37083-37-7

• 常用中文名：5,10,15,20-四(2,6-二氯苯基)卟吩
• 常用英文名：5,10,15,20-Tetrakis(2,6-dichlorophenyl)porphyrin
• CAS号：37083-37-7
• 分子式：C₄₄H₂₂Cl₈N₄
• 分子量：890.296
• 相关类别： 研究领域 其他
• 发布时间：2018-12-16 17:59:34
• 更新时间：2024-01-02 11:57:47
• 5,10,15,20-四(2,6-二氯苯基)卟啉是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

名称

• 中文名: 5,10,15,20-四(2,6-二氯苯基)卟啉
• 英文名: meso-tetrakis-(2,6-dichlorophenyl)porphyrin
• 中文别名: 5,10,15,20-四(2,6-二氯苯基)卟吩
• 英文别名: 5,10,15,20-Tetrakis(2,6-dichlorophenyl)-21H,23H-porphine; 5,10,15,20-Tetrakis(2,6-dichlorophenyl)porphine; 5,10,15,20-Tetrakis(2,6-dichlorophenyl)porphyrin; MESO-TETRA(O-DICHLOROPHENYL) PORPHINE; meso-Tetrakis(2,6-dichlorophenyl)porphine; 21H,23H-Porphine, 5,10,15,20-tetrakis(2,6-dichlorophenyl)-

物化性质

• 密度: 1.5±0.1 g/cm3
• 分子式: C₄₄H₂₂Cl₈N₄
• 分子量: 890.296
• 精确质量: 885.935242
• PSA: 56.30000
• LogP: 16.24
• 外观性状: 固体;Green to Dark green to Dark blue powder to crystal
• 折射率: 1.706
• 储存条件: 室温
• 计算化学:

  1.疏水参数计算参考值（XlogP）:15.4

  2.氢键供体数量:2

  3.氢键受体数量:2

  4.可旋转化学键数量:4

  5.互变异构体数量:2

  6.拓扑分子极性表面积57.4

  7.重原子数量:56

  8.表面电荷:0

  9.复杂度:1210

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

生物活性

• 描述: 5,10,15,20-四(2,6-二氯苯基)卟啉是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。
• 相关类别:
  研究领域 >> 其他

