Ethanol,2-(trimethylsilyl)-, 1-carbamate

Modify Date: 2024-01-08 17:57:58

Ethanol,2-(trimethylsilyl)-, 1-carbamate Structure
Ethanol,2-(trimethylsilyl)-, 1-carbamate structure
 Common Name Ethanol,2-(trimethylsilyl)-, 1-carbamate
CAS Number 3124-37-6 Molecular Weight 161.27400
Density 0.946g/cm3 Boiling Point 232.8ºC at 760mmHg
Molecular Formula C6H15NO2Si Melting Point N/A
MSDS N/A Flash Point 94.6ºC

 Names

Name 2-trimethylsilylethyl carbamate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.946g/cm3
Boiling Point 232.8ºC at 760mmHg
Molecular Formula C6H15NO2Si
Molecular Weight 161.27400
Flash Point 94.6ºC
Exact Mass 161.08700
PSA 52.32000
LogP 2.12020
Index of Refraction 1.428

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KM5482000
CHEMICAL NAME :
Ethanol, 2-(trimethylsilyl)-, carbamate
CAS REGISTRY NUMBER :
3124-37-6
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C6-H15-N-O2-Si
MOLECULAR WEIGHT :
161.31

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
450 mg/kg
TOXIC EFFECTS :
Behavioral - altered sleep time (including change in righting reflex) Behavioral - changes in motor activity (specific assay) Behavioral - ataxia
REFERENCE :
JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 8,604,1965

 Synthetic Route

2-(Trimethylsilyl)ethanol structure

2-(Trimethylsil...

CAS#:2916-68-9

N,N-Carbonyldiimidazole structure

N,N-Carbonyldii...

CAS#:530-62-1

~81%

Ethanol,2-(trimethylsilyl)-, 1-carbamate Structure

Ethanol,2-(trim...

CAS#:3124-37-6

Literature: Reddy, K. Laxma; Dress, K. Ruprecht; Sharpless, K. Barry Tetrahedron Letters, 1998 , vol. 39, # 22 p. 3667 - 3670
2-(Trimethylsilyl)ethanol structure

2-(Trimethylsil...

CAS#:2916-68-9

Sodium cyanate structure

Sodium cyanate

CAS#:917-61-3

~%

Ethanol,2-(trimethylsilyl)-, 1-carbamate Structure

Ethanol,2-(trim...

CAS#:3124-37-6

Literature: Mironov,V.F. et al. J. Gen. Chem. USSR (Engl. Transl.), 1969 , vol. 39, p. 813 - 816,776 - 778
2-(Trimethylsilyl)ethanol structure

2-(Trimethylsil...

CAS#:2916-68-9

Phenyl chloroformate structure

Phenyl chloroformate

CAS#:1885-14-9

~%

Ethanol,2-(trimethylsilyl)-, 1-carbamate Structure

Ethanol,2-(trim...

CAS#:3124-37-6

Literature: Fessenden; Coon Journal of medicinal chemistry, 1965 , vol. 8, # 5 p. 604 - 608

 Synonyms

carbamic acid 2-trimethylsilylethyl ester
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