Trimethyl((4-(trifluoromethyl)phenyl)ethynyl)silane

Modify Date: 2024-01-10 19:55:05

Trimethyl((4-(trifluoromethyl)phenyl)ethynyl)silane Structure
Trimethyl((4-(trifluoromethyl)phenyl)ethynyl)silane structure
Common Name Trimethyl((4-(trifluoromethyl)phenyl)ethynyl)silane
CAS Number 40230-95-3 Molecular Weight 242.31200
Density 1.029 g/mL at 25ºC(lit.) Boiling Point 80ºC0.1 mm Hg(lit.)
Molecular Formula C12H13F3Si Melting Point N/A
MSDS Chinese USA Flash Point 135 °F
Symbol GHS02
GHS02
Signal Word Warning

 Names

Name trimethyl-[2-[4-(trifluoromethyl)phenyl]ethynyl]silane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.029 g/mL at 25ºC(lit.)
Boiling Point 80ºC0.1 mm Hg(lit.)
Molecular Formula C12H13F3Si
Molecular Weight 242.31200
Flash Point 135 °F
Exact Mass 242.07400
LogP 3.93430
Index of Refraction n20/D 1.4760(lit.)

 Safety Information

Symbol GHS02
GHS02
Signal Word Warning
Hazard Statements H226
Personal Protective Equipment Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)
Hazard Codes F+
Safety Phrases 24/25
RIDADR UN 1993 3/PG 3
WGK Germany 3
HS Code 2931900090

 Synthetic Route

~98%

Trimethyl((4-(trifluoromethyl)phenyl)ethynyl)silane Structure

Trimethyl((4-(t...

CAS#:40230-95-3

Literature: Shimada, Toyoshi; Mukaide, Kotaro; Shinohara, Akihiro; Han, Jin Wook; Hayashi, Tamio Journal of the American Chemical Society, 2002 , vol. 124, # 8 p. 1584 - 1585

~10%

Trimethyl((4-(trifluoromethyl)phenyl)ethynyl)silane Structure

Trimethyl((4-(t...

CAS#:40230-95-3

Literature: Gottardo, Christine; Aguirre, Andrea Tetrahedron Letters, 2002 , vol. 43, # 39 p. 7091 - 7094

~93%

Trimethyl((4-(trifluoromethyl)phenyl)ethynyl)silane Structure

Trimethyl((4-(t...

CAS#:40230-95-3

Literature: Andreev, Aleksey A.; Konshin, Valeri V.; Komarov, Nikolai V.; Rubin, Michael; Brouwer, Chad; Gevorgyan, Vladimir Organic Letters, 2004 , vol. 6, # 3 p. 421 - 424

~72%

Trimethyl((4-(trifluoromethyl)phenyl)ethynyl)silane Structure

Trimethyl((4-(t...

CAS#:40230-95-3

Literature: Rahaim Jr., Ronald J.; Shaw, Jared T. Journal of Organic Chemistry, 2008 , vol. 73, # 7 p. 2912 - 2915

~%

Trimethyl((4-(trifluoromethyl)phenyl)ethynyl)silane Structure

Trimethyl((4-(t...

CAS#:40230-95-3

Literature: FMC Corporation Patent: US5073564 A1, 1991 ;

~%

Trimethyl((4-(trifluoromethyl)phenyl)ethynyl)silane Structure

Trimethyl((4-(t...

CAS#:40230-95-3

Literature: Miura, Katsukiyo; Inoue, Gen; Sasagawa, Hisashi; Kinoshita, Hidenori; Ichikawa, Junji; Hosomi, Akira Organic Letters, 2009 , vol. 11, # 21 p. 5066 - 5069

~%

Trimethyl((4-(trifluoromethyl)phenyl)ethynyl)silane Structure

Trimethyl((4-(t...

CAS#:40230-95-3

Literature: Dai, Jian-Jun; Fang, Chi; Xiao, Bin; Yi, Jun; Xu, Jun; Liu, Zhao-Jing; Lu, Xi; Liu, Lei; Fu, Yao Journal of the American Chemical Society, 2013 , vol. 135, # 23 p. 8436 - 8439

~%

Trimethyl((4-(trifluoromethyl)phenyl)ethynyl)silane Structure

Trimethyl((4-(t...

CAS#:40230-95-3

Literature: Chae, Yeong Mi; Bae, Jun Sung; Moon, Jong Hun; Lee, Jin Yong; Yun, Jaesook Advanced Synthesis and Catalysis, 2014 , vol. 356, # 4 p. 843 - 849

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Synonyms

MFCD03427266
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