(S)-2-Aminohexan-1-ol

Modify Date: 2024-01-14 19:12:53

(S)-2-Aminohexan-1-ol Structure
(S)-2-Aminohexan-1-ol structure
Common Name (S)-2-Aminohexan-1-ol
CAS Number 80696-29-3 Molecular Weight 117.189
Density 0.9±0.1 g/cm3 Boiling Point 191.9±0.0 °C at 760 mmHg
Molecular Formula C6H15NO Melting Point 35-40ºC(lit.)
MSDS Chinese USA Flash Point 100.0±0.0 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name l-norleucinol
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 191.9±0.0 °C at 760 mmHg
Melting Point 35-40ºC(lit.)
Molecular Formula C6H15NO
Molecular Weight 117.189
Flash Point 100.0±0.0 °C
Exact Mass 117.115364
PSA 46.25000
LogP 0.63
Vapour Pressure 0.1±0.8 mmHg at 25°C
Index of Refraction 1.453
Storage condition 2-8°C

 MSDS

Name: L-Norleucinol Material Safety Data Sheet
Synonym: (S)-(+)-2-Amino-1-hexano
CAS: 80696-29-3
Section 1 - Chemical Product MSDS Name:L-Norleucinol Material Safety Data Sheet
Synonym:(S)-(+)-2-Amino-1-hexano

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
80696-29-3 L-Norleucinol unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 80696-29-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 216 deg C @760mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 99 deg C ( 210.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H15NO
Molecular Weight: 117.19

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 80696-29-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
L-Norleucinol - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 80696-29-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 80696-29-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 80696-29-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi: Irritant;
Risk Phrases 36/37/38
Safety Phrases 26-36
RIDADR NONH for all modes of transport
HS Code 2922199090

 Synthetic Route

~77%

(S)-2-Aminohexan-1-ol Structure

(S)-2-Aminohexa...

CAS#:80696-29-3

Literature: Segat-Dioury, Fabienne; Lingibe, Olivier; Graffe, Bernadette; Sacquet, Marie-Claude; Lhommet, Gerard Tetrahedron, 2000 , vol. 56, # 2 p. 233 - 248

~%

(S)-2-Aminohexan-1-ol Structure

(S)-2-Aminohexa...

CAS#:80696-29-3

Literature: Segat-Dioury, Fabienne; Lingibe, Olivier; Graffe, Bernadette; Sacquet, Marie-Claude; Lhommet, Gerard Tetrahedron, 2000 , vol. 56, # 2 p. 233 - 248

~%

(S)-2-Aminohexan-1-ol Structure

(S)-2-Aminohexa...

CAS#:80696-29-3

Literature: Segat-Dioury, Fabienne; Lingibe, Olivier; Graffe, Bernadette; Sacquet, Marie-Claude; Lhommet, Gerard Tetrahedron, 2000 , vol. 56, # 2 p. 233 - 248

~%

(S)-2-Aminohexan-1-ol Structure

(S)-2-Aminohexa...

CAS#:80696-29-3

Literature: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM; ARMSTRONG, Daniel, W.; PING, Sun; BREITBACH, Zachary, S.; WANG, Chunlei Patent: WO2010/148191 A2, 2010 ; Location in patent: Page/Page column 45-49; 59 ;

~%

(S)-2-Aminohexan-1-ol Structure

(S)-2-Aminohexa...

CAS#:80696-29-3

Literature: Rinaldi, Peter L.; Wilk, Melody Journal of Organic Chemistry, 1983 , vol. 48, # 13 p. 2141 - 2146

~%

(S)-2-Aminohexan-1-ol Structure

(S)-2-Aminohexa...

CAS#:80696-29-3

Literature: Segat-Dioury, Fabienne; Lingibe, Olivier; Graffe, Bernadette; Sacquet, Marie-Claude; Lhommet, Gerard Tetrahedron, 2000 , vol. 56, # 2 p. 233 - 248

~%

(S)-2-Aminohexan-1-ol Structure

(S)-2-Aminohexa...

CAS#:80696-29-3

Literature: Takahata, Hiroki; Takehara, Hiroyuki; Ohkubo, Naoki; Momose, Takefumi Tetrahedron: Asymmetry, 1990 , vol. 1, # 8 p. 561 - 566

~%

(S)-2-Aminohexan-1-ol Structure

(S)-2-Aminohexa...

CAS#:80696-29-3

Literature: Braconnier, M.F.; Braekman, J.C.; Daloze, D. Bulletin des Societes Chimiques Belges, 1985 , vol. 94, # 8 p. 605 - 614

 Customs

HS Code 2922199090
Summary 2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

MFCD02683226
1-Hexanol, 2-amino-, (2S)-
(2S)-2-aminohexan-1-ol
(2S)-2-Amino-1-hexanol
(S)-(+)-2-Amino-1-hexanol