haloxyfop

Modify Date: 2024-01-03 17:51:50

haloxyfop Structure
haloxyfop structure
Common Name haloxyfop
CAS Number 69806-34-4 Molecular Weight 361.700
Density 1.4±0.1 g/cm3 Boiling Point 420.3±45.0 °C at 760 mmHg
Molecular Formula C15H11ClF3NO4 Melting Point N/A
MSDS Chinese USA Flash Point 208.0±28.7 °C

 Use of haloxyfop


Haloxyfop is an aryloxyphenoxypropionic acid herbicide and is widely used in grass weeds in broad-leaf crops[2]. Haloxyfop inhibits the acetyl coenzyme A carboxylase (EC 6.4.1.2) from corn seedling chloroplasts with an IC50 of 0.5 μM, but has no effect on this enzyme in pea[2].

 Names

Name haloxyfop
Synonym More Synonyms

 haloxyfop Biological Activity

Description Haloxyfop is an aryloxyphenoxypropionic acid herbicide and is widely used in grass weeds in broad-leaf crops[2]. Haloxyfop inhibits the acetyl coenzyme A carboxylase (EC 6.4.1.2) from corn seedling chloroplasts with an IC50 of 0.5 μM, but has no effect on this enzyme in pea[2].
Related Catalog
Target

IC50: 0.5 μM (acetyl coenzyme A carboxylase (EC 6.4.1.2))[2]

References

[1]. Urairat Koesukwiwat, et al. Method Development and Validation for Total Haloxyfop Analysis in Infant Formulas and Related Ingredient Matrices Using Liquid Chromatography-Tandem Mass Spectrometry. Anal Bioanal Chem

[2]. J D Burton, et al. Inhibition of Plant Acetyl-Coenzyme A Carboxylase by the Herbicides Sethoxydim and Haloxyfop. Biochem Biophys Res Commun

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 420.3±45.0 °C at 760 mmHg
Molecular Formula C15H11ClF3NO4
Molecular Weight 361.700
Flash Point 208.0±28.7 °C
Exact Mass 361.032867
PSA 68.65000
LogP 2.80
Vapour Pressure 0.0±1.0 mmHg at 25°C
Index of Refraction 1.536
Storage condition 0-6°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UA2458284
CHEMICAL NAME :
Propanoic acid, 2-(4-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)p henoxy)-
CAS REGISTRY NUMBER :
69806-34-4
LAST UPDATED :
199606
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C15-H11-Cl-F3-N-O4
MOLECULAR WEIGHT :
361.72

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
28 mg/kg/4W-C
TOXIC EFFECTS :
Liver - changes in liver weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other transferases Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other Enzymes
REFERENCE :
FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 28,71,1995
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
280 mg/kg/4W-C
TOXIC EFFECTS :
Liver - changes in liver weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - catalases Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other transferases
REFERENCE :
FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 28,71,1995
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
1820 mg/kg/13W-C
TOXIC EFFECTS :
Liver - changes in liver weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other Enzymes
REFERENCE :
FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 28,71,1995

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
RIDADR NONH for all modes of transport
RTECS UA2458284

 Synthetic Route

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haloxyfop Structure

haloxyfop

CAS#:69806-34-4

Literature: US4529438 A1, ;

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haloxyfop Structure

haloxyfop

CAS#:69806-34-4

Literature: Bioscience, Biotechnology, and Biochemistry, , vol. 56, # 2.3.4. p. 620 - 623

~%

haloxyfop Structure

haloxyfop

CAS#:69806-34-4

Literature: Bioscience, Biotechnology, and Biochemistry, , vol. 56, # 2.3.4. p. 620 - 623

~%

haloxyfop Structure

haloxyfop

CAS#:69806-34-4

Literature: Bioscience, Biotechnology, and Biochemistry, , vol. 56, # 2.3.4. p. 620 - 623

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 Synonyms

2-(4-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)propanoic acid
Propanoic acid, 2-[4-[[3-chloro-5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]-
2-[4-[[3-chloro-5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]propanoic acid
Haloxyfop (free acid)
2-(4-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]oxy}phenoxy)propanoic acid
2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid
Propanoic acid,2-4-3-chloro-5-(trifluoromethyl)-2-pyridinyloxyphenoxy
2-<4-(3-chloro-5-trifluoromethyl-2-pyridinyloxy)phenoxy>propionic acid
(RS)-Haloxyfop
rac-(2R)-2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid
2-[4-[3-chloro-5-(tr
HALOXYFOP PESTANAL
Halossifop
T6NJ BOR DOY1&VQ& CG EXFFF
Haloxyfop acid
MFCD00871401
2-(4-((3-chloro-5-(trifluoromethyl)-pyridin-2-yl)oxy)phenoxy)propionic acid
(RS)-2-{4-[3-chloro-5-(trifluoromethyl)-2-pyridyloxy]phenoxy}propionic acid
haloxyfop
2-[4-(3-chloro-5-trifluoromethyl-2-pyridyloxy)phenoxy]propionic acid
2-(4-{[3-Chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid
DOWCO453
2-(4-((3-Chloro-5-(trifluoromethyl)pyridin-2-yl)oxy)phenoxy)propanoic acid
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