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硫氰酸苯甲酯

硫氰酸苯甲酯用途

【用途一】
用于杀虫剂的制备

硫氰酸苯甲酯名称

[ CAS 号 ]:
3012-37-1

[ 中文名 ]:
硫氰酸苄酯

[ 英文名 ]:
benzyl thiocyanate

[中文别名 ]:

[英文别名 ]:

Benzyl thiocyanate
Solvat 14
EINECS 221-144-2
Benzylrhodonid
Thiocyanic acid,benzyl ester
MFCD00001832
Benzyl-thiocyanate
Thiocyanic Acid Benzyl Ester
Thiocyanic acid,phenylmethyl ester
Tropeolin

硫氰酸苯甲酯物理化学性质

[ 密度 ]:
1.32

[ 沸点 ]:
230-235 °C(lit.)

[ 熔点 ]:
39-41 °C(lit.)

[ 分子式 ]:
C₈H₇NS

[ 分子量 ]:
149.21300

[ 闪点 ]:
>230 °F

[ 精确质量 ]:
149.03000

[ PSA ]:
49.09000

[ LogP ]:
2.40088

[ 外观性状 ]:
黄色-类白色晶体

[ 折射率 ]:
1.561 (20ºC)

[ 储存条件 ]:
低温通风干燥,与库房食品原料分开存放

[ 水溶解性 ]:
insoluble

硫氰酸苯甲酯MSDS

硫氰酸苯甲酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XK8155000

CHEMICAL NAME :: Thiocyanic acid, benzyl ester

CAS REGISTRY NUMBER :: 3012-37-1

BEILSTEIN REFERENCE NO. :: 1859726

LAST UPDATED :: 199701

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C8-H7-N-S

MOLECULAR WEIGHT :: 149.22

WISWESSER LINE NOTATION :: NCS1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 40 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ARZNAD Arzneimittel-Forschung. Drug Research. (Editio Cantor Verlag, Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.) V.1- 1951- Volume(issue)/page/year: 16,870,1966

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 17 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PCBPBS Pesticide Biochemistry and Physiology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1971- Volume(issue)/page/year: 2,95,1972

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Lungs, Thorax, or Respiration - respiratory stimulation Lungs, Thorax, or Respiration - other changes

REFERENCE :: JJPAAZ Japanese Journal of Pharmacology. (Japanese Pharmacological Soc., c/o Dept. of Pharmacology, Faculty of Medicine, Kyoto Univ., Sakyo-ku, Kyoto 606, Japan) V.1- 1951- Volume(issue)/page/year: 3,99,1954 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1248 No. of Facilities: 28 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 112 (estimated)

硫氰酸苯甲酯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302 + H312 + H332

[ 警示性声明 ]:
P280

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R20/21/22;R32

[ 安全声明 (欧洲) ]:
S13-S36/37-S50A

[ 危险品运输编码 ]:
UN 1759 8/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
XK8155000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
29309070

硫氰酸苯甲酯合成路线

硫氰酸苯甲酯上下游产品

硫氰酸苯甲酯上游产品

硫氰酸苯甲酯下游产品

硫氰酸苯甲酯海关

[ 海关编码 ]: 2930909090

[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

硫氰酸苯甲酯文献

In vitro metabolic conversion of the organic breakdown products of glucosinolate to goitrogenic thiocyanate anion.

J. Sci. Food Agric. 95 , 2244-51, (2015)

Glucosinolates are abundant in Brassicaceae vegetables, and they are degraded into various organic breakdown products (BPs) (R-CN, -NCS and -SCN) by myrosinase when plant tissues are damaged. This stu...

Subcellular localization of enzymes in Streptomyces aureofaciens and its alteration by benzyl thiocyanate. I. Phosphatases and ATP-glucokinase.

Folia Microbiol. (Praha) 32(5) , 402-10, (1987)

Mycelia of a low- and a high-production strain of Streptomyces aureofaciens were converted into protoplasts and divided into five subcellular fractions in order to localize exopolyphosphatases (EC 3.6...

Protein profiles of Streptomyces aureofaciens producing tetracyclines: reappraisal of the effect of benzyl thiocyanate.

Curr. Microbiol. 31(2) , 84-91, (1995)

Cell protein profiles of submerged cultures of Streptomyces aureofaciens cultivated in the absence or presence of 12 microM benzyl thiocyanate (BT) were analyzed by one-dimensional SDS polyacrylamide ...

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