salicylaldehyde, oxime

Modify Date: 2024-01-02 06:52:23

salicylaldehyde, oxime structure	Common Name	salicylaldehyde, oxime
	CAS Number	94-67-7	Molecular Weight	137.136
	Density	1.2±0.1 g/cm3	Boiling Point	256.5±23.0 °C at 760 mmHg
	Molecular Formula	C₇H₇NO₂	Melting Point	59-61 °C(lit.)
	MSDS	Chinese USA	Flash Point	146.9±11.9 °C
	Symbol	GHS07	Signal Word	Warning

Use of salicylaldehyde, oxime

Salicylaldoxime is an organic compound, that has been used as a reagent for the gravimetric determination and separation of Cooper, Nickel, Palladium, Lead, Bismuth and Zine. The copper complex of Salicylaldoxime has anticancer activity[1][2].

Name	Salicylaldoxime
Synonym	More Synonyms

Description	Salicylaldoxime is an organic compound, that has been used as a reagent for the gravimetric determination and separation of Cooper, Nickel, Palladium, Lead, Bismuth and Zine. The copper complex of Salicylaldoxime has anticancer activity[1][2].
Related Catalog	Research Areas >> Cancer Signaling Pathways >> Others >> Others
In Vitro	Salicylaldoxime (300 μM) completely inhibits the relaxation activity of topoisomerase II when it forms a complex with copper; also inhibits L1210 leukaemia cell proliferation[1].
References	[1]. W Ligett and L Biefeld. Separation and Determination of Lead with Salicylaldoxime. Ind. Eng. Chem. Anal. Ed. 1941, 13, 11, 813-815. [2]. D. Jayaraju and Anand K. Kondapi. Anti-cancer copper salicylaldoxime complex inhibits topoisomerase II catalytic activity. Current Science. Vol. 81, No. 7 (10 October 2001), pp. 787-792

Density	1.2±0.1 g/cm3
Boiling Point	256.5±23.0 °C at 760 mmHg
Melting Point	59-61 °C(lit.)
Molecular Formula	C₇H₇NO₂
Molecular Weight	137.136
Flash Point	146.9±11.9 °C
Exact Mass	137.047684
PSA	52.82000
LogP	1.88
Vapour Pressure	0.0±0.5 mmHg at 25°C
Index of Refraction	1.552
Storage condition	2-8°C

salicylaldehyde, oxime MSDS(Chinese)

CHEMICAL IDENTIFICATION

RTECS NUMBER :: VN5775000

CHEMICAL NAME :: Salicylaldehyde, oxime

CAS REGISTRY NUMBER :: 94-67-7

BEILSTEIN REFERENCE NO. :: 1859881

LAST UPDATED :: 199712

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C7-H7-N-O2

MOLECULAR WEIGHT :: 137.15

WISWESSER LINE NOTATION :: QNU1R BQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 400 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,36,1953

Symbol	GHS07
Signal Word	Warning
Hazard Statements	H302-H315-H319-H335
Precautionary Statements	P261-P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes	Xi:Irritant;
Risk Phrases	R36/37/38
Safety Phrases	S26-S36
RIDADR	NONH for all modes of transport
WGK Germany	3
RTECS	VN5775000

Precursor 8
CAS#:90-02-8 Salicylaldehyde CAS#:89-95-2 2-Methylbenzyl ... CAS#:90-01-7 salicyl alcohol CAS#:108-95-2 Phenol
CAS#:30866-43-4 N'-(2-hydroxybe... CAS#:50-00-0 Formaldehyde CAS#:59417-52-6 2-(acetoxyimino... CAS#:80277-94-7 hexanoylsalicyl...
DownStream 10
CAS#:10419-35-9 2-ETHOXYCHROMAN CAS#:3516-95-8 2'-Hydroxy-3-ph... CAS#:4481-51-0 2-(((2-hydroxyb... CAS#:51449-77-5 2-(1H-TETRAZOL-...
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CAS#:611-20-1 2-Cyanophenol CAS#:271-95-4 1,2-BENZISOXAZOLE

Selective and potent agonists for estrogen receptor beta derived from molecular refinements of salicylaldoximes.

Eur. J. Med. Chem. 46 , 2453-62, (2011)

In a continuing effort to improve the subtype selectivity and agonist potency of estrogen receptor β (ERβ) ligands, we have designed and developed a thus far unexplored structural series obtained by m...

Structural evolutions of salicylaldoximes as selective agonists for estrogen receptor beta.

J. Med. Chem. 52 , 858-67, (2009)

The bioisosteric replacement of the phenol ring, a signature functional group of most estrogen receptor (ER) ligands, with a hydrogen-bonded pseudocyclic ring, led to the development of a novel class ...

Linking [M(III)3] triangles with "double-headed" phenolic oximes.

Dalton Trans. 41(29) , 8777-85, (2012)

Strapping two salicylaldoxime units together with aliphatic α,Ω-aminomethyl links in the 3-position gives ligands which allow the assembly of the polynuclear complexes [Fe(7)O(2)(OH)(6)(H(2)L1)(3)(py)...

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China
Product Name: salicylaldehyde, oxime
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China
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China
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China
Product Name: Salicylaldoxime
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