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三氟硝草醚

三氟硝草醚用途

该品为触杀型芽前或芽后降草剂。适用于大豆，花生，水稻田除草，持效8-12星期。

三氟硝草醚名称

[ CAS 号 ]:
15457-05-3

[ 中文名 ]:
三氟硝草醚

[ 英文名 ]:
Benzene,2-nitro-1-(4-nitrophenoxy)-4-(trifluoromethyl)-

[中文别名 ]:

消草醚

[英文别名 ]:

MFCD00055532
EINECS 239-474-0
Flurodifen

三氟硝草醚物理化学性质

[ 密度 ]:
1.51g/cm3

[ 沸点 ]:
371.1ºC at 760 mmHg

[ 熔点 ]:
94℃

[ 分子式 ]:
C₁₃H₇F₃N₂O₅

[ 分子量 ]:
328.20000

[ 闪点 ]:
178.2ºC

[ 精确质量 ]:
328.03100

[ PSA ]:
100.87000

[ LogP ]:
5.36050

[ 蒸汽压 ]:
2.26E-05mmHg at 25°C

[ 折射率 ]:
1.565

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

三氟硝草醚MSDS

三氟硝草醚毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: KO2750000

CHEMICAL NAME :: Ether, (p-nitrophenyl) (alpha,alpha,alpha-trifluoro-2-nitro-p-tolyl)

CAS REGISTRY NUMBER :: 15457-05-3

LAST UPDATED :: 199701

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C13-H7-F3-N2-O5

MOLECULAR WEIGHT :: 328.22

WISWESSER LINE NOTATION :: WNR DOR BNW BXFFF

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: CIGET* Ciba-Geigy Toxicology Data/Indexes. (Ciba-Geigy Corp., 556 Morris Ave., Summit, NJ 07901) Volume(issue)/page/year: -,-,1977 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 9 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 8,414,1987

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >990 mg/m3/6H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 8,414,1987

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >3 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 8,414,1987

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >15 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CIGET* Ciba-Geigy Toxicology Data/Indexes. (Ciba-Geigy Corp., 556 Morris Ave., Summit, NJ 07901) Volume(issue)/page/year: -,-,1972

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CIGET* Ciba-Geigy Toxicology Data/Indexes. (Ciba-Geigy Corp., 556 Morris Ave., Summit, NJ 07901) Volume(issue)/page/year: -,-,1972

三氟硝草醚安全信息

[ 符号 ]:

GHS07, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H319-H332-H400

[ 警示性声明 ]:
P273-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
Xi,N

[ 风险声明 (欧洲) ]:
R36;R50/53

[ 安全声明 (欧洲) ]:
S26;S60;S61

[ 危险品运输编码 ]:
UN3077 9/PG 3

[ RTECS号 ]:
KO2750000

[ 海关编码 ]:
2909309014

三氟硝草醚合成路线

三氟硝草醚上下游产品

三氟硝草醚上游产品

三氟硝草醚下游产品

三氟硝草醚制备

以对氯甲苯为起始原料经氯化、氟化得对氯三氟甲苯，再经硝化、与对硝基苯酚缩合而制得氟甲消草醚。

三氟硝草醚海关

[ 海关编码 ]: 2909309014

[ 中文概述 ]:
2909309014 三氟硝草醚、草枯醚。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:5.5%。普通关税:30.0%

[ Summary ]:
2909309014 2-nitro-1-(4-nitrophenoxy)-4-(trifluoromethyl)benzene。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:5.5%。general tariff:30.0%

三氟硝草醚文献

Induction of glutathione S-transferase in biofilms and germinating spores of Mucor hiemalis strain EH5 from cold sulfidic spring waters.

Appl. Environ. Microbiol. 73(8) , 2697-707, (2007)

The occurrence and activation of glutathione S-transferase (GST) and the GST activities in biofilms in cold sulfidic spring waters were compared to the occurrence and activation of GST and the GST act...

Triosephosphate isomerases in Italian ryegrass ( Lolium multiflorum ): characterization and susceptibility to herbicides.

J. Agric. Food Chem. 57(17) , 7924-30, (2009)

The effect of treatments with four herbicides and a safener on the activity of triosephosphate isomerase (TPI) extracted from shoots of Italian ryegrass was investigated. It was found that atrazine an...

Forced evolution of a herbicide detoxifying glutathione transferase.

J. Biol. Chem. 278(26) , 23930-5, (2003)

Plant Tau class glutathione transferases (GSTUs) detoxify diphenylether herbicides such as fluorodifen, determining their selectivity in crops and weeds. Using reconstructive PCR, a series of mutant G...

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