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溴代叔丁烷

溴代叔丁烷用途

【用途一】
用作有机合成中间体
【用途二】
有机中间体，溶剂。

溴代叔丁烷名称

[ CAS 号 ]:
507-19-7

[ 中文名 ]:
溴代叔丁烷

[ 英文名 ]:
2-Bromo-2-methylpropane

[中文别名 ]:

[英文别名 ]:

t-Butyl bromide
EINECS 208-065-9
t-butylbromide
2-Bromo-2-methylpropane
Tertiary butyl bromide
Propane,2-bromo-2-methyl
1-bromo-1,1-dimethylethane
2-methyl-2-bromopropane
Bromotrimethylmethane
2-Bromo-2-methyl-propane

溴代叔丁烷物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
73.2±0.0 °C at 760 mmHg

[ 熔点 ]:
-20 °C

[ 分子式 ]:
C₄H₉Br

[ 分子量 ]:
137.018

[ 闪点 ]:
18.3±0.0 °C

[ 精确质量 ]:
135.988754

[ LogP ]:
2.38

[ 外观性状 ]:
透明无色液体

[ 蒸汽压 ]:
125.7±0.1 mmHg at 25°C

[ 折射率 ]:
1.438

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开存放

[ 水溶解性 ]:
insoluble

溴代叔丁烷MSDS

详细MSDS(安全技术说明书)

溴代叔丁烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TX4150000

CHEMICAL NAME :: Propane, 2-bromo-2-methyl-

CAS REGISTRY NUMBER :: 507-19-7

LAST UPDATED :: 199709

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C4-H9-Br

MOLECULAR WEIGHT :: 137.04

WISWESSER LINE NOTATION :: EX1&1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1250 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,29,1982

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 4400 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,29,1982 ** TUMORIGENIC DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 3000 mg/kg/8W-I

TOXIC EFFECTS :: Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors

REFERENCE :: CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 35,1411,1975

溴代叔丁烷安全信息

[ 符号 ]:

GHS02

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225

[ 警示性声明 ]:
P210

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable;Xi:Irritant;

[ 风险声明 (欧洲) ]:
R11;R36/37/38

[ 安全声明 (欧洲) ]:
S16-S33-S37/39-S26

[ 危险品运输编码 ]:
UN 2342 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
TX4150000

[ 包装等级 ]:
II

[ 危险类别 ]:
3

[ 海关编码 ]:
29033036

溴代叔丁烷合成路线

详细合成路线

溴代叔丁烷上下游产品

溴代叔丁烷上游产品

溴代叔丁烷下游产品

溴代叔丁烷制备

叔丁醇经溴化而得。

溴代叔丁烷海关

[ 海关编码 ]: 29033036

溴代叔丁烷文献

Deguanylation of guanine based-nucleosides and calf thymus DNA induced by halogenated alkanes at the physiological condition. Sherchan J and Lee E-S.

Bull. Korean Chem. Soc. 30(12) , 2318-2328, (2009)

Deadenylation of Adenine Based-Nucleosides and Calf thymus DNA Induced by Halogenated Alkanes at the Physiological Condition. Sherchan J, et al.

Bull. Korean Chem. Soc. 30(10) , 2318-2328, (2009)

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