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乙酰丙酮铝

乙酰丙酮铝用途

用作有机合成中间体

乙酰丙酮铝名称

[ CAS 号 ]:
13963-57-0

[ 中文名 ]:
三乙酰丙酮铝

[ 英文名 ]:
Aluminum acetylacetonate

[中文别名 ]:

[英文别名 ]:

ACETYLACETONE ALUMINIUM
Alumium acety acetonate
3-Penten-2-one, 4-hydroxy-, aluminum salt (3:1)
tris-pentane-2,4-dionato aluminium
Aluminum acetoacetonate
aluminium tris(acetylacetonate)
aluminum acetyl acetonate
Aluminum(III) acetylacetonate
Aluminium tris(4-oxo-2-penten-2-olate)
Acetylacetone Aluminum(III) Salt

乙酰丙酮铝物理化学性质

[ 密度 ]:
1,27 g/cm3

[ 沸点 ]:
315 °C(lit.)

[ 熔点 ]:
190-193 °C(lit.)

[ 分子式 ]:
C₁₅H₂₁AlO₆

[ 分子量 ]:
324.305

[ 闪点 ]:
314-316°C

[ 精确质量 ]:
324.115356

[ PSA ]:
78.90000

[ LogP ]:
2.88030

[ 外观性状 ]:
白色至淡琥珀色

[ 储存条件 ]:
室温

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
2.5 G/L (20 ºC)

乙酰丙酮铝MSDS

乙酰丙酮铝毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BD2230000

CHEMICAL NAME :: Aluminum, tris(2,4-pentanedionato)-

CAS REGISTRY NUMBER :: 13963-57-0

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C15-H21-Al-O6

MOLECULAR WEIGHT :: 324.34

WISWESSER LINE NOTATION :: D6O-AL-O BDJ D1 F1 B-& BD6O-AL-O BDJ D1 F1 B-& BD6O-AL-O BDJ D1 F1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 178 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02376 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 3600 ug/kg/9D-I

TOXIC EFFECTS :: Cardiac - cardiomyopathy including infarction Cardiac - other changes Related to Chronic Data - death

REFERENCE :: TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 39,185,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X6003 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 28 (estimated)

乙酰丙酮铝安全信息

[ 符号 ]:

GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H300-H315-H317-H319-H335

[ 警示性声明 ]:
P261-P264-P280-P301 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R25;R36

[ 安全声明 (欧洲) ]:
26-36/37/39-45-28A

[ 危险品运输编码 ]:
UN 3467 6.1/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
BD2230000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2914190090

乙酰丙酮铝合成路线

乙酰丙酮铝上下游产品

乙酰丙酮铝上游产品

乙酰丙酮铝下游产品

乙酰丙酮铝制备

1.将6g（0.06mol）新蒸馏的乙酰丙酮溶于40mL水中，搅拌下滴加6mol/L氨水至乙酰丙酮溶解。将6g（0.0093mol）硫酸铝［Al2（SO4）3·17H2O］溶于60mL水，将此溶液加入到乙酰丙酮氨溶液中，生成沉淀。反应中控制溶液的pH值为中性。过滤，水洗、自然干燥。用少量苯溶解粗产物，过滤，在滤液中慢慢滴加石油醚使其生成沉淀。过滤，用石油醚洗涤，自然干燥，得4.2g产物，收率81%。必要时可用升华法提纯。

2.由市售的无水AlCl3和乙酰丙酮在氯仿溶液中反应制得的乙酰丙酮铝含有难于去除的铁。常用的方法是用氢氧化铝，由含铁量极少的分析纯氢氧化铝制涂的乙酰丙酮铝在石油醚中进行多次重结晶后得到纯的乙酰丙酮铝。

乙酰丙酮铝海关

[ 海关编码 ]: 2914190090

[ 中文概述 ]:
2914190090 其他不含其他含氧基的无环酮。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
2914190090 other acyclic ketones without other oxygen function。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

乙酰丙酮铝文献

Does aluminum lactate cause spinal cord infarction in rabbits?

Environ. Health Perspect. 96 , 245, (1991)

Low-temperature synthesis of gamma-alumina nanocrystals from aluminum acetylacetonate in nonaqueous media.

Small 3(5) , 763-7, (2007)

Procedures for labeling the high-resolution axis of two-dimensional MQ-MAS NMR spectra of half-integer quadrupole spins.

Solid State Nucl. Magn. Reson. 21(1-2) , 21-43, (2002)

The increasing development and application of the multiple-quantum MAS NMR for half-integer quadrupole spins has led to various RF pulse sequences for improving the excitation of multiple-quantum cohe...

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