1-Bromo-3-(chloromethyl)benzene

Modify Date: 2024-01-08 13:19:25

1-Bromo-3-(chloromethyl)benzene Structure
1-Bromo-3-(chloromethyl)benzene structure
Common Name 1-Bromo-3-(chloromethyl)benzene
CAS Number 932-77-4 Molecular Weight 205.480
Density 1.5±0.1 g/cm3 Boiling Point 245.5±15.0 °C at 760 mmHg
Molecular Formula C7H6BrCl Melting Point 32.5ºC
MSDS Chinese USA Flash Point 111.7±10.5 °C
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name 3-Bromobenzyl chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.5±0.1 g/cm3
Boiling Point 245.5±15.0 °C at 760 mmHg
Melting Point 32.5ºC
Molecular Formula C7H6BrCl
Molecular Weight 205.480
Flash Point 111.7±10.5 °C
Exact Mass 203.934128
LogP 3.26
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.570

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive;
Risk Phrases R34
Safety Phrases S26-S27-S28-S36/37/39-S45
RIDADR UN 3265 8/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 8
HS Code 2903999090

 Synthetic Route

~80%

1-Bromo-3-(chloromethyl)benzene Structure

1-Bromo-3-(chlo...

CAS#:932-77-4

Literature: Kim, Hyung Woo; Lee, Yun-Sang; Shetty, Dinesh; Lee, Hak Jeong; Lee, Dong Soo; Chung, June-Key; Lee, Myung Chul; Chung, Kyoo-Hyun; Jeong, Jae Min Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 11 p. 3434 - 3436

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1-Bromo-3-(chloromethyl)benzene Structure

1-Bromo-3-(chlo...

CAS#:932-77-4

Literature: Monatshefte fuer Chemie, , vol. 64, p. 153,157 Journal fuer Praktische Chemie (Leipzig), , vol. <2> 133, p. 331,346

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1-Bromo-3-(chloromethyl)benzene Structure

1-Bromo-3-(chlo...

CAS#:932-77-4

Literature: Synthesis, , # 24 art. no. P08208SS, p. 3937 - 3940

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1-Bromo-3-(chloromethyl)benzene Structure

1-Bromo-3-(chlo...

CAS#:932-77-4

Literature: Monatshefte fuer Chemie, , vol. 64, p. 153,157

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Detail
Literature: Journal of the American Chemical Society, , vol. 73, p. 2940

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1-Bromo-3-(chloromethyl)benzene Structure

1-Bromo-3-(chlo...

CAS#:932-77-4

Literature: Journal of the American Chemical Society, , vol. 70, p. 2310,2313

 Customs

HS Code 2903999090
Summary 2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Articles3

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Use of the [(18)F]-fluoromethyl phenyl group is an attractive alternative to direct fluorination of phenyl groups because the fluorination of the methyl group takes place under milder reaction conditi...

Bromo Derivatives of Benzylphenols. I. Some Monobromo, Dibromo and Tribromo Derivatives of Ortho and Para Benzylphenols. Huston RC, et al.

J. Am. Chem. Soc. 55(5) , 2146-2149, (1933)

Facile Chlorination of Benzyl Alcohols Using 1, 8-Diazabicyclo [5.4. 0] undec-7-ene (DBU) and Sulfonyl Chlorides. Kim HW, et al.

ChemInform 42(14) , (2011)

 Synonyms

1-Bromo-3-(chloromethyl)benzene
1-bromo-3-chloromethylbenzene
m-Bromobenzylchloride
3-Bromobenzylchloride
Benzene, 1-bromo-3-(chloromethyl)-
MFCD00040865
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