chloromethylsilatrane

Modify Date: 2024-01-04 18:13:07

chloromethylsilatrane Structure
chloromethylsilatrane structure
Common Name chloromethylsilatrane
CAS Number 42003-39-4 Molecular Weight 223.730
Density 1.2±0.1 g/cm3 Boiling Point 263.1±40.0 °C at 760 mmHg
Molecular Formula C7H14ClNO3Si Melting Point 221ºC
MSDS N/A Flash Point 112.9±27.3 °C

 Names

Name 5-(chloromethyl)-4,6,11-trioxa-1-aza-5-silabicyclo[3.3.3]undecane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 263.1±40.0 °C at 760 mmHg
Melting Point 221ºC
Molecular Formula C7H14ClNO3Si
Molecular Weight 223.730
Flash Point 112.9±27.3 °C
Exact Mass 223.043152
PSA 30.93000
LogP 0.23
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.502

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
YJ9030500
CHEMICAL NAME :
2,8,9-Trioxa-5-aza-1-silabicyclo(3.3.3)undecane, 1-(chloromethyl)
CAS REGISTRY NUMBER :
42003-39-4
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C7-H14-Cl-N-O3-Si
MOLECULAR WEIGHT :
223.76
WISWESSER LINE NOTATION :
T88 A B C AO DN GO-SI-OTJ H1G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
3 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GWXXBX German Offenlegungsschrift Patent Document. (U.S. Patent and Trademark Office, Foreign Patents, Washington, DC 20231) Volume(issue)/page/year: #2530255

 Safety Information

HS Code 2934999090

 Synthetic Route

~%

chloromethylsilatrane Structure

chloromethylsil...

CAS#:42003-39-4

Literature: Voronkov; Mikhail Grigorievich; Dyakov; Valery Mikhailovich Patent: US4048206 A1, 1977 ;

~82%

chloromethylsilatrane Structure

chloromethylsil...

CAS#:42003-39-4

Literature: D'yakov, V. M.; Makarov, A. F. J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 2.2 p. 359 - 363,291 - 294

~80%

chloromethylsilatrane Structure

chloromethylsil...

CAS#:42003-39-4

Literature: D'yakov, V. M.; Makarov, A. F. J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 2.2 p. 359 - 363,291 - 294

~80%

chloromethylsilatrane Structure

chloromethylsil...

CAS#:42003-39-4

Literature: D'yakov, V. M.; Makarov, A. F. J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 2.2 p. 359 - 363,291 - 294

~10%

chloromethylsilatrane Structure

chloromethylsil...

CAS#:42003-39-4

Literature: Gevorgyan, Vladimir; Borisova, Larisa; Vyater, Armand; Ryabova, Victoria; Lukevics, Edmunds Journal of Organometallic Chemistry, 1997 , vol. 548, # 2 p. 149 - 155

~66%

chloromethylsilatrane Structure

chloromethylsil...

CAS#:42003-39-4

Literature: Voronkov; Kuznetsova Russian Journal of General Chemistry, 2009 , vol. 79, # 5 p. 925 - 927

~90%

chloromethylsilatrane Structure

chloromethylsil...

CAS#:42003-39-4

Literature: Voronkov, M. G.; Kuznetsova, G. A.; Baryshok, V. P. J. Gen. Chem. USSR (Engl. Transl.), 1983 , vol. 53, # 7 p. 1682,1512 - 1513

~79%

chloromethylsilatrane Structure

chloromethylsil...

CAS#:42003-39-4

Literature: Nies, J. Dirk; Bellama, Jon M.; Ben-Zvi, Nava Journal of Organometallic Chemistry, 1985 , vol. 296, p. 315 - 320

 Customs

HS Code 2934999090
Summary 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

EINECS 255-621-1
1-(Chloromethyl)-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane
1-chloromethyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane
1-(Chloromethyl)silatrane
2,8,9-Trioxa-5-aza-1-silabicyclo(3.3.3)undecane,1-(chloromethyl)
Silimin
Chloromethylsilatrane
Mival
5-chloromethyl-silitrane
(TB-5-23)-(2,2',2''-azanetriyl-tris-ethanolato(3-)-N,O,O',O'')-chloromethyl-silicon
2,8,9-Trioxa-5-aza-1-silabicyclo[3.3.3]undecane, 1-(chloromethyl)-