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14873-63-3

14873-63-3 structure
14873-63-3 structure
  • Name: Bis(benzonitrile)dichloroplatinum(II)
  • Chemical Name: Dichlorobis(benzonitrile)platinum(II)
  • CAS Number: 14873-63-3
  • Molecular Formula: C14H10Cl2N2Pt
  • Molecular Weight: 472.233
  • Create Date: 2018-08-26 17:56:13
  • Modify Date: 2024-01-02 10:00:40

Name Dichlorobis(benzonitrile)platinum(II)
Synonyms EINECS 238-943-7
Benzonitrile, platinum(2+) salt, hydrochloride (2:1:2)
Bis(benzonitrile)dichloroplatinum(II)
Platinum(2+) chloride - benzonitrile (1:2:2)
Platinum(2+)ato chlorido - benzonitrilato (1:2:2)
MFCD00013125
Boiling Point 191.1ºC at 760mmHg
Melting Point 224ºC (dec.)
Molecular Formula C14H10Cl2N2Pt
Molecular Weight 472.233
Flash Point 71.7ºC
Exact Mass 470.986908
PSA 47.58000
Vapour Pressure 0.524mmHg at 25°C

Section 1: Product Identification
Chemical Name:Dichlorobis(benzonitrile)platinum (II), 99%
CAS Registry Number:14873-63-3
Formula:PtCl2(C6H5CN)2
EINECS Number:238-943-7
Chemical Family:organometallic complexes
Synonym:Platinum dichlorobis(benzonitrile)

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound14873-63-3100%1mg/m3(as-Pt)no data

Section 3: Hazards Identification
Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, inhalation, skin
Eye Contact:Causes mild to moderate irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to skin, eyes and respiratory tract.
Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Acute Health Affects:Irritating to skin, eyes, mucous membranes, and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:To minimize exposure, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:To minimize exposure, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:yellow to orange xtl.
Molecular Weight:472.24
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents, halogens and active metals
Decomposition Products:carbon monoxide, carbon dioxide, hydrogen chloride, organic fumes, and platinum salts.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Not regulated by Title 313.
Second Ingredient:None


SECTION 16 - ADDITIONAL INFORMATION
N/A
Risk Phrases R20/21/22
Safety Phrases S26-S36/37/39
RIDADR UN3439
Packaging Group III
Hazard Class 6.1

~85%

14873-63-3 structure

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Literature: Canadian Journal of Chemistry, , vol. 74, # 2 p. 144 - 152

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14873-63-3 structure

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Literature: Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 947 - 952

~60%

14873-63-3 structure

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14873-63-3 structure

14873-63-3

Literature: Inorganica Chimica Acta, , vol. 201, p. 15 - 22