Benzene,1-(3-bromopropoxy)-3-methyl-

Modify Date: 2024-01-02 18:14:59

Benzene,1-(3-bromopropoxy)-3-methyl- Structure
Benzene,1-(3-bromopropoxy)-3-methyl- structure
Common Name Benzene,1-(3-bromopropoxy)-3-methyl-
CAS Number 6291-74-3 Molecular Weight 229.11400
Density 1.302 g/cm3 Boiling Point 125-126ºC (16 mmHg) ,292.1ºC at 760 mmHg
Molecular Formula C10H13BrO Melting Point N/A
MSDS N/A Flash Point 115.5ºC

 Names

Name 1-(3-bromopropoxy)-3-methylbenzene
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.302 g/cm3
Boiling Point 125-126ºC (16 mmHg) ,292.1ºC at 760 mmHg
Molecular Formula C10H13BrO
Molecular Weight 229.11400
Flash Point 115.5ºC
Exact Mass 228.01500
PSA 9.23000
LogP 3.15880
Index of Refraction 1.541-1.543

 MSDS

Name: 1-(3-Bromopropoxy)-3-methylbenzene 95% Material Safety Data Sheet
Synonym:
CAS: 6291-74-3
Section 1 - Chemical Product MSDS Name:1-(3-Bromopropoxy)-3-methylbenzene 95% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
6291-74-3 1-(3-Bromopropoxy)-3-methylbenzene 95% unlisted
Hazard Symbols: XN
Risk Phrases: 20/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 6291-74-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: Not available.
Odor: stench
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 125 - 126 deg C @16mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >140 deg C
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H13BrO
Molecular Weight: 229.12

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 6291-74-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-(3-Bromopropoxy)-3-methylbenzene - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 6291-74-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 6291-74-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6291-74-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xn: Harmful;
Risk Phrases R36/37/38
Safety Phrases 37/39-26
HS Code 2909309090

 Synthetic Route

~50%

Benzene,1-(3-bromopropoxy)-3-methyl- Structure

Benzene,1-(3-br...

CAS#:6291-74-3

Literature: Capuano, Ben; Crosby, Ian T.; McRobb, Fiona M.; Podloucka, Anna; Taylor, David A.; Vom, Amelia; Yuriev, Elizabeth Australian Journal of Chemistry, 2010 , vol. 63, # 1 p. 116 - 124

~%

Benzene,1-(3-bromopropoxy)-3-methyl- Structure

Benzene,1-(3-br...

CAS#:6291-74-3

Literature: Synthesis, , # 11 p. 1069 - 1071

 Customs

HS Code 2909309090
Summary 2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Synonyms

3-Methylphenoxypropylbromide
1-<3-Brom-propoxy>-3-methyl-benzol
MFCD02030488
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