1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE

Modify Date: 2024-01-02 18:53:32

1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Structure
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE structure
Common Name 1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE
CAS Number 17082-61-0 Molecular Weight 230.452
Density 0.9±0.1 g/cm3 Boiling Point 215.1±0.0 °C at 760 mmHg
Molecular Formula C10H22O2Si2 Melting Point N/A
MSDS Chinese USA Flash Point 61.1±0.0 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 1,2-bis(trimethylsilyloxy)cyclobutene
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 215.1±0.0 °C at 760 mmHg
Molecular Formula C10H22O2Si2
Molecular Weight 230.452
Flash Point 61.1±0.0 °C
Exact Mass 230.115829
PSA 18.46000
LogP 4.45
Vapour Pressure 0.2±0.4 mmHg at 25°C
Index of Refraction 1.442
Storage condition 2-8°C

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi
Risk Phrases R36/37/38:Irritating to eyes, respiratory system and skin .
Safety Phrases S26-S36
RIDADR 1993
WGK Germany 3
HS Code 2931900090

 Synthetic Route

~70%

1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Structure

1,2-BIS(TRIMETH...

CAS#:17082-61-0

Literature: Majkosza, Mieczyslaw; Nieczypor, Piotr; Grela, Karol Tetrahedron, 1998 , vol. 54, # 36 p. 10827 - 10836

~58%

1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Structure

1,2-BIS(TRIMETH...

CAS#:17082-61-0

Literature: Bisel, Philippe; Breitling, Elke; Frahm, August Wilhelm European Journal of Organic Chemistry, 1998 , # 4 p. 729 - 733

~70%

1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Structure

1,2-BIS(TRIMETH...

CAS#:17082-61-0

Literature: Makosza, Mieczyslaw; Grela, Karol Synlett, 1997 , vol. 1997, # 3 p. 267 - 268

~%

1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Structure

1,2-BIS(TRIMETH...

CAS#:17082-61-0

Literature: Synthetic Communications, , vol. 38, # 6 p. 841 - 847

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles5

More Articles

J. Am. Chem. Soc. 106 , 1759, (1984)

Organic Synth. 7 , 112, (1990)

Photoaddition with 1, 2-bis (trimethylsiloxy) cyclobutene: a versatile entry to the stereocontrolled total synthesis of various sesquiterpenes and diterpenes. de Keukeleire D, et al.

J. Photochem. 28(2) , 165-74, (1985)

 Synonyms

MFCD00010798
[1-Cyclobutene-1,2-diylbis(oxy)]bis(trimethylsilane)
trimethyl-(2-trimethylsilyloxycyclobuten-1-yl)oxysilane
[Cyclobut-1-ene-1,2-diylbis(oxy)]bis(trimethylsilane)
1,2-Bis(triMethylsilyloxy)cyclobutene
1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene
Cyclobutene, 1,2-bis[(trimethylsilyl)oxy]-
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