MSDS

Section I.Chemical Product and Company Identification Chemical Name 5,10,15,20-Tetrakis(2,6-dichlorophenyl)porphine Portland OR Not available. Synonym C44H22Cl8N4 Chemical Formula CAS Number37083-37-7 Section II.Composition and Information on Ingredients Chemical NameCAS Number Percent (%)TLV/PELToxicology Data 5,10,15,20-Tetrakis(2,6-dichlorophenyl)porphine37083-37-7Min. Not available.Not available. 98.0%(HPLC) Section III. Hazards Identification Acute Health EffectsNo specific information is available in our data base regarding the toxic effects of this material for humans. However, exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling this compound. CARCINOGENIC EFFECTS : Not available. Chronic Health Effects MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions. Section IV.First Aid Measures Eye ContactCheck for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Skin ContactIn case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. If the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or Inhalation waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not improve. IngestionINDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Section V.Fire and Explosion Data Not available. Auto-Ignition FlammabilityMay be combustible at high temperature. Flash PointsFlammable LimitsNot available. Not available. Combustion ProductsThese products are toxic carbon oxides (CO, CO2), nitrogen oxides (NO, NO2), halogenated compounds. WARNING: Highly toxic HCl gas is produced during combustion. Fire Hazards Not available. Explosion HazardsRisks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting Media SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet. and Instructions Consult with local fire authorities before attempting large scale fire-fighting operations. Continued on Next Page 5,10,15,20-Tetrakis(2,6-dichlorophenyl)porphine Section VI.Accidental Release Measures Spill CleanupUse a shovel to put the material into a convenient waste disposal container. Finish cleaning the spill by rinsing any contaminated surfaces with copious amounts of water. Consult federal, state, and/or local authorities for assistance on Instructions disposal. Section VII. Handling and Storage Keep away from heat. Mechanical exhaust required. When not in use, tightly seal the container and store in a dry, cool Handling and Storage place. Avoid excessive heat and light. Do not breathe dust. Information Always store away from incompatible compounds such as oxidizing agents. Section VIII. Exposure Controls/Personal Protection Engineering ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal ProtectionSplash goggles. Lab coat. Dust respirator. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure LimitsNot available. Section IX. Physical and Chemical Properties Solid. (Violet Crystalline Powder.)Solubility Physical state @ 20°CNot available. Not available. Specific Gravity Molecular Weight890.31Partition CoefficientNot available. Boiling Point Not available.Vapor PressureNot applicable. Melting PointNot available.Vapor DensityNot available. Refractive IndexNot available.VolatilityNot available. Critical TemperatureNot available.OdorNot available. ViscosityNot available.TasteNot available. Section X.Stability and Reactivity Data Stability This material is stable if stored under proper conditions. (See Section VII for instructions) Conditions of InstabilityAvoid excessive heat and light. IncompatibilitiesReactive with oxidizing agents. Section XI. Toxicological Information Not available. RTECS Number Eye Contact. Ingestion. Inhalation. Routes of Exposure Toxicity DataNot available. Chronic Toxic EffectsCARCINOGENIC EFFECTS : Not available. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions. Acute Toxic EffectsNo specific information is available in our data base regarding the toxic effects of this material for humans. However, exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling this compound. Continued on Next Page 5,10,15,20-Tetrakis(2,6-dichlorophenyl)porphine Section XII.Ecological Information EcotoxicityNot available. Not available. Environmental Fate Section XIII. Disposal Considerations Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a Waste Disposal combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section XIV. Transport Information DOT ClassificationNot a DOT controlled material (United States). Not applicable. PIN Number Proper Shipping Name Not applicable. Packing Group (PG)Not applicable. DOT Pictograms Section XV. Other Regulatory Information and Pictograms TSCA Chemical InventoryThis product is NOT on the EPA Toxic Substances Control Act (TSCA) inventory. The following notices are required by 40 CFR 720.36 (C) for those products not on the inventory list: (EPA) (i) These products are supplied solely for use in research and development by or under the supervision of a technically qualified individual as defined in 40 CFR 720.0 et sec. (ii) The health risks of these products have not been fully determined. Any information that is or becomes available will be supplied on an MSDS sheet. WHMIS ClassificationNot controlled under WHMIS (Canada). (Canada) EINECS Number (EEC)Not available. EEC Risk StatementsNot available. SECTION 16 - ADDITIONAL INFORMATION N/A

合成路线

109-97-7 83-38-5 ~22% 37083-37-7

文献：Naik, Rajan; Joshi, Padmakar; Kaiwar, Sharada P.; Deshpande, Rajesh K. Tetrahedron, 2003 , vol. 59, # 13 p. 2207 - 2213

83-38-5 ~% 37083-37-7

文献：Li, Feirong; Yang, Kexin; Tyhonas, John S.; MacCrum, Kristy A.; Lindsey, Jonathan S. Tetrahedron, 1997 , vol. 53, # 37 p. 12339 - 12360

83-38-5 194796-34-4 ~19% 37083-37-7

文献：Naik, Rajan; Joshi, Padmakar; Kaiwar, Sharada P.; Deshpande, Rajesh K. Tetrahedron, 2003 , vol. 59, # 13 p. 2207 - 2213

109-97-7 874-42-0 ~5% 37083-37-7

文献：Gonsalves, A. M. d'A.; Varejao, Jorge M. T. B.; Pereira, Mariette M. Journal of Heterocyclic Chemistry, 1991 , vol. 28, # 3 p. 635 - 640

109-97-7 5866-97-7 83-38-5 ~% 37083-37-7 详细

文献：Banfi, Stefano; Montanari, Fernando; Pozzi, Gianluca; Quici, Silvio Tetrahedron, 1994 , vol. 50, # 30 p. 9025 - 9036

109-97-7 6361-22-4 83-38-5 ~% 37083-37-7 详细

文献：Banfi, Stefano; Montanari, Fernando; Quici, Silvio Gazzetta Chimica Italiana, 1990 , vol. 120, # 7 p. 435 - 441

6575-24-2 ~% 37083-37-7

文献：Farhadi, Saeid; Zabardasti, Abedien; Rahmati, Mohammad Hosien Journal of Chemical Research, 2011 , vol. 35, # 3 p. 157 - 160

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