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1,2,6-己三醇

1,2,6-己三醇用途

【用途一】
用作聚酰胺脂增塑剂、烟草湿润剂、特种水力流体的溶剂和偶合剂。也是生产醇酸树脂。赛璐珞、聚氨酯和合成橡胶的原料。

1,2,6-己三醇名称

[ CAS 号 ]:
106-69-4

[ 中文名 ]:
1,2,6-己三醇

[ 英文名 ]:
UNII:W45XXM0XWE

[中文别名 ]:

[英文别名 ]:

Hexan-1,2,6-triol
1,2,6-Hexanetriol
MFCD00002976
1,2,6-Trihydroxyhexane
EINECS 203-424-6
UNII:W45XXM0XWE
Hexane-1,2,6-triol
1,5,6-Hexanetriol
TRIHYDROXYHEXANE(1,2,6-)
1,2,6Htriol

1,2,6-己三醇物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
323.1±0.0 °C at 760 mmHg

[ 熔点 ]:
25-32 °C

[ 分子式 ]:
C₆H₁₄O₃

[ 分子量 ]:
134.174

[ 闪点 ]:
165.5±16.9 °C

[ 精确质量 ]:
134.094299

[ PSA ]:
60.69000

[ LogP ]:
-1.75

[ 外观性状 ]:
透明淡黄色粘性液体

[ 蒸汽密度 ]:
4.63 (vs air)

[ 蒸汽压 ]:
0.0±1.5 mmHg at 25°C

[ 折射率 ]:
1.483

[ 储存条件 ]:
库房通风低温干燥

[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidizing agents, acid anhydrides, acid chlorides.

[ 水溶解性 ]:
MISCIBLE

1,2,6-己三醇MSDS

详细MSDS(安全技术说明书)

1,2,6-己三醇毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MO4650000

CHEMICAL NAME :: 1,2,6-Hexanetriol

CAS REGISTRY NUMBER :: 106-69-4

BEILSTEIN REFERENCE NO. :: 1304479

LAST UPDATED :: 199806

DATA ITEMS CITED :: 12

MOLECULAR FORMULA :: C6-H14-O3

MOLECULAR WEIGHT :: 134.20

WISWESSER LINE NOTATION :: Q4YQ1Q

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Open irritation test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 7/13/1971 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 15500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,731,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 10 gm/kg

TOXIC EFFECTS :: Gastrointestinal - changes in structure or function of endocrine pancreas Liver - other changes

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 15,282,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 10900 mg/kg

TOXIC EFFECTS :: Behavioral - altered sleep time (including change in righting reflex) Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory stimulation

REFERENCE :: SKIZAB Shikoku Igaku Zasshi. Shikoku Medical Journal. (Tokushima Igakkai, Tokushima Daigaku Igakubu, Kuramoto-cho, Tokushima 770, Japan) V.1- 1950- Volume(issue)/page/year: 28,276,1972

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5600 mg/kg

TOXIC EFFECTS :: Gastrointestinal - changes in structure or function of endocrine pancreas Liver - other changes

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 15,282,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 11400 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583) Volume(issue)/page/year: -,5,1961

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 5800 mg/kg

TOXIC EFFECTS :: Behavioral - altered sleep time (including change in righting reflex) Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory stimulation

REFERENCE :: SKIZAB Shikoku Igaku Zasshi. Shikoku Medical Journal. (Tokushima Igakkai, Tokushima Daigaku Igakubu, Kuramoto-cho, Tokushima 770, Japan) V.1- 1950- Volume(issue)/page/year: 28,276,1972

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >20 mL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 7/13/1971 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83569 No. of Facilities: 1530 (estimated) No. of Industries: 9 No. of Occupations: 10 No. of Employees: 9278 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83569 No. of Facilities: 207 (estimated) No. of Industries: 6 No. of Occupations: 6 No. of Employees: 8973 (estimated) No. of Female Employees: 7703 (estimated)

1,2,6-己三醇安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
Xi

[ 安全声明 (欧洲) ]:
S24/25

[ 危险品运输编码 ]:
NA 1993 / PGIII

[ WGK德国 ]:
1

[ RTECS号 ]:
MO4650000

[ 海关编码 ]:
2905499000

1,2,6-己三醇合成路线

详细合成路线

1,2,6-己三醇上下游产品

1,2,6-己三醇上游产品

1,2,6-己三醇下游产品

1,2,6-己三醇制备

由丙烯醛二聚物水解、加氢制得。

精制方法：由于脱水缩合或分解而使杂质混入，可在减压下蒸馏精制。

1,2,6-己三醇海关

[ 海关编码 ]: 2905499000

[ 中文概述 ]:
2905499000 其他多元醇。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ Summary ]:
2905499000 other polyhydric alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%