16473-11-3

• 常用中文名：二环[3.3.1]壬烷-2,6-二酮
• 常用英文名：Bicyclo[3,3,1]nonane-2,6-dione
• CAS号：16473-11-3
• 分子式：C₉H₁₂O₂
• 分子量：152.19000
• 发布时间：2018-12-25 13:14:32
• 更新时间：2024-01-04 08:28:36
• 下载msds

名称

• 中文名: 二环[3.3.1]壬烷-2,6-二酮
• 英文名: Bicyclo[3.3.1]nonane-2,6-dione
• 英文别名: bicyclo[3.3.1]nonane-2,6-dione; MFCD00153926

物化性质

• 密度: 1.138 g/cm3
• 沸点: 283.7ºC at 760 mmHg ，180ºC/20mm
• 熔点: 151ºC
• 分子式: C₉H₁₂O₂
• 分子量: 152.19000
• 闪点: 105.6ºC
• 精确质量: 152.08400
• PSA: 34.14000
• LogP: 1.33470
• 外观性状: 白色至灰白色结晶粉末
• 蒸汽压: 0.00311mmHg at 25°C
• 折射率: 1.507
• 储存条件: 室温

MSDS

Name: Bicyclo[3.3.1]nonane-2 6-dione 97% Material Safety Data Sheet Synonym: CAS: 16473-11-3 Section 1 - Chemical Product MSDS Name:Bicyclo[3.3.1]nonane-2 6-dione 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 16473-11-3 Bicyclo[3.3.1]nonane-2,6-dione 97% unlisted Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 16473-11-3: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 180 deg C @20mmHg Freezing/Melting Point: 151 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C9H12O2 Molecular Weight: 152 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, acrid smoke and fumes. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 16473-11-3 unlisted. LD50/LC50: Not available. Carcinogenicity: Bicyclo[3.3.1]nonane-2,6-dione - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 16473-11-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 16473-11-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 16473-11-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 符号: GHS05
• 信号词: Danger
• 危害声明: H318
• 警示性声明: P280-P305 + P351 + P338
• 个人防护装备: dust mask type N95 (US);Eyeshields;Gloves
• 危害码 (欧洲): Xi
• 风险声明 (欧洲): R41
• 安全声明 (欧洲): S24/25
• 危险品运输编码: NONH for all modes of transport
• 海关编码: 2914299000

合成路线

6966-22-9 ~78% 16473-11-3

文献：Mislin, Gaetan; Miesch, Michel European Journal of Organic Chemistry, 2001 , # 9 p. 1753 - 1759

315207-70-6 ~% 16473-11-3

文献：Journal of Organic Chemistry, , vol. 33, # 7 p. 2655 - 2659

18214-48-7 ~% 16473-11-3

文献：Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 1885 - 1888

58773-94-7 ~% 16473-11-3

文献：Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 1885 - 1888

16473-12-4 1066-30-4 ~% 16473-11-3

文献：Journal fuer Praktische Chemie (Leipzig), , vol. <2> 104, p. 182

54696-28-5 7732-18-5 ~% 16473-11-3

文献：Justus Liebigs Annalen der Chemie, , vol. 398, p. 214

201992-27-0 7732-18-5 ~% 16473-11-3

文献：Justus Liebigs Annalen der Chemie, , vol. 398, p. 214

42824-94-2 1066-30-4 ~% 16473-11-3

文献：Journal fuer Praktische Chemie (Leipzig), , vol. <2> 104, p. 182

7647-01-0 315207-70-6 ~% 16473-11-3

文献：Justus Liebigs Annalen der Chemie, , vol. 398, p. 214

上下游产品

上游产品  9
6966-22-9 315207-70-6 58773-94-7 16473-12-4
1066-30-4 54696-28-5 7732-18-5 201992-27-0
42824-94-2
下游产品  9
10036-12-1 106913-99-9 26069-13-6 81386-78-9
13534-07-1 16473-12-4 42824-94-2 89784-07-6
39751-07-0

海关

海关编码	2914299000
中文概述	2914299000. 其他不含其他含氧基的环烷酮、环烯酮或环萜烯酮. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 丙酮报明包装
Summary	2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%