乙烯基三甲氧基硅烷
乙烯基三甲氧基硅烷用途
作为RTV单组份硅橡胶交联剂,(醇型),作为交联剂应用在聚合物中(如PE)。作为偶联剂处理各种纤维、塑料、无机填料。
【用途二】
用作交联聚乙烯的交联剂
【用途三】
用作玻璃纤维处理剂
乙烯基三甲氧基硅烷名称
[ CAS 号 ]:
2768-02-7
[ 中文名 ]:
乙烯基三甲氧基硅烷
[ 英文名 ]:
Vinyltrimethoxysilane
[中文别名 ]:
[英文别名 ]:
- vts-m
- a171
- VTMO
- sz6300
- EINECS 220-449-8
- ethenyl(trimethoxy)silane
- Trimethoxy(vinyl)silane
- VTMS
- vinyl trimethoxy silane
- Trimethoxyvinylsilane
乙烯基三甲氧基硅烷物理化学性质
[ 密度 ]:
0.9±0.1 g/cm3
[ 沸点 ]:
123.0±0.0 °C at 760 mmHg
[ 熔点 ]:
123ºC
[ 分子式 ]:
C5H12O3Si
[ 分子量 ]:
148.232
[ 闪点 ]:
22.8±0.0 °C
[ 精确质量 ]:
148.055573
[ PSA ]:
27.69000
[ LogP ]:
3.12
[ 外观性状 ]:
透明无色液体
[ 蒸汽压 ]:
16.4±0.2 mmHg at 25°C
[ 折射率 ]:
1.398
[ 储存条件 ]:
2-8°C
[ 水溶解性 ]:
slightly soluble
乙烯基三甲氧基硅烷MSDS
乙烯基三甲氧基硅烷毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- VV6770000
- CHEMICAL NAME :
- Silane, trimethoxyvinyl-
- CAS REGISTRY NUMBER :
- 2768-02-7
- BEILSTEIN REFERENCE NO. :
- 1099136
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 11
- MOLECULAR FORMULA :
- C5-H12-O3-Si
- MOLECULAR WEIGHT :
- 148.26
- WISWESSER LINE NOTATION :
- 1U1-SI-O1&O1&O1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1224,1986
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1224,1986 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 7340 uL/kg
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Behavioral - somnolence (general depressed activity) Skin and Appendages - hair
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0539432
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2773 ppm
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - lacrimation Behavioral - somnolence (general depressed activity) Skin and Appendages - hair
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0539432
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 3360 uL/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - ataxia Skin and Appendages - dermatitis, other (after systemic exposure)
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0539432 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 400 ppm/14W-I
- TOXIC EFFECTS :
- Kidney, Ureter, Bladder - other changes
- REFERENCE :
- TOPADD Toxicologic Pathology. (c/o Dr. F.A. de la Iglesia, Warner-Lambert Co., Pharmaceutical Research Div., POB 1047, Ann Arbor, MI 48106) V.6(3/4)- 1978- Volume(issue)/page/year: 17,800,1989
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 750 ppm/6H/9D-I
- TOXIC EFFECTS :
- Behavioral - fluid intake Kidney, Ureter, Bladder - hematuria Nutritional and Gross Metabolic - weight loss or decreased weight gain
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0539432
乙烯基三甲氧基硅烷安全信息
[ 符号 ]:
GHS02, GHS07
[ 信号词 ]:
Danger
[ 危害声明 ]:
H225-H332
[ 警示性声明 ]:
P210
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
Xi:Irritant
[ 风险声明 (欧洲) ]:
R10;R36/37/38
[ 安全声明 (欧洲) ]:
S26-S36/37/39-S37/39-S16
[ 危险品运输编码 ]:
UN 1993 3/PG 2
[ WGK德国 ]:
1
[ RTECS号 ]:
VV6770000
[ 包装等级 ]:
III
[ 危险类别 ]:
3
[ 海关编码 ]:
29310095
乙烯基三甲氧基硅烷合成路线
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乙烯基三甲氧基硅烷海关
[ 海关编码 ]: 29310095
乙烯基三甲氧基硅烷文献
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We report results of our investigations on the cytotoxic efficacy of Organically modified silica nanoparticle (SiNp)-curcumin complex conjugated with hyaluronic acid (HA) (HA-SiNp-cur) and HA free SiN...
Versatile ene-thiol photoclick reaction for preparation of multimodal monolithic silica capillary columns.J. Chromatogr. A. 1365 , 140-7, (2014)
This paper presents a photografting process of monolithic silica capillary columns based on the ene-thiol click chemistry. This study is performed on a generic vinyl-functionalized silica monolith (Hm...
Polymeric ionic liquid bucky gels as sorbent coatings for solid-phase microextractionJ. Chromatogr. A. 1344 , 15-22, (2014)
• Polymeric ionic liquid bucky gel sorbent coatings were developed for SPME. • Method involved on-fiber co-polymerization by thermal free-radical polymerization. • Sorbent coatings were used for the e...
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