1-[4-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]Methyl]phenyl]-2,2,2-trifluoro-ethanone

Modify Date: 2024-01-04 09:57:07

1-[4-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]Methyl]phenyl]-2,2,2-trifluoro-ethanone Structure
1-[4-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]Methyl]phenyl]-2,2,2-trifluoro-ethanone structure
Common Name 1-[4-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]Methyl]phenyl]-2,2,2-trifluoro-ethanone
CAS Number 87736-75-2 Molecular Weight 318.40700
Density N/A Boiling Point 145 °C/0.8 mmHg
Molecular Formula C15H21F3O2Si Melting Point N/A
MSDS N/A Flash Point 148 °C

 Names

Name 1-[4-[[tert-butyl(dimethyl)silyl]oxymethyl]phenyl]-2,2,2-trifluoroethanone

 Chemical & Physical Properties

Boiling Point 145 °C/0.8 mmHg
Molecular Formula C15H21F3O2Si
Molecular Weight 318.40700
Flash Point 148 °C
Exact Mass 318.12600
PSA 26.30000
LogP 4.95340
Index of Refraction 1.47

 Synthetic Route

~90%

1-[4-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]Methyl]phenyl]-2,2,2-trifluoro-ethanone Structure

1-[4-[[[(1,1-Di...

CAS#:87736-75-2

Literature: Fishwick, Colin W. G.; Sanderson, John M.; Findlay, John B. C. Tetrahedron Letters, 1994 , vol. 35, # 26 p. 4611 - 4614

~89%

1-[4-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]Methyl]phenyl]-2,2,2-trifluoro-ethanone Structure

1-[4-[[[(1,1-Di...

CAS#:87736-75-2

Literature: Wiegand, Michaela; Lindhorst, Thisbe K. European Journal of Organic Chemistry, 2006 , # 21 p. 4841 - 4851

~10%

1-[4-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]Methyl]phenyl]-2,2,2-trifluoro-ethanone Structure

1-[4-[[[(1,1-Di...

CAS#:87736-75-2

Literature: Nakamoto, Kosuke; Ueno, Yoshihito Journal of Organic Chemistry, 2014 , vol. 79, # 6 p. 2463 - 2472

~%

1-[4-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]Methyl]phenyl]-2,2,2-trifluoro-ethanone Structure

1-[4-[[[(1,1-Di...

CAS#:87736-75-2

Literature: Wiegand, Michaela; Lindhorst, Thisbe K. European Journal of Organic Chemistry, 2006 , # 21 p. 4841 - 4851

~%

1-[4-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]Methyl]phenyl]-2,2,2-trifluoro-ethanone Structure

1-[4-[[[(1,1-Di...

CAS#:87736-75-2

Literature: Wiegand, Michaela; Lindhorst, Thisbe K. European Journal of Organic Chemistry, 2006 , # 21 p. 4841 - 4851

~%

1-[4-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]Methyl]phenyl]-2,2,2-trifluoro-ethanone Structure

1-[4-[[[(1,1-Di...

CAS#:87736-75-2

Literature: Richardson, Stewart K.; Ife, Robert J. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 1172 - 1174

~%

1-[4-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]Methyl]phenyl]-2,2,2-trifluoro-ethanone Structure

1-[4-[[[(1,1-Di...

CAS#:87736-75-2

Literature: Nakamoto, Kosuke; Ueno, Yoshihito Journal of Organic Chemistry, 2014 , vol. 79, # 6 p. 2463 - 2472