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4-溴-2-甲基苯甲醚

4-溴-2-甲基苯甲醚名称

[ CAS 号 ]:
14804-31-0

[ 中文名 ]:
2-甲基-4-溴苯甲醚

[ 英文名 ]:
4-Bromo-1-methoxy-2-methylbenzene

[中文别名 ]:

[英文别名 ]:

4-Bromo-2-methylanisole
5-BroMo-2-Methoxytoluene
MFCD01321139
4-Bromo-1-methoxy-2-methylbenzene
4-Bromo-2-methylphenyl methyl ether
Benzene, 4-bromo-1-methoxy-2-methyl-

4-溴-2-甲基苯甲醚物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
226.1±20.0 °C at 760 mmHg

[ 熔点 ]:
66-69 °C(lit.)

[ 分子式 ]:
C₈H₉BrO

[ 分子量 ]:
201.061

[ 闪点 ]:
102.3±7.8 °C

[ 精确质量 ]:
199.983673

[ PSA ]:
9.23000

[ LogP ]:
3.63

[ 外观性状 ]:
无色至淡黄色液体

[ 蒸汽压 ]:
0.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.535

[ 储存条件 ]:
室温

4-溴-2-甲基苯甲醚MSDS

4-溴-2-甲基苯甲醚安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 安全声明 (欧洲) ]:
S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2909309090

4-溴-2-甲基苯甲醚合成路线

4-溴-2-甲基苯甲醚上下游产品

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4-溴-2-甲基苯甲醚海关

[ 海关编码 ]: 2909309090

[ 中文概述 ]:
2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物（包括亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

4-溴-2-甲基苯甲醚文献

A useful Pd-catalyzed Negishi coupling approach to benzylic sulfonamide derivatives.

Org. Lett. 10(12) , 2517-20, (2008)

A mild catalytic system to access diversely functionalized benzylic sulfonamides has been developed. Palladium-catalyzed alpha-arylation by Negishi cross-coupling of sulfonamide-stabilized anions and ...

Synthesis of aromatic bisabolene natural products via palladium-catalyzed cross-couplings of organozinc reagents.

J. Org. Chem. 69(7) , 2461-8, (2004)

Aromatic bisabolene derivatives were prepared by two methods involving cross-coupling of organozinc reagents. The first synthesis of (+/-)-glandulone A (10), as well as syntheses of (+/-)-curcuhydroqu...

Total synthesis of (±)-heliannuol D, an allelochemical from Helianthus annuus. Vyvyan JR and Looper RE.

Tetrahedron Lett. 41(8) , 1151-1154, (2000)

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