4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one

Modify Date: 2024-01-10 21:36:11

4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one Structure
4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one structure
 Common Name 4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one
CAS Number 77188-70-6 Molecular Weight 246.80600
Density N/A Boiling Point N/A
Molecular Formula C11H19ClO2Si Melting Point N/A
MSDS N/A Flash Point N/A

 Names

Name 4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one
Synonym More Synonyms

 Chemical & Physical Properties

Molecular Formula C11H19ClO2Si
Molecular Weight 246.80600
Exact Mass 246.08400
PSA 26.30000
LogP 3.47230

 Synthetic Route

tert-Butyldimethylsilyl chloride structure

tert-Butyldimet...

CAS#:18162-48-6

3-chloro-4-hydroxycyclopent-2-en-1-one structure

3-chloro-4-hydr...

CAS#:77188-69-3

~90%

4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one Structure

4-[tert-butyl(d...

CAS#:77188-70-6

Literature: Lombardo, Luciano Tetrahedron Letters, 1984 , vol. 25, # 2 p. 227 - 228
Imidazole structure

Imidazole

CAS#:288-32-4

tert-Butyldimethylsilyl chloride structure

tert-Butyldimet...

CAS#:18162-48-6

3-chloro-4-hydroxycyclopent-2-en-1-one structure

3-chloro-4-hydr...

CAS#:77188-69-3

~62%

4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one Structure

4-[tert-butyl(d...

CAS#:77188-70-6

Detail
Literature: Christie, Robert M.; Gill, Melvyn; Rickards, Rodney W. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 593 - 598
3,5,5-trichloro-4-hydroxycyclopent-2-enone structure

3,5,5-trichloro...

CAS#:58528-45-3

~%

4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one Structure

4-[tert-butyl(d...

CAS#:77188-70-6

Literature: Christie, Robert M.; Gill, Melvyn; Rickards, Rodney W. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 593 - 598
N/A structure

N/A

CAS#:13373-35-8

~%

4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one Structure

4-[tert-butyl(d...

CAS#:77188-70-6

Literature: Christie, Robert M.; Gill, Melvyn; Rickards, Rodney W. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 593 - 598
3-acetoxy-5-tert-butyldimethylsilyloxy-1-chlorocyclopentene structure

3-acetoxy-5-ter...

CAS#:102355-08-8

~%

4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one Structure

4-[tert-butyl(d...

CAS#:77188-70-6

Literature: Sugiura; Hazato; Tanaka; Okamura; Bannai; Manabe; Kurozumi; Suzuki; Noyori Chemical and Pharmaceutical Bulletin, 1985 , vol. 33, # 9 p. 4120 - 4122
(R)-(-)-BENZOIN structure

(R)-(-)-BENZOIN

CAS#:61305-35-9

~%

4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one Structure

4-[tert-butyl(d...

CAS#:77188-70-6

Literature: Sugiura; Hazato; Tanaka; Okamura; Bannai; Manabe; Kurozumi; Suzuki; Noyori Chemical and Pharmaceutical Bulletin, 1985 , vol. 33, # 9 p. 4120 - 4122
(3-chloro-4-oxocyclopent-2-en-1-yl) acetate structure

(3-chloro-4-oxo...

CAS#:102355-06-6

~%

4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one Structure

4-[tert-butyl(d...

CAS#:77188-70-6

Literature: Sugiura; Hazato; Tanaka; Okamura; Bannai; Manabe; Kurozumi; Suzuki; Noyori Chemical and Pharmaceutical Bulletin, 1985 , vol. 33, # 9 p. 4120 - 4122
(R)-4-(tert-Butyldimethylsilanyloxy)-6-oxabicyclo[3.1.0]hexan-2-one structure

(R)-4-(tert-But...

CAS#:64079-55-6

~%

4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one Structure

4-[tert-butyl(d...

CAS#:77188-70-6

Literature: Sugiura; Hazato; Tanaka; Okamura; Bannai; Manabe; Kurozumi; Suzuki; Noyori Chemical and Pharmaceutical Bulletin, 1985 , vol. 33, # 9 p. 4120 - 4122

 Synonyms

3-chloro-4-tert-butyldimethylsilyloxy-2-cyclopentenone
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Chemsrc provides CAS#:77188-70-6 MSDS, density, melting point, boiling point, structure, etc. Its name is 4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one>> amp version: 4-[tert-butyl(dimethyl)silyl]oxy-3-chlorocyclopent-2-en-1-one

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