Cyclohexanol,1-[(1-hydroperoxycyclohexyl)dioxy]-

Modify Date: 2024-01-07 18:17:07

Cyclohexanol,1-[(1-hydroperoxycyclohexyl)dioxy]- Structure
Cyclohexanol,1-[(1-hydroperoxycyclohexyl)dioxy]- structure
 Common Name Cyclohexanol,1-[(1-hydroperoxycyclohexyl)dioxy]-
CAS Number 78-18-2 Molecular Weight 230.30100
Density 1.2 g/cm3 Boiling Point 374.7ºC at 760 mmHg
Molecular Formula C12H22O4 Melting Point 76-80ºC
MSDS N/A Flash Point 180.4ºC

 Names

Name Cyclohexanone peroxide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2 g/cm3
Boiling Point 374.7ºC at 760 mmHg
Melting Point 76-80ºC
Molecular Formula C12H22O4
Molecular Weight 230.30100
Flash Point 180.4ºC
Exact Mass 230.15200
PSA 74.60000
LogP 3.05660
Index of Refraction 1.518

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GV9570000
CHEMICAL NAME :
Cyclohexanol, 1-((1-hydroperoxycyclohexyl)dioxy)-
CAS REGISTRY NUMBER :
78-18-2
BEILSTEIN REFERENCE NO. :
1567208
LAST UPDATED :
199710
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C12-H22-O5
MOLECULAR WEIGHT :
246.34
WISWESSER LINE NOTATION :
L6TJ AQ AOO- AL6TJ AOQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Rinsed with water
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 8,25,1958 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Parenteral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCPBBY National Clearinghouse for Poison Control Centers, Bulletin. (U.S. Department of Health, Education, and Welfare, Washington, DC) Volume(issue)/page/year: Jan/Feb,1969 *** REVIEWS *** TOXICOLOGY REVIEW CMTVAS Cahiers de Medecine du Travail. (Association Professionnelle Belge des Medecine du Travail, rue du Bultia, 6280 Gerpinnes, Belgium) V.1- 1963- Volume(issue)/page/year: 10(3),49,1973 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-GERMANY JAN 1993

 Safety Information

RIDADR UN 2117/2118/2119/2896
Packaging Group II
Hazard Class 5.2

 Synthetic Route

Cyclohexanone structure

Cyclohexanone

CAS#:108-94-1

~82%

Cyclohexanol,1-[(1-hydroperoxycyclohexyl)dioxy]- Structure

Cyclohexanol,1-...

CAS#:78-18-2

Literature: McCullough, Kevin J.; Morgan, Alistair R.; Nonhebel, Derek C.; Pauson, Peter L.; White, Graham J. Journal of Chemical Research, Miniprint, 1980 , # 2 p. 601 - 628
Cyclohexanone structure

Cyclohexanone

CAS#:108-94-1

~%

Cyclohexanol,1-[(1-hydroperoxycyclohexyl)dioxy]- Structure

Cyclohexanol,1-...

CAS#:78-18-2

1,1'-dioxybiscyclohexan-1-ol structure

1,1'-dioxybiscy...

CAS#:2407-94-5

Hydroperoxide,1,1'-(dioxydicyclohexylidene)bis- structure

Hydroperoxide,1...

CAS#:2699-12-9

Literature: Vikhorev, A. A.; Syroezhko, A. M.; Proskuryakov, V. A.; Korotkova, N. P. Russian Journal of Physical Chemistry, 1980 , vol. 54, # 2 p. 251 - 253 Zhurnal Fizicheskoi Khimii, 1980 , vol. 54, # 2 p. 443 - 447
cyclohexyl hydroperoxide structure

cyclohexyl hydr...

CAS#:766-07-4

~%

Cyclohexanol,1-[(1-hydroperoxycyclohexyl)dioxy]- Structure

Cyclohexanol,1-...

CAS#:78-18-2

1,1'-dioxybiscyclohexan-1-ol structure

1,1'-dioxybiscy...

CAS#:2407-94-5

Hydroperoxide,1,1'-(dioxydicyclohexylidene)bis- structure

Hydroperoxide,1...

CAS#:2699-12-9

Detail
Literature: Vikhorev, A. A.; Syroezhko, A. M.; Proskuryakov, V. A.; Korotkova, N. P. Russian Journal of Physical Chemistry, 1980 , vol. 54, # 2 p. 251 - 253 Zhurnal Fizicheskoi Khimii, 1980 , vol. 54, # 2 p. 443 - 447
Hydrochloric acid structure

Hydrochloric acid

CAS#:7647-01-0

Water structure

Water

CAS#:7732-18-5

Hydrogen peroxide structure

Hydrogen peroxide

CAS#:7722-84-1

Cyclohexanone structure

Cyclohexanone

CAS#:108-94-1

~%

Detail
Literature: Stoll; Scherrer Helvetica Chimica Acta, 1930 , vol. 13, p. 142,149 Show Details Brown et al. Journal of the American Chemical Society, 1955 , vol. 77, p. 1760 View citing articles Show Details Kharasch; Sosnovsky Journal of Organic Chemistry, 1958 , vol. 23, p. 1322,1324 Show Details Cooper; Davison Journal of the Chemical Society, 1952 , p. 1180 Show Details Criegee; Schnorrenberg; Becke Justus Liebigs Annalen der Chemie, 1949 , vol. 565, p. 7,17
Cyclohexanol structure

Cyclohexanol

CAS#:108-93-0

~%

Cyclohexanol,1-[(1-hydroperoxycyclohexyl)dioxy]- Structure

Cyclohexanol,1-...

CAS#:78-18-2

Literature: Brown et al. Journal of the American Chemical Society, 1955 , vol. 77, p. 1760
Hydrochloric acid structure

Hydrochloric acid

CAS#:7647-01-0

Diethyl ether structure

Diethyl ether

CAS#:60-29-7

Water structure

Water

CAS#:7732-18-5

Hydrogen peroxide structure

Hydrogen peroxide

CAS#:7722-84-1

Cyclohexanone structure

Cyclohexanone

CAS#:108-94-1

Detail
Literature: Milas; Harris; Panagiotakos Journal of the American Chemical Society, 1939 , vol. 61, p. 2430

 Synonyms

Cyclohexone Peroxide
Peroxycyclohexanone
1-[(hydroperoxycyclohexyl)dioxy]cyclohex-anol
MFCD00003856
1-hydroxy-1'-hydroperoxydicyclohexyl peroxide
perhexap
Cyclonox BT 50
Luperox CH-S
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide
1-Hydroperoxycyclohexyl
CADOX HDP
1-(1-Hydroperoxy-cyclohexylperoxy)-cyclohexanol
1-hydroxy-1'-hydroperoxycyclohexyl peroxide
CyclohexanonePerxide
1-hydroperoxycyclohexyl 1-hydroxycyclohexyl peroxide
cyclohexanone diperoxide
Dicyclohexanone peroxide
EINECS 235-527-7
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Chemsrc provides CAS#:78-18-2 MSDS, density, melting point, boiling point, structure, etc. Its name is Cyclohexanol,1-[(1-hydroperoxycyclohexyl)dioxy]->> amp version: Cyclohexanol,1-[(1-hydroperoxycyclohexyl)dioxy]-

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