Prussian blue

Modify Date: 2024-01-02 12:36:52

Prussian blue Structure
Prussian blue structure
 Common Name Prussian blue
CAS Number 14038-43-8 Molecular Weight 859.228
Density 1.8 Boiling Point 25.7ºC at 760 mmHg
Molecular Formula C18Fe7N18 Melting Point N/A
MSDS Chinese USA Flash Point N/A

 Use of Prussian blue


Prussian blue insoluble (Iron(III) ferrocyanide) is a good adsorbent to be used as antidotes for poisoning with cesium or thallium ions. Prussian blue insoluble (Iron(III) ferrocyanide) has anticancerous and antibacterial properties. Prussian blue insoluble (Iron(III) ferrocyanide) can be used as a contrast agent in photoacoustic and magnetic resonance imaging (MRI). Prussian blue insoluble can be used for contrast agents, antidotes and cancer research[1][2][3][4].

 Names

Name ferric ferrocyanide
Synonym More Synonyms

 Prussian blue Biological Activity

Description Prussian blue insoluble (Iron(III) ferrocyanide) is a good adsorbent to be used as antidotes for poisoning with cesium or thallium ions. Prussian blue insoluble (Iron(III) ferrocyanide) has anticancerous and antibacterial properties. Prussian blue insoluble (Iron(III) ferrocyanide) can be used as a contrast agent in photoacoustic and magnetic resonance imaging (MRI). Prussian blue insoluble can be used for contrast agents, antidotes and cancer research[1][2][3][4].
Related Catalog
In Vitro Prussian blue insoluble (Iron(III) ferrocyanide) (0.1-3.0μg/mL; 24 hours; HUVECs) has photo-thermal effect and inhibits cell viabilities[1]. Prussian blue insoluble (Iron(III) ferrocyanide) (0.07 mM; 0-24 hours) act as a metabolic indicator, being reduced by bacterial metabolism, producing a visible color change from blue to colorless[2]. Cell Viability Assay[1] Cell Line: HUVECs Concentration: 24 hours Incubation Time: 0.1, 0.2, 0.5, 1.0, 2.0 and 3.0 μg/mL Result: Decreased the cell viabilities as the time of NIR laser irradiation
In Vivo Prussian blue insoluble (3 g/day; p.o.; for 8 days; rats)(Iron(III) ferrocyanide) can be used as a therapeutic agent in radiocesium and thallium poisoning[3]. Animal Model: Rats[3] Dosage: 3 g/day Administration: Oral administration; 8 days Result: Increased excretion of cesium-134.
References

[1]. Chen HJ, et, al. Facile synthesis of Prussian blue nanoparticles as pH-responsive drug carriers for combined photothermal-chemo treatment of cancer. RCS advances. 2016 Oct 9; 7:248-255.

[2]. Ferrer-Vilanova A, et, al. Electrochromogenic Detection of Live Bacteria Using Soluble and Insoluble Prussian Blue. ACS Omega. 2021 Nov 11;6(46):30989-30997.

[3]. Thompson DF, et, al. Soluble or insoluble prussian blue for radiocesium and thallium poisoning? Ann Pharmacother. 2004 Sep;38(9):1509-14.

[4]. Busquets MA, et, al. Prussian blue nanoparticles: synthesis, surface modification, and biomedical applications. Drug Discov Today. 2020 Aug;25(8):1431-1443.

 Chemical & Physical Properties

Density 1.8
Boiling Point 25.7ºC at 760 mmHg
Molecular Formula C18Fe7N18
Molecular Weight 859.228
Exact Mass 859.599915
PSA 428.22000
LogP 0.28454
Vapour Pressure 740mmHg at 25°C
Stability Stable. Incompatible with strong acids, strong oxidizing agents, ammonia. Light sensitive.

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LJ8200000
CAS REGISTRY NUMBER :
14038-43-8
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C18-Fe3-N18.4Fe

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>8 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 35(1),35,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2100 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Liver - other changes
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 35(1),35,1991
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intratracheal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Kidney, Ureter, Bladder - other changes
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 35(1),35,1991
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>8 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 35(1),35,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Blood - changes in spleen
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 35(1),35,1991
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>8 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 35(1),35,1991 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - T1624 No. of Facilities: 5778 (estimated) No. of Industries: 67 No. of Occupations: 58 No. of Employees: 85363 (estimated) No. of Female Employees: 20494 (estimated)

 Synthetic Route

tetrabutylammonium hexacyanoferrate(iii) structure

tetrabutylammon...

CAS#:14589-06-1

Ferric chloride structure

Ferric chloride

CAS#:7705-08-0

~%

Prussian blue Structure

Prussian blue

CAS#:14038-43-8

Literature: Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 2059 - 2062

 Precursor & DownStream

Precursor  2

DownStream  0

 Customs

HS Code 29322910

 Articles38

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 Synonyms

Iron(3+) hexakis(cyano-κC)ferrate(4-) (4:3)
Tetrairon(3+) tris[hexacyanoferrate(4-)]
PARIS BLUE
EINECS 237-875-5
BERLIN BLUE
Miroli Blue
Ferrate(4-), hexakis(cyano-κC)-, iron(3+) (3:4)
Prussian blue
MFCD00135663
Iron(III) Hexacyanoferrate(II)
CHINESE BLUE
Iron(III) Ferrocyanide
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