九水合硝酸铝

九水合硝酸铝用途

【用途一】
用于制催化剂、媒染剂、皮革鞣剂、防腐蚀抑制剂、其他铝盐及在核工业中用作盐析剂
【用途二】
用作分析试剂、氧化剂和媒染剂
【用途三】
用于制造有机合成用催化剂、印染工业的媒染剂、用作鞣革和皮革整理剂。也用于制造其他铝盐产品。
【用途四】
铀的萃取，硝化剂，阻蚀剂，石油精制催化剂,媒染剂, 其他铝盐及在核工业中用作盐析剂。

九水合硝酸铝名称

[ CAS 号 ]:
7784-27-2

[ 中文名 ]:
硝酸铝九水合物

[ 英文名 ]:
Aluminumnitratenonahydrate

[中文别名 ]:

[英文别名 ]:

Aluminium trinitrate
Aluminum nitrate hydrate (1:3:9)
Nitricacid,al
Aluminium nitrate no
MFCD00149132
AluminiumNitrate9H2OAcs
AluminiumNitrateAr
UNII:8MC6621V1H
ALUMINIUM STANDARD
ALUMINUM NITRATE 9H2O

九水合硝酸铝物理化学性质

[ 密度 ]:
1.25

[ 沸点 ]:
100°C/760mmHg

[ 熔点 ]:
73 °C(lit.)

[ 分子式 ]:
AlN₃O₉

[ 分子量 ]:
212.996

[ 精确质量 ]:
212.944992

[ PSA ]:
289.71000

[ LogP ]:
0.61110

[ 外观性状 ]:
白色结晶粉末

[ 折射率 ]:
1.54

[ 储存条件 ]:
库房通风低温干燥

[ 稳定性 ]:
Strong oxidizer - contact with combustible material may lead to fire. Incompatible with water, most common metals, organics. Moisture-sensitive.

[ 水溶解性 ]:
64 g/100 mL (25 ºC)

九水合硝酸铝MSDS

九水合硝酸铝毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BD1050000

CAS REGISTRY NUMBER :: 7784-27-2

LAST UPDATED :: 199712

DATA ITEMS CITED :: 25

MOLECULAR FORMULA :: N3-O9.Al.9H2-O

MOLECULAR WEIGHT :: 375.19

WISWESSER LINE NOTATION :: .AL..N-O3*3.QH9

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3671 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Gastrointestinal - changes in structure or function of salivary glands

REFERENCE :: HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 31(7-9),204,1966

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 901 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Skin and Appendages - hair Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: PHTOEH Pharmacology and Toxicology (Copenhagen). (Munksgaard International Pub., POB 2148, DK-1016 Copenhagen K, Denmark) V.60- 1987- Volume(issue)/page/year: 60,280,1987

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 3980 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Skin and Appendages - hair Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: PHTOEH Pharmacology and Toxicology (Copenhagen). (Munksgaard International Pub., POB 2148, DK-1016 Copenhagen K, Denmark) V.60- 1987- Volume(issue)/page/year: 60,280,1987

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1587 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Skin and Appendages - hair Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: PHTOEH Pharmacology and Toxicology (Copenhagen). (Munksgaard International Pub., POB 2148, DK-1016 Copenhagen K, Denmark) V.60- 1987- Volume(issue)/page/year: 60,280,1987 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 9800 mg/kg/28W-C

TOXIC EFFECTS :: Kidney, Ureter, Bladder - other changes in urine composition Kidney, Ureter, Bladder - changes in bladder weight Related to Chronic Data - changes in testicular weight

REFERENCE :: TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 116,1,1997

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1820 mg/kg/26W-I

TOXIC EFFECTS :: Nutritional and Gross Metabolic - other changes

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 31(8),16,1966

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3 gm/kg/10D-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - acute pulmonary edema Gastrointestinal - peritonitis Gastrointestinal - other changes

REFERENCE :: CCROBU Cancer Chemotherapy Reports, Part 1. (Washington, DC) V.52(6)-59, 1968-75. For publisher information, see CTRRDO. Volume(issue)/page/year: 59,599,1975

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2500 mg/kg/10D-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - acute pulmonary edema Related to Chronic Data - death

REFERENCE :: CCROBU Cancer Chemotherapy Reports, Part 1. (Washington, DC) V.52(6)-59, 1968-75. For publisher information, see CTRRDO. Volume(issue)/page/year: 59,599,1975

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 1820 mg/kg/26W-I

TOXIC EFFECTS :: Behavioral - irritability

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 31(8),16,1966 ** REPRODUCTIVE DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 1620 mg/kg

SEX/DURATION :: female 6-14 day(s) after conception

TOXIC EFFECTS :: Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Effects on Embryo or Fetus - fetal death Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue)

REFERENCE :: TJADAB Teratology, The International Journal of Abnormal Development. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1968- Volume(issue)/page/year: 38,253,1988

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 1620 mg/kg

SEX/DURATION :: female 6-14 day(s) after conception

TOXIC EFFECTS :: Reproductive - Specific Developmental Abnormalities - musculoskeletal system

REFERENCE :: TJADAB Teratology, The International Journal of Abnormal Development. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1968- Volume(issue)/page/year: 38,253,1988

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 6480 mg/kg

SEX/DURATION :: female 6-14 day(s) after conception

TOXIC EFFECTS :: Reproductive - Specific Developmental Abnormalities - cardiovascular (circulatory) system

REFERENCE :: TJADAB Teratology, The International Journal of Abnormal Development. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1968- Volume(issue)/page/year: 38,253,1988

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 7740 mg/kg

SEX/DURATION :: female 1-22 day(s) after conception lactating female 21 day(s) post-birth

TOXIC EFFECTS :: Reproductive - Effects on Newborn - physical

REFERENCE :: RCOCB8 Research Communications in Chemical Pathology and Pharmacology. (PJD Pub. Ltd., P.O. Box 966, Westbury, NY 11590) V.1- 1970- Volume(issue)/page/year: 57,129,1987 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Al)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Al)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Al)/m3 JAN 1993 OEL-FRANCE:TWA 2 mg(Al)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3 JAN 1993 OEL-RUSSIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Al)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

九水合硝酸铝安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H318

[ 警示性声明 ]:
P280-P305 + P351 + P338 + P310

[ 个人防护装备 ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
Xn:Harmful

[ 风险声明 (欧洲) ]:
R22;R36;R8

[ 安全声明 (欧洲) ]:
S17-S26-S36

[ 危险品运输编码 ]:
UN 1438 5.1/PG 3

[ WGK德国 ]:
1

[ RTECS号 ]:
BD1050000

[ 包装等级 ]:
III

[ 危险类别 ]:
5.1

[ 海关编码 ]:
28342980

九水合硝酸铝合成路线

九水合硝酸铝上下游产品

九水合硝酸铝上游产品

九水合硝酸铝下游产品

九水合硝酸铝制备

1.合成法将金属铝板用10%烧碱溶液清洗除去表面油污后，用水冲洗，放入带搅拌的反应器中，加入少量氧化汞作氧化剂，再缓慢加入约38%稀硝酸，用蒸汽加热使反应在110～115℃下进行2h，生成反应溶液浓度为25～32°Bé，经澄清、过滤，滤液经蒸发浓缩至45～47°Bé，再经冷却结晶、离心分离，制得硝酸铝成品。其

母液送至蒸发器循环使用。反应时放出的二氧化氮气体用碱液吸收可副产亚硝酸钠或硝酸钠。
铝灰-硝酸法将烧碱溶液和铝灰加入反应器中进行反应生成铝酸钠后，加硝酸进行反应生成氢氧化铝和硝酸钠，反应液经过滤后，将氢氧化铝加硝酸溶解而成硝酸铝溶液，再经过滤、蒸发浓缩、冷却结晶、离心分离，制得硝酸铝成品。其
2.将400g Al(OH)3的潮湿膏状物在不断搅拌下分次加入170mL HNO3(密度为1.34g/cm3)。将形成的浑浊溶液在水浴上蒸发至溶液密度为1.42g/cm3(50℃)。冷却后，加入200mL水溶解过滤，滤液重新在水浴上蒸发至溶液密度为1.42g/cm3。冷却结晶，用少量水(10mL)洗涤，即得。 3. ．在搅拌下徐徐将相对密度为1.34的硝酸加到潮湿的氢氧化铝糊状物中，进行反应：将反应后的混浊液体加热蒸发至密度1.52 （ 50℃）。将溶液冷却并全部结晶，加蒸馏水至结晶全部溶解，过滤，滤液重新加热蒸发至密度为 1.52（50℃）时冷却结晶，甩干，然后用少
量水洗涤结晶2次，干燥，可得分析纯结晶硝酸铝。母液可按上法回收结晶。
4．用水分别溶解结晶硫酸铝和硝酸钡，将两种溶液分别加热后进行反应：反应结束后过滤，滤出硫酸钡，检验滤液中SO ₄ ^2- 、Ba ²⁺离子含量合格（若不合格，可加硝酸钡或硫酸铝溶液除去）后，按上述方法进行蒸发提纯。

九水合硝酸铝海关

[ 海关编码 ]: 28342980

九水合硝酸铝文献

Multivariate optimization of process parameters in the synthesis of calcined Ca‒Al (NO3) LDH for defluoridation using 3(3) factorial, central composite and Box-Behnken design.

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Response surface methodology was applied for the first time in the optimization of the preparation of layered double hydroxide (LDH) for defluoridation. The influence of three vital process parameters...

The metal-organic framework HKUST-1 as efficient sorbent in a vortex-assisted dispersive micro solid-phase extraction of parabens from environmental waters, cosmetic creams, and human urine.

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Visible light functioning photocatalyst based on Al2O3 doped Mn3O4 nanomaterial for the degradation of organic toxin.

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Al2O3 doped Mn3O4 nanomaterial was synthesized by low-temperature stirring method and applied as a catalyst for the degradation of organic pollutants under solar light for prospective environmental ap...

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