(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

Modify Date: 2024-01-02 11:12:14

(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl Structure
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl structure
Common Name (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
CAS Number 76189-55-4 Molecular Weight 622.67
Density N/A Boiling Point 724.3±55.0 °C at 760 mmHg
Molecular Formula C44H32P2 Melting Point 283-286 °C(lit.)
MSDS Chinese USA Flash Point 419.0±37.8 °C

 Use of (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl


(R)-BINAP is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

 Names

Name (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
Synonym More Synonyms

  Biological Activity

Description (R)-BINAP is a biochemical reagent that can be used as a biological material or organic compound for life science related research.
Related Catalog
In Vitro (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthy 用作金属介导的不对称催化的手性配体。

 Chemical & Physical Properties

Boiling Point 724.3±55.0 °C at 760 mmHg
Melting Point 283-286 °C(lit.)
Molecular Formula C44H32P2
Molecular Weight 622.67
Flash Point 419.0±37.8 °C
Exact Mass 622.197937
PSA 27.18000
LogP 13.38
Vapour Pressure 0.0±2.3 mmHg at 25°C
Index of Refraction 235 ° (C=0.3, Toluene)
Water Solubility insoluble

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Hazard Codes Xi:Irritant
Risk Phrases R36/37/38
Safety Phrases S22-S24/25-S37/39-S26
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2902909090

 Precursor & DownStream

Precursor  0

DownStream  2

 Customs

HS Code 2902909090
Summary 2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

 Articles15

More Articles
The preparation of bi-functional organophosphine oxides as potential antitumor agents.

Eur. J. Med. Chem. 45 , 5527-30, (2010)

Following our previously reported pyridinyl phosphine oxides as antitumor agents, we targeted the commercially available C(2)-axial chiral organophosphine ligand catalysts, such as 2,2'-bis(diphenylph...

Desymmetrization of meso-dienyne by asymmetric Pauson-Khand type reaction catalysts.

Chem. Commun. (Camb.) , 1134-1135, (2004)

Desymmetrization of the meso dienynes, such as propargyl 1-vinylallyl N-tosylamides (1a-c) and propargyl 1-vinylallyl ethers (1d-e), by asymmetric Pauson-Khand type reaction catalysts was studied. The...

Catalytic enantioselective hetero-Diels-Alder reactions of an azo compound.

J. Am. Chem. Soc. 128 , 16482, (2006)

This communication describes studies in which an azo hetero-Diels-Alder adduct was furnished in high regio- and enantioselectivity using azopyridine as a reagent and silver as a catalyst. The obtained...

 Synonyms

2,2'-Bis(diphenylphosphanyl)-1,1'-binaphthalene
Phosphine, 1,1'-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenyl-
rac-2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl
1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)
(±)-BINAP
1,1'-Binaphthalen-2,2'-diylbis(diphenylphosphan)
1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine)
UNII:OX12238KWH
(r)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl
BINAP
[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine]
MFCD00010805
UNII:970O8508MB
UNII:4F1X2F8NA3
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