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α-氧化蒎烯

α-氧化蒎烯用途

α-Pinene oxide 是从 Picea abies (L.) Karst 中分离得到的天然产物。

α-氧化蒎烯名称

[ CAS 号 ]:
1686-14-2

[ 中文名 ]:
α-环氧蒎烷

[ 英文名 ]:
3-Oxatricyclo[4.1.1.02,4]octane,2,7,7-trimethyl-

[中文别名 ]:

[英文别名 ]:

EINECS 216-869-6
α-Pinene oxide
Alpha-Pinene Oxide
2,3-Epoxypinane
Pinane, 2,3-epoxy-, (-)-
MFCD00066955

α-氧化蒎烯生物活性

[ 描述 ]:

α-Pinene oxide 是从 Picea abies (L.) Karst 中分离得到的天然产物。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[参考文献]

[1]. Heemann V, et al. Gaschromatographisch-massenspektrometrische Untersuchungen der Flüchtigen Rindeninhaltsstoffe von Picea abies (L.) Karst [Volatile constituents from the bark of picea abies (L.) karst (author's transl)]. Planta Med. 1977 Dec;32(4):342-6. German.

α-氧化蒎烯物理化学性质

[ 密度 ]:
1.027g/cm3

[ 沸点 ]:
102 - 103ºC at 30 mm Hg

[ 分子式 ]:
C₁₀H₁₆O

[ 分子量 ]:
152.23300

[ 闪点 ]:
65.6ºC

[ 精确质量 ]:
152.12000

[ PSA ]:
12.53000

[ LogP ]:
2.20990

[ 外观性状 ]:
透明液体

[ 折射率 ]:
n20/D 1.469(lit.)

[ 储存条件 ]:
室温

α-氧化蒎烯MSDS

α-氧化蒎烯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TK4565000

CHEMICAL NAME :: Pinane, 2,3-epoxy-

CAS REGISTRY NUMBER :: 1686-14-2

BEILSTEIN REFERENCE NO. :: 0080362

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C10-H16-O

MOLECULAR WEIGHT :: 152.26

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intramuscular

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Lung

DOSE/DURATION :: 500 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 249,55,1991

α-氧化蒎烯安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
TK4565000

[ 海关编码 ]:
2932999099

α-氧化蒎烯合成路线

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α-氧化蒎烯海关

[ 海关编码 ]: 2932999099

[ 中文概述 ]:
2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

α-氧化蒎烯文献

Secondary organic aerosol from alpha-pinene ozonolysis in dynamic chamber system.

Indoor Air 19(4) , 335-45, (2009)

The formation of secondary organic aerosol (SOA) produced from alpha-pinene ozonolysis was examined using a dynamic chamber system that allowed the simulation of ventilated indoor environments. Partic...

Improvement of P450(BM-3) whole-cell biocatalysis by integrating heterologous cofactor regeneration combining glucose facilitator and dehydrogenase in E. coli.

Appl. Microbiol. Biotechnol. 78(1) , 55-65, (2008)

Escherichia coli BL21, expressing a quintuple mutant of P450(BM-3), oxyfunctionalizes alpha-pinene in an NADPH-dependent reaction to alpha-pinene oxide, verbenol, and myrtenol. We optimized the whole-...

Optimization of isonovalal production from alpha-pinene oxide using permeabilized cells of Pseudomonas rhodesiae CIP 107491.

Appl. Microbiol. Biotechnol. 60(5) , 534-40, (2003)

Optimization studies on the synthesis of isonovalal from alpha-pinene oxide by Pseudomonas rhodesiae CIP 107491 operated in a biphasic medium are presented. Three key parameters are identified. The fi...

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