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亚磷酸三(2-氯乙基)酯

亚磷酸三(2-氯乙基)酯用途

二甲基乙烯酮的前驱体

亚磷酸三(2-氯乙基)酯名称

[ CAS 号 ]:
140-08-9

[ 中文名 ]:
三(2-氯乙基)亚磷酸酯

[ 英文名 ]:
tris(2-chloroethyl) phosphite

[中文别名 ]:

[英文别名 ]:

MFCD00000968
EINECS 205-397-6
TRIS(2-CHLOROETHYL) PHOSPHITE
Phosphorous Acid Tris(2-chloroethyl) Ester

亚磷酸三(2-氯乙基)酯物理化学性质

[ 密度 ]:
1.328 g/mL at 25 °C(lit.)

[ 沸点 ]:
112-115 °C2 mm Hg(lit.)

[ 分子式 ]:
C₆H₁₂Cl₃O₃P

[ 分子量 ]:
269.49000

[ 闪点 ]:
375 °F

[ 精确质量 ]:
267.95900

[ PSA ]:
41.28000

[ LogP ]:
2.97950

[ 外观性状 ]:
液体;Colorless to Almost colorless clear liquid

[ 蒸汽压 ]:
0.00359mmHg at 25°C

[ 折射率 ]:
n20/D 1.487(lit.)

[ 储存条件 ]:
-20°C

亚磷酸三(2-氯乙基)酯MSDS

详细MSDS(安全技术说明书)

亚磷酸三(2-氯乙基)酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: KK2810000

CAS REGISTRY NUMBER :: 140-08-9

BEILSTEIN REFERENCE NO. :: 1704979

LAST UPDATED :: 199710

DATA ITEMS CITED :: 11

MOLECULAR FORMULA :: C6-H12-Cl3-O3-P

MOLECULAR WEIGHT :: 269.50

WISWESSER LINE NOTATION :: G2OPO2GO2G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 250 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 810 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 21 gm/kg/2D-I

TOXIC EFFECTS :: Blood - hemorrhage Skin and Appendages - dermatitis, other (after systemic exposure) Related to Chronic Data - death

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 333 ug/plate

REFERENCE :: ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 5(Suppl 1),3,1983

亚磷酸三(2-氯乙基)酯安全信息

[ 符号 ]:

GHS06, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H311-H315-H319-H330-H335-H340-H350

[ 警示性声明 ]:
P201-P260-P280-P284-P301 + P310-P305 + P351 + P338

[ 危害码 (欧洲) ]:
T: Toxic;

[ 风险声明 (欧洲) ]:
R45

[ 安全声明 (欧洲) ]:
S53-S26-S36/37/39-S45-S36/37

[ 危险品运输编码 ]:
UN 2810 6.1/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
KK2810000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
2920901900

亚磷酸三(2-氯乙基)酯合成路线

详细合成路线

亚磷酸三(2-氯乙基)酯上下游产品

亚磷酸三(2-氯乙基)酯上游产品

亚磷酸三(2-氯乙基)酯下游产品

亚磷酸三(2-氯乙基)酯海关

[ 海关编码 ]: 2920901900

[ 中文概述 ]:
2920901900 亚磷酸酯。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2920901900 VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%