2275-14-1

2275-14-1结构式

常用中文名：芬硫磷
常用英文名：Phenkapton
CAS号：2275-14-1
分子式：C₁₁H₁₅Cl₂O₂PS₃
分子量：377.310
相关类别：化学农药原药杀虫剂杀螨剂
发布时间：2018-04-26 08:00:00
更新时间：2024-01-02 20:20:50

中文名	芬硫磷
英文名	phenkapton
中文别名	酚开普顿
英文别名	Caswell No. 335B CMP Dithiophosphate de S-{[(2,5-dichlorophényl)sulfanyl]méthyle} et de O,O-diéthyle S-{[(2,5-Dichlorophenyl)sulfanyl]methyl} O,O-diethyl phosphorodithioate