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醛试剂

醛试剂用途

5,5-二甲基环己烷-1,3-二酮是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

醛试剂名称

[ CAS 号 ]:
126-81-8

[ 中文名 ]:
5,5-二甲基-1,3-环己二酮

[ 英文名 ]:
Dimedone

[中文别名 ]:

[英文别名 ]:

Dimedone
1,1-Dimethyl-3,5-diketocyclohexane
cyclohexane-1,3-dione, 5,5-dimethyl-
1,1-Dimethyl-3,5-cyclohexanedione
Methone
Dimedone,Methone
Dimethyldihydroresorcinol
5,5-Dimethylcyclohexane-1,3-dione
MFCD00001588
1,3-Cyclohexanedione, 5,5-dimethyl-

醛试剂生物活性

[ 描述 ]:

5,5-二甲基环己烷-1,3-二酮是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[体外研究]

抗癌、抗氧化、抗组胺和抗凝血剂。

醛试剂物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
233.7±23.0 °C at 760 mmHg

[ 熔点 ]:
146-148 °C(lit.)

[ 分子式 ]:
C₈H₁₂O₂

[ 分子量 ]:
140.18

[ 闪点 ]:
85.1±19.6 °C

[ 精确质量 ]:
140.083725

[ PSA ]:
34.14000

[ LogP ]:
0.15

[ 外观性状 ]:
黄色晶体

[ 蒸汽压 ]:
0.1±0.5 mmHg at 25°C

[ 折射率 ]:
1.453

[ 储存条件 ]:
2-8°C

[ 稳定性 ]:
Stable, but may be light sensitive. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
0.416 g/100 mL (25 ºC)

醛试剂MSDS

醛试剂毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GV0345000

CHEMICAL NAME :: 1,3-Cyclohexanedione, 5,5-dimethyl-

CAS REGISTRY NUMBER :: 126-81-8

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C8-H12-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,28,1953

醛试剂安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
GV0345000

[ 海关编码 ]:
29142900

醛试剂合成路线

醛试剂上下游产品

醛试剂上游产品

醛试剂下游产品

醛试剂制备

在室温下先将丙二酸二乙酯缓慢加到醇钠的乙醇溶液中且搅拌均匀，在水冷却下缓慢加入亚异丙丙酮，然后加热到50℃，维持2h，减压蒸出大部分乙醇，冷却，过滤，滤出的固体用15%的氢氧化钾溶解，恒温60℃，充分搅拌反应得5,5-二甲基-1,3-环己二酮，所得粗产品在30℃下用4mol/L的稀盐酸调节pH＝4.5，滤干后可在乙醇中重结晶精制。

醛试剂海关

[ 海关编码 ]: 2914299000

[ 中文概述 ]:
2914299000. 其他不含其他含氧基的环烷酮、环烯酮或环萜烯酮. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

醛试剂文献

[The role of aldehydes in development of oxidative stress under rhabdomyolysis in rats].

Fiziol. Zh. 59(1) , 25-31, (2013)

We investigated the changes in the forms of plasma iron and participation of aldehydes in the development of oxidative stress under glycerol-induced rhabdomyolysis in rats. Rhabdomyolysis was caused b...

Thiol-blocking electrophiles interfere with labeling and detection of protein sulfenic acids.

FEBS J. 280(23) , 6150-61, (2013)

Cellular exposure to reactive oxygen species induces rapid oxidation of DNA, proteins, lipids and other biomolecules. At the proteome level, cysteine thiol oxidation is a prominent post-translational ...

Open season for hunting and trapping post-translational cysteine modifications in proteins and enzymes.

ChemBioChem. 12(6) , 841-4, (2011)

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醛试剂