N-naphthalen-1-yl-1-phenylmethanimine

Modify Date: 2024-01-17 01:34:52

N-naphthalen-1-yl-1-phenylmethanimine Structure
N-naphthalen-1-yl-1-phenylmethanimine structure
Common Name N-naphthalen-1-yl-1-phenylmethanimine
CAS Number 890-51-7 Molecular Weight 231.29200
Density 1.02g/cm3 Boiling Point 400.5ºC at 760 mmHg
Molecular Formula C17H13N Melting Point N/A
MSDS N/A Flash Point 188.5ºC

 Names

Name N-naphthalen-1-yl-1-phenylmethanimine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.02g/cm3
Boiling Point 400.5ºC at 760 mmHg
Molecular Formula C17H13N
Molecular Weight 231.29200
Flash Point 188.5ºC
Exact Mass 231.10500
PSA 12.36000
LogP 4.59040
Index of Refraction 1.592

 MSDS

Name: N-BENZYLIDENE-1-NAPTHYLAMINE 97% Material Safety Data Sheet
Synonym:
CAS: 890-51-7
Section 1 - Chemical Product MSDS Name:N-BENZYLIDENE-1-NAPTHYLAMINE 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
890-51-7 N-BENZYLIDENE-1-NAPTHYLAMINE 97% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 890-51-7: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: light brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 73 - 75 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 231.30

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 890-51-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N-BENZYLIDENE-1-NAPTHYLAMINE - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 890-51-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 890-51-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 890-51-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Safety Phrases S24/25
HS Code 2925290090

 Synthetic Route

~86%

N-naphthalen-1-yl-1-phenylmethanimine Structure

N-naphthalen-1-...

CAS#:890-51-7

Literature: Nishinaga, Akira; Yamazaki, Shigekazu; Matsuura, Teruo Tetrahedron Letters, 1988 , vol. 29, # 33 p. 4115 - 4118

~83%

N-naphthalen-1-yl-1-phenylmethanimine Structure

N-naphthalen-1-...

CAS#:890-51-7

Literature: Xu, Jian; Zhuang, Rongqiang; Bao, Lingling; Tang, Guo; Zhao, Yufen Green Chemistry, 2012 , vol. 14, # 9 p. 2384 - 2387

~80%

N-naphthalen-1-yl-1-phenylmethanimine Structure

N-naphthalen-1-...

CAS#:890-51-7

Literature: Simion, Alina; Simion, Cristian; Kanda, Tadeshige; Nagashima, Satoko; Mitoma, Yoshiharu; Yamada, Tomoko; Mimura, Keisuke; Tashiro, Masashi Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 17 p. 2071 - 2078

~69%

N-naphthalen-1-yl-1-phenylmethanimine Structure

N-naphthalen-1-...

CAS#:890-51-7

Literature: Jin, Xukang; Liu, Yuxiao; Lu, Qiongqiong; Yang, Dejun; Sun, Jiangkai; Qin, Shuangshuang; Zhang, Jingwu; Shen, Jiaxuan; Chu, Changhu; Liu, Renhua Organic and Biomolecular Chemistry, 2013 , vol. 11, # 23 p. 3776 - 3780

~77%

N-naphthalen-1-yl-1-phenylmethanimine Structure

N-naphthalen-1-...

CAS#:890-51-7

Literature: Cui, Xinjiang; Zhang, Chengming; Shi, Feng; Deng, Youquan Chemical Communications, 2012 , vol. 48, # 75 p. 9391 - 9393

~99%

N-naphthalen-1-yl-1-phenylmethanimine Structure

N-naphthalen-1-...

CAS#:890-51-7

Literature: Cui, Xinjiang; Shi, Feng; Deng, Youquan Chemical Communications, 2012 , vol. 48, # 61 p. 7586 - 7588

~%

N-naphthalen-1-yl-1-phenylmethanimine Structure

N-naphthalen-1-...

CAS#:890-51-7

Literature: Bucherer; Schwalbe Chemische Berichte, 1906 , vol. 39, p. 2801

~%

N-naphthalen-1-yl-1-phenylmethanimine Structure

N-naphthalen-1-...

CAS#:890-51-7

Literature: Lachowicz Monatshefte fuer Chemie, 1888 , vol. 9, p. 698

~%

N-naphthalen-1-yl-1-phenylmethanimine Structure

N-naphthalen-1-...

CAS#:890-51-7

Literature: Bucherer; Schwalbe Chemische Berichte, 1906 , vol. 39, p. 2801

 Customs

HS Code 2925290090
Summary 2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Synonyms

N-benzylidene-1-naphthylamine
N-benzylidenenaphthylamine
benzylidene-1-naphthylamine