Sodium molybdate

Modify Date: 2024-01-03 02:10:50

Sodium molybdate Structure
Sodium molybdate structure
Common Name Sodium molybdate
CAS Number 7631-95-0 Molecular Weight 205.917
Density 3.78 g/mL at 25 °C(lit.) Boiling Point 100ºC
Molecular Formula MoNa2O4 Melting Point 687 °C(lit.)
MSDS Chinese USA Flash Point N/A

 Use of Sodium molybdate


Sodium molybdate is a useful source of molybdate. It is often found as Sodium molybdate dihydrate. In murine models, Sodium molybdate dihydrate inactivated both the active and inactive form of the gluco corticoid receptor complex. With the use of nitrites, molybdate salts have been shown to reduce the emission of hydrogen sulfide from swine manure.

 Names

Name sodium molybdate (anhydrous)
Synonym More Synonyms

 Sodium molybdate Biological Activity

Description Sodium molybdate is a useful source of molybdate. It is often found as Sodium molybdate dihydrate. In murine models, Sodium molybdate dihydrate inactivated both the active and inactive form of the gluco corticoid receptor complex. With the use of nitrites, molybdate salts have been shown to reduce the emission of hydrogen sulfide from swine manure.
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 Chemical & Physical Properties

Density 3.78 g/mL at 25 °C(lit.)
Boiling Point 100ºC
Melting Point 687 °C(lit.)
Molecular Formula MoNa2O4
Molecular Weight 205.917
Exact Mass 207.864609
PSA 80.26000
Index of Refraction 1.714
Stability Stable. Incompatible with strong oxidizing agents.

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QA5075000
CHEMICAL NAME :
Molybdic acid, disodium salt
CAS REGISTRY NUMBER :
7631-95-0
LAST UPDATED :
199806
DATA ITEMS CITED :
36
MOLECULAR FORMULA :
Mo-O4.2Na
MOLECULAR WEIGHT :
205.92
WISWESSER LINE NOTATION :
NA2 MO-O4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>2080 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
576 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
303 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
570 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Mammal - cat
DOSE/DURATION :
917 mg/kg
TOXIC EFFECTS :
Vascular - BP lowering not characterized in autonomic section Lungs, Thorax, or Respiration - respiratory depression
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
18200 mg/kg/13W-I
TOXIC EFFECTS :
Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - phosphatases Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - dehydrogenases
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - domestic
DOSE/DURATION :
484 mg/kg/21W-I
TOXIC EFFECTS :
Blood - other changes Musculoskeletal - other changes Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intratesticular
DOSE :
16474 ug/kg
SEX/DURATION :
male 1 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Paternal Effects - testes, epididymis, sperm duct

MUTATION DATA

TYPE OF TEST :
Sex chromosome loss and nondisjunction
TEST SYSTEM :
Yeast - Saccharomyces cerevisiae
DOSE/DURATION :
80 mmol/L
REFERENCE :
MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1986- Volume(issue)/page/year: 1,21,1986 *** REVIEWS *** ACGIH TLV-TWA 5 mg(Mo)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW ADTEAS Advances in Teratology. (New York, NY) V.1-5, 1966-72. Discontinued. Volume(issue)/page/year: 5,51,1972 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 5 mg(Mo)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,173,1971 OSHA PEL (Gen Indu):8H TWA 5 mg(Mo)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 5 mg(Mo)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 5 mg(Mo)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 5 mg(Mo)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Mo)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Mo)/m3 JAN 1993 OEL-DENMARK:TWA 5 mg(Mo)/m3 JAN 1993 OEL-FINLAND:TWA 5 mg(Mo)/m3 JAN 1993 OEL-FRANCE:TWA 5 mg(Mo)/m3;STEL 10 mg(Mo)/m3 JAN 1993 OEL-GERMANY:TWA 5 mg(Mo)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 5 mg(Mo)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 5 mg(Mo)/m3 JAN 1993 OEL-SWITZERLAND:TWA 5 mg(Mo)/m3 JAN 1993 OEL-TURKEY:TWA 5 mg(Mo)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Mo)/m3;STEL 10 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81120 No. of Facilities: 1540 (estimated) No. of Industries: 35 No. of Occupations: 33 No. of Employees: 10443 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81120 No. of Facilities: 2082 (estimated) No. of Industries: 55 No. of Occupations: 46 No. of Employees: 33075 (estimated) No. of Female Employees: 6787 (estimated)

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36
RIDADR NONH for all modes of transport
WGK Germany 1
RTECS QA5075000
HS Code 2841709000

 Precursor & DownStream

Precursor  0

DownStream  2

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

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 Synonyms

Molybdenum, diolatodioxo-, sodium salt (1:2)
sodium molybdate (anhydrous)
Sodium molybdenum oxide
Disodium dioxido(dioxo)molybdenum
Sodium molybdate
EINECS 231-551-7
MFCD00003486
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