14873-63-3

• 常用中文名：双(氰苯)二氯铂(II)
• 常用英文名：Bis(benzonitrile)dichloroplatinum(II)
• CAS号：14873-63-3
• 分子式：C₁₄H₁₀Cl₂N₂Pt
• 分子量：472.233
• 发布时间：2018-08-26 17:56:13
• 更新时间：2024-01-02 10:00:40

名称

• 中文名: 双(氰苯)二氯铂(II)
• 英文名: Dichlorobis(benzonitrile)platinum(II)
• 中文别名: 二(苯甲氰)合二氯化铂; 二(苯基氰)二氯化铂; 二(苯甲腈)合二氯化铂; 二(苯基氰)二氯化铂(II)
• 英文别名: EINECS 238-943-7; Benzonitrile, platinum(2+) salt, hydrochloride (2:1:2); Bis(benzonitrile)dichloroplatinum(II); Platinum(2+) chloride - benzonitrile (1:2:2); Platinum(2+)ato chlorido - benzonitrilato (1:2:2); MFCD00013125

物化性质

• 沸点: 191.1ºC at 760mmHg
• 熔点: 224ºC (dec.)
• 分子式: C₁₄H₁₀Cl₂N₂Pt
• 分子量: 472.233
• 闪点: 71.7ºC
• 精确质量: 470.986908
• PSA: 47.58000
• 蒸汽压: 0.524mmHg at 25°C
• 储存条件:

  常温密闭避光，通风干燥

• 稳定性:

  常温常压下稳定

  避免的物料：水分/潮湿 氧化物
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：470.986904 Da

  8、标称质量：471 Da

  9、平均质量：472.2326 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:4

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积47.6

  7.重原子数量:19

  8.表面电荷:0

  9.复杂度:103

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:5

• 更多:

  1.性状：黄色微晶

  2.密度（g/mL,25/4℃）：未确定

  3.相对蒸汽密度（g/mL,空气=1）：未确定

  4.熔点（ºC）：224

  5.沸点（ºC,常压）：未确定

  6.沸点（ºC,5.2kPa）：未确定

  7.折射率：未确定

  8.闪点（ºC）：未确定

  9.比旋光度（º）：未确定

  10.自燃点或引燃温度（ºC）：未确定

  11.蒸气压（kPa,25ºC）：未确定

  12.饱和蒸气压（kPa,60ºC）：未确定

  13.燃烧热（KJ/mol）：未确定

  14.临界温度（ºC）：未确定

  15.临界压力（KPa）：未确定

  16.油水（辛醇/水）分配系数的对数值：未确定

  17.爆炸上限（%,V/V）：未确定

  18.爆炸下限（%,V/V）：未确定

  19.溶解性：未确定

MSDS

Section 1: Product Identification Chemical Name:Dichlorobis(benzonitrile)platinum (II), 99% CAS Registry Number:14873-63-3 Formula:PtCl2(C6H5CN)2 EINECS Number:238-943-7 Chemical Family:organometallic complexes Synonym:Platinum dichlorobis(benzonitrile) Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound14873-63-3100%1mg/m3(as-Pt)no data Section 3: Hazards Identification Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, inhalation, skin Eye Contact:Causes mild to moderate irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to skin, eyes and respiratory tract. Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions. Acute Health Affects:Irritating to skin, eyes, mucous membranes, and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry place in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:To minimize exposure, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:To minimize exposure, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:yellow to orange xtl. Molecular Weight:472.24 Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents, halogens and active metals Decomposition Products:carbon monoxide, carbon dioxide, hydrogen chloride, organic fumes, and platinum salts. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Not regulated by Title 313. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

安全

• 风险声明 (欧洲): R20/21/22
• 安全声明 (欧洲): S26-S36/37/39
• 危险品运输编码: UN3439
• 包装等级: III
• 危险类别: 6.1

合成路线

10025-99-7 100-47-0 ~85% 14873-63-3

文献：Canadian Journal of Chemistry, , vol. 74, # 2 p. 144 - 152

10025-99-7 ~60% 14873-63-3 14873-63-3

文献：Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 947 - 952

10025-99-7 100-47-0 ~60% 14873-63-3 14873-63-3

文献：Inorganica Chimica Acta, , vol. 201, p. 15 - 22

上下游产品

上游产品  2
10025-99-7 100-47-0
下游产品  4
22455-18-1 14056-88-3 10199-34-5 30053-58-8