Clothianidin

Modify Date: 2024-01-02 09:55:17

Clothianidin Structure
Clothianidin structure
 Common Name Clothianidin
CAS Number 210880-92-5 Molecular Weight 249.678
Density 1.7±0.1 g/cm3 Boiling Point 435.2±55.0 °C at 760 mmHg
Molecular Formula C6H8ClN5O2S Melting Point 178.8 °C
MSDS Chinese USA Flash Point 217.0±31.5 °C
Symbol GHS07 GHS09
GHS07, GHS09		 Signal Word Warning

 Use of Clothianidin


Clothianidin is a neonicotinoid insecticide. Clothianidin shows excellent long-term control effect in small doses against various insect pests such as Coleoptera, Thysanoptera, Lepidoptera, Diptera, Homoptera, Heteroptera, Orthoptera and Isoptera families. Clothianidin has various application methods and high safety for crops[1].

 Names

Name Clothianidin
Synonym More Synonyms

 Clothianidin Biological Activity

Description Clothianidin is a neonicotinoid insecticide. Clothianidin shows excellent long-term control effect in small doses against various insect pests such as Coleoptera, Thysanoptera, Lepidoptera, Diptera, Homoptera, Heteroptera, Orthoptera and Isoptera families. Clothianidin has various application methods and high safety for crops[1].
Related Catalog
In Vitro Clothianidin (30 nM) 在离体神经元上表现出高活性[2]。 Clothianidin (1 µg/L；36 h) 对马利筋中的帝王蝶幼虫显示出亚致死效应[3]。 Clothianidin (0.25 mg/粒 和 0.50 mg/粒) 在玉米和大豆耕作的农田中，在土壤和水中浓度低[4]。
References

[1]. Uneme H. Chemistry of clothianidin and related compounds. J Agric Food Chem. 2011 Apr 13;59(7):2932-7.  

[2]. Nauen R, et al. Thiamethoxam is a neonicotinoid precursor converted to clothianidin in insects and plants[J]. Pesticide biochemistry and physiology, 2003, 76(2): 55-69.

[3]. Pecenka JR, et al. Non-target effects of clothianidin on monarch butterflies. Naturwissenschaften. 2015 Apr;102(3-4):19.  

[4]. de Perre C, et al. Fate and effects of clothianidin in fields using conservation practices. Environ Toxicol Chem. 2015 Feb;34(2):258-65.  

 Chemical & Physical Properties

Density 1.7±0.1 g/cm3
Boiling Point 435.2±55.0 °C at 760 mmHg
Melting Point 178.8 °C
Molecular Formula C6H8ClN5O2S
Molecular Weight 249.678
Flash Point 217.0±31.5 °C
Exact Mass 249.008728
PSA 123.37000
LogP 0.40
Vapour Pressure 0.0±1.0 mmHg at 25°C
Index of Refraction 1.709
Storage condition 0-6°C
Water Solubility 327 MG/L AT 20 ºC

 Safety Information

Symbol GHS07 GHS09
GHS07, GHS09
Signal Word Warning
Hazard Statements H302-H410
Precautionary Statements P273-P301 + P312 + P330-P391-P501
Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Hazard Codes Xn,Xi
Risk Phrases R22:Harmful if swallowed. R36/37/38:Irritating to eyes, respiratory system and skin . R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
Safety Phrases S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S22:Do not breathe dust .
RIDADR UN2811
WGK Germany 3
RTECS ME9565000
Packaging Group III
Hazard Class 6.1
HS Code 2934100016

 Synthetic Route

O-methyl-N-(2-chloro-5-thiazolylmethyl)-N'-nitroisourea structure

O-methyl-N-(2-c...

CAS#:187149-02-6

~98%

Clothianidin Structure

Clothianidin

CAS#:210880-92-5
Literature: Takeda Chemical Industries, Ltd. Patent: US6008363 A1, 1999 ;
O-methyl-N-nitroisourea structure

O-methyl-N-nitr...

CAS#:57538-27-9
1-(2-Chloro-1,3-thiazol-5-yl)methanamine structure

1-(2-Chloro-1,3...

CAS#:120740-08-1

~36%

Clothianidin Structure

Clothianidin

CAS#:210880-92-5
Literature: Takeda Chemical Industries, Ltd. Patent: US6008363 A1, 1999 ;
N/A structure

N/A

CAS#:305838-80-6

~%

Clothianidin Structure

Clothianidin

CAS#:210880-92-5
Literature: Tetrahedron Letters, , vol. 41, # 37 p. 7187 - 7191

 Customs

HS Code 2934100016
Summary 2934100016 (z)-1-((2-chlorothiazol-5-yl)methyl)-2-methyl-3-nitroguanidine。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%

 Articles20

More Articles
Capillary electrophoresis-mass spectrometry as a new approach to analyze neonicotinoid insecticides.

J. Chromatogr. A. 1359 , 317-24, (2014)

This paper represents the first report of a capillary electrophoresis (CE) method compatible with mass spectrometry (MS) detection for simultaneously analyzing seven neonicotinoid insecticides (acetam...
Simultaneous determination of neonicotinoid insecticides in human serum and urine using diatomaceous earth-assisted extraction and liquid chromatography-tandem mass spectrometry.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 969 , 85-94, (2014)

A rapid and sensitive analytical method was developed for simultaneous determination of eight neonicotinoid insecticides (acetamiprid, clothianidin, dinotefuran, flonicamid, imidacloprid, nitenpyram, ...
A simultaneous extraction method for organophosphate, pyrethroid, and neonicotinoid insecticides in aqueous samples.

Arch. Environ. Contam. Toxicol. 68(4) , 745-56, (2015)

A method was developed for the extraction and analysis of 2 organophosphate, 8 pyrethroid, and 5 neonicotinoid insecticides from the same water sample. A salted liquid-liquid extraction (LLE) was opti...

 Synonyms

TI 435
1-(2-Chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroguanidine
Pancho
3-(2-chloro-5-thiazolylmethyl)-1-methyl-2-nitroguanidine
(E)-1-[(2-chloro-1,3-thiazol-5-yl)methyl]-3-methyl-2-nitroguanidine
[C(E)]-N-[(2-Chloro-5-thiazolyl)methyl]-N′-methyl-N″-nitroguanidine
Guanidine, N-[(2-chloro-5-thiazolyl)methyl]-N''-methyl-N'-nitro-
Poncho
1-(2-chlorothiazol-5-ylmethyl)-2-nitro-3-methyl-guanidine
Dantop
MFCD06200753
1-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroguanidine)
(E)-1-(2-CHLORO-5-THIAZOLYLMETHYL)-3-METHYL-2-NITROGUANIDINE
(E)-1-(2-Chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroguanidine
(E)-1-(2-chlorothiazol-5-ylmethyl)-3-methyl-2-nitroguanidine
1-[(2-Chloro-1,3-thiazol-5-yl)methyl]-2-methyl-3-nitroguanidine
Clothianidin
Apacz
T5N CSJ BG D1MYM1&UNNW &&E Form
N-(2-chloro-5-thiazolylmethyl)-3-methyl-2-nitro-guanidine
Celero
Belay
Clutch
Dantotsu
1-[(2-chloro-5-thiazolyl)methyl]-3-methyl-2-nitroguanidine
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Related Compounds: More...
Clothianidin-d3
1262776-24-8
(E)-clothianidin
205510-53-8
Chemsrc provides Clothianidin(CAS#:210880-92-5) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Articles of Clothianidin are included as well.>> amp version: Clothianidin

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