D-Phenothrin

Modify Date: 2024-01-02 19:59:22

D-Phenothrin Structure
D-Phenothrin structure
 Common Name D-Phenothrin
CAS Number 26046-85-5 Molecular Weight 350.45100
Density 1.12 g/cm3 Boiling Point 437ºC at 760 mmHg
Molecular Formula C23H26O3 Melting Point N/A
MSDS N/A Flash Point 186.6ºC

 Use of D-Phenothrin


D-Phenothrin ((-)-trans-Phenothrin), an orally active Type II synthetic pyrethroid, is widely used to kill insects, mosquitoes, and human lice. D-Phenothrin is also used in veterinary medicine to control insect pests on animals and protect agricultural crops[1].

 Names

Name (3-phenoxyphenyl)methyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate
Synonym More Synonyms

 D-Phenothrin Biological Activity

Description D-Phenothrin ((-)-trans-Phenothrin), an orally active Type II synthetic pyrethroid, is widely used to kill insects, mosquitoes, and human lice. D-Phenothrin is also used in veterinary medicine to control insect pests on animals and protect agricultural crops[1].
Related Catalog
In Vivo D-Phenothrin ((-)-trans-Phenothrin; 25-200 mg/kg; IP; 14 consecutive days) significantly, dose-dependently increases oxidative DNA damage in both organs of animals[1]. D-Phenothrin (100, 300 or 1000 mg/kg/day; p.o.; 3 days) exhibits no potential to cause adverse estrogenic or (anti-)androgenic effects[2]. Animal Model: Male Wistar albino rats (6-week-old, 150-200 g) Dosage: 25, 50, 100, 200 mg/kg Administration: IP; 14 consecutive days Result: Had a statistically significant, dose-dependent increase in oxidative DNA damage in both organs of animals.
References

[1]. Atmaca E, et al. d-Phenothrin-induced oxidative DNA damage in rat liver and kidney determined by HPLC-ECD/DAD. Environ Toxicol. 2015 May;30(5):607-13.

[2]. Yamada T, et al. Lack of estrogenic or (anti-)androgenic effects of d-phenothrin in the uterotrophic and Hershberger assays. Toxicology. 2003 Apr 22;186(3):227-39.

 Chemical & Physical Properties

Density 1.12 g/cm3
Boiling Point 437ºC at 760 mmHg
Molecular Formula C23H26O3
Molecular Weight 350.45100
Flash Point 186.6ºC
Exact Mass 350.18800
PSA 35.53000
LogP 5.76050
Vapour Pressure 0mmHg at 25°C
Index of Refraction 1.588
Storage condition 0-6°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GZ2002530
CHEMICAL NAME :
Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, (3-phenoxyphenyl) methyl ester, (1R-trans)-
CAS REGISTRY NUMBER :
26046-85-5
LAST UPDATED :
199112
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C23-H26-O3
MOLECULAR WEIGHT :
350.49

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (37),30,1980
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Amphibian - frog
DOSE/DURATION :
>20 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PCBPBS Pesticide Biochemistry and Physiology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1971- Volume(issue)/page/year: 20,217,1983

 Safety Information

Hazard Codes Xi
Risk Phrases R36/37/38:Irritating to eyes, respiratory system and skin .
Safety Phrases S24/25-S37/39-S26

 Precursor & DownStream

Precursor  2

DownStream  0

 Synonyms

biophenothrin
trans-4-Hydroxy-1-hydroxymethyl-cyclohexan
EINECS 247-431-2
1-Chlor-trans,trans-dimethylcyclopropan
1r-Chlor-2t,3t-dimethyl-cyclopropan
1-Chlor-2,3-cis-dimethylcyclopropan
trans-4-Hydroxycyclohexylcarbinol
trans-4-Hydroxymethyl-cyclohexanol
1R-trans-Phenothrin
MFCD01735786
1r-chloro-2t,3t-dimethyl-cyclopropane
D-Phenothrin
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