safety Phrases S24/25
RIDADR UN 3082 9 / PGIII
WGK Germany 1
RTECS OF0670000

 Synthetic Route

 Articles17

More Articles
Direct quantification of fatty acids in wet microalgal and yeast biomass via a rapid in situ fatty acid methyl ester derivatization approach.

Appl. Microbiol. Biotechnol. 99 , 10237-47, (2015)

Accurate determination of fatty acid contents is routinely required in microalgal and yeast biofuel studies. A method of rapid in situ fatty acid methyl ester (FAME) derivatization directly from wet f...

Optimization of supercritical fluid consecutive extractions of fatty acids and polyphenols from Vitis vinifera grape wastes.

J. Food Sci. 80(1) , E101-7, (2015)

In this study, supercritical fluid extraction has been successfully applied to a sequential fractionation of fatty acids and polyphenols from wine wastes (2 different vitis vinifera grapes). To this a...

Evaluation of injection methods for fast, high peak capacity separations with low thermal mass gas chromatography.

J. Chromatogr. A. 1392 , 82-90, (2015)

Low thermal mass gas chromatography (LTM-GC) was evaluated for rapid, high peak capacity separations with three injection methods: liquid, headspace solid phase micro-extraction (HS-SPME), and direct ...

 Synonyms

EINECS 203-911-3
Lauric acid methyl ester,Methyl dodecanoate
Lauric acid methyl ester
Methyl laurate
Dodecanoic acid, methyl ester
Dodecanoic acid methyl ester
Lauric acid, methyl ester
Methyl n-dodecanoate
11VO1
MFCD00008966
Methyldodecanoate
methyl dodecanoate
Methyl dodecylate
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