4-(t-butyldimethylsiloxy)butyne

Modify Date: 2024-01-24 14:18:58

4-(t-butyldimethylsiloxy)butyne Structure
4-(t-butyldimethylsiloxy)butyne structure
Common Name 4-(t-butyldimethylsiloxy)butyne
CAS Number 78592-82-2 Molecular Weight 184.35100
Density 0.893 g/mL at 25ºC(lit.) Boiling Point 70-74ºC10 mm Hg(lit.)
Molecular Formula C10H20OSi Melting Point N/A
MSDS N/A Flash Point 137 °F

 Names

Name tert-butyl-but-3-ynoxy-dimethylsilane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.893 g/mL at 25ºC(lit.)
Boiling Point 70-74ºC10 mm Hg(lit.)
Molecular Formula C10H20OSi
Molecular Weight 184.35100
Flash Point 137 °F
Exact Mass 184.12800
PSA 9.23000
LogP 3.03150
Index of Refraction n20/D 1.43(lit.)

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases 36/37/38
Safety Phrases 26-36
RIDADR UN 1993 3/PG 2
WGK Germany 3
HS Code 2931900090

 Synthetic Route

~98%

4-(t-butyldimethylsiloxy)butyne Structure

4-(t-butyldimet...

CAS#:78592-82-2

Literature: Yi, Jun; Lu, Xi; Sun, Yan-Yan; Xiao, Bin; Liu, Lei Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12409 - 12413 Angew. Chem., 2013 , vol. 125, # 47 p. 12635 - 12639,5

~95%

4-(t-butyldimethylsiloxy)butyne Structure

4-(t-butyldimet...

CAS#:78592-82-2

Literature: Jones, Graham B.; Wright, Justin M.; Hynd, George; Wyatt, Justin K.; Warner, Philip M.; Huber, Robert S.; Li, Aiwen; Kilgore, Michael W.; Sticca, Robert P.; Pollenz, Richard S. Journal of Organic Chemistry, 2002 , vol. 67, # 16 p. 5727 - 5732

~0%

4-(t-butyldimethylsiloxy)butyne Structure

4-(t-butyldimet...

CAS#:78592-82-2

Detail
Literature: Bristol-Myers Squibb Company Patent: US5382592 A1, 1995 ; US 5382592 A

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Synonyms

1-(tert-butyldimethylsilyloxy)but-3-yne
1-(t-butyl dimethylsiloxy)-3-butyne
4-(t-Butyldimethylsilyloxy)-1-butyne
1-(t-butyldimethylsilyloxy)-3-butyne
4-(T-butyldimethylsiloxy)butyne
4-(tert-Butyldimethylsilyloxy)-1-butyne
(but-3-ynyloxy)(tert-butyl)dimethylsilane
MFCD03427046
TBDMS ether of homopropargylic alcohol
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