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2-氨基联苯

2-氨基联苯用途

【用途一】
用作有机合成的原料。制造咔唑树脂，合成橡胶。
【用途二】
制造咔唑树脂及合成橡胶。癌症研究。化学分析。糖类的测定

2-氨基联苯名称

[ CAS 号 ]:
90-41-5

[ 中文名 ]:
邻氨基联苯

[ 英文名 ]:
2-Aminodiphenyl

[中文别名 ]:

[英文别名 ]:

2-phenylaniline
MFCD00007126
(1,1'-BIPHENYL)AMINE
PHENYLANILINE
EINECS 201-990-9
2-Biphenylamine
biphenylamine
[1,1'-Biphenyl]-2-amine
2-Aminobiphenyl
biphenyl-2-amine

2-氨基联苯物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
299.0±0.0 °C at 760 mmHg

[ 熔点 ]:
47-50 °C(lit.)

[ 分子式 ]:
C₁₂H₁₁N

[ 分子量 ]:
169.222

[ 闪点 ]:
149.9±14.6 °C

[ 精确质量 ]:
169.089142

[ PSA ]:
26.02000

[ LogP ]:
2.68

[ 外观性状 ]:
无色至紫色结晶固体

[ 蒸汽密度 ]:
5.9 (vs air)

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.619

[ 储存条件 ]:
库房通风低温干燥

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
<0.01 g/100 mL at 21 ºC

2-氨基联苯MSDS

详细MSDS(安全技术说明书)

2-氨基联苯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DU8850000

CHEMICAL NAME :: 2-Biphenylamine

CAS REGISTRY NUMBER :: 90-41-5

BEILSTEIN REFERENCE NO. :: 0471874

LAST UPDATED :: 199710

DATA ITEMS CITED :: 23

MOLECULAR FORMULA :: C12-H11-N

MOLECULAR WEIGHT :: 169.24

WISWESSER LINE NOTATION :: ZR BR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2340 mg/kg

TOXIC EFFECTS :: Behavioral - coma Lungs, Thorax, or Respiration - dyspnea Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 1020 mg/kg

TOXIC EFFECTS :: Behavioral - coma Lungs, Thorax, or Respiration - dyspnea Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 137 gm/kg/13W-C

TOXIC EFFECTS :: Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis) Blood - changes in spleen Blood - changes in leukocyte (WBC) count

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 7 gm/kg/14D-C

TOXIC EFFECTS :: Blood - changes in spleen

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 328 gm/kg/13W-C

TOXIC EFFECTS :: Liver - other changes Blood - changes in bone marrow (not otherwise specified) Blood - changes in leukocyte (WBC) count

MUTATION DATA

TYPE OF TEST :: Cytogenetic analysis

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 1100 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 265,45,1992 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 82091 No. of Facilities: 28 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 700 (estimated)

2-氨基联苯安全信息

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22;R40;R52/53

[ 安全声明 (欧洲) ]:
S36/37-S61

[ 危险品运输编码 ]:
3077.0

[ WGK德国 ]:
3

[ RTECS号 ]:
DV5530000

[ 危险类别 ]:
9.0

[ 海关编码 ]:
29214980

2-氨基联苯合成路线

详细合成路线

2-氨基联苯上下游产品

2-氨基联苯上游产品

2-氨基联苯下游产品

2-氨基联苯制备

以邻硝基联苯为原料，经还原而得：将邻硝基联苯、乙醇、氯化亚锡于水浴回流3h，回收乙醇，将剩余物冷却，加入40%液碱使呈强碱性，分出油层，水层用乙醚提取，将提取液用无水氯化钙干燥，过滤回收乙醚，用乙醇洗得粗品，再将粗品减压蒸馏而得成品。

2-氨基联苯海关

[ 海关编码 ]: 2921499090

[ 中文概述 ]:
2921499090 其他芳香单胺及衍生物及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%