21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester

Modify Date: 2024-01-09 17:11:55

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester Structure
21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester structure
Common Name 21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester
CAS Number 1263-63-4 Molecular Weight 594.74300
Density 1.171g/cm3 Boiling Point 1009.8ºC at 760mmHg
Molecular Formula C36H42N4O4 Melting Point 215ºC
MSDS N/A Flash Point 564.5ºC

 Names

Name Mesoporphyrin IX dimethyl ester,Dimethyl 8,13-bis(ethyl)-3,7,12,17-tetramethyl-21H,23H-porphine-2,18-dipropionate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.171g/cm3
Boiling Point 1009.8ºC at 760mmHg
Melting Point 215ºC
Molecular Formula C36H42N4O4
Molecular Weight 594.74300
Flash Point 564.5ºC
Exact Mass 594.32100
PSA 108.90000
LogP 4.25190
Vapour Pressure 0mmHg at 25°C
Index of Refraction 1.582

 MSDS


Section 1: Product Identification
Chemical Name:Mesoporphyrin IX, dimethyl ester, 97%
CAS Registry Number:1263-63-4
Formula:C36H42N4O4
EINECS Number:215-030-1
Chemical Family:porphine (porphyrin) ligand
Synonym:Dimethyl 7,12-diethyl-3,8,13,17-tetramethyl-21H,23H-porphine- 2,18-dipropionate

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound1263-63-4100%no datano data

Section 3: Hazards Identification
Emergency Overview:No particular hazard associated with this material.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:May cause slight to mild irritation of the eyes.
Skin Contact:May cause slight to mild irritation of the skin.
Inhalation:May be irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No specific information is available on the physiological effects of ingestion.
Acute Health Affects:May be irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If this material is involved in a fire, fire fighters should be equipped with a NIOSH approved, positive pressure
Special Fire Fighting Procedures:
self contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container. Keep away from heat and direct sunlight.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:purple xtl.
Molecular Weight:594.76
Melting Point:215°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable solid
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, nitrogen oxides, and organic fumes

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Not reportable under SARA Title 313
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Safety Phrases S24/25

 Synthetic Route

~%

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester Structure

21H,23H-Porphin...

CAS#:1263-63-4

Literature: Hoppe-Seyler's Zeitschrift fuer Physiologische Chemie, , vol. 37, p. 54,69, 71 Journal of the American Chemical Society, , vol. 68, p. 2473,2475 Journal of Biological Chemistry, , vol. 172, p. 717,723 Justus Liebigs Annalen der Chemie, , vol. 459, p. 96

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21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester Structure

21H,23H-Porphin...

CAS#:1263-63-4

Literature: Australian Journal of Chemistry, , vol. 44, # 3 p. 411 - 426

~%

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester Structure

21H,23H-Porphin...

CAS#:1263-63-4

Literature: Justus Liebigs Annalen der Chemie, , vol. 548, p. 183,190

~%

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester Structure

21H,23H-Porphin...

CAS#:1263-63-4

Literature: Chemische Berichte, , vol. 61, p. 2509,2516

~82%

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester Structure

21H,23H-Porphin...

CAS#:1263-63-4

Literature: Byrne, Christopher J.; Ward, A. David Tetrahedron Letters, 1988 , vol. 29, # 12 p. 1421 - 1424

~%

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester Structure

21H,23H-Porphin...

CAS#:1263-63-4

Literature: Justus Liebigs Annalen der Chemie, , vol. 459, p. 96

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21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester Structure

21H,23H-Porphin...

CAS#:1263-63-4

Literature: Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2864 - 2870

~%

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester Structure

21H,23H-Porphin...

CAS#:1263-63-4

Literature: Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2864 - 2870

~%

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester Structure

21H,23H-Porphin...

CAS#:1263-63-4

Literature: Acta Chemica Scandinavica (1947-1973), , vol. 4, p. 1221,1224 Justus Liebigs Annalen der Chemie, , vol. 537, p. 250,253,259 Justus Liebigs Annalen der Chemie, , vol. 541, p. 196,199

 Synonyms

2,18-Porphinedipropionic acid,7,12-diethyl-3,8,13,17-tetramethyl-,dimethyl ester
Dimethyl 8,13-diethyl-3,7,12,17-tetramethyl-21H,23H-porphine-2,18-dipropionate
mesoporphyrin-(IX)-dimethylester
EINECS 215-030-1
DIMETHYL 7,12-DIETHYL-3,8,13,17-TETRAMETHYL-21 H,23 H-PORPHINE-2,18-DIPROPIONATE
DIMETHYL 8,13-BIS(ETHYL)-3,7,12,17-TETRAMETHYL-21H,23H-PORPHINE-2,18-DIPROPIONATE
Mesoporphyrin dimethyl ester
MFCD00010036
23h-porphine-2,18-dipropanoicacid,7,12-diethyl-3,8,13,17-tetramethyl-21di
MESOPORPHYRIN IX DIMETHYL ESTER,SYNTHET IC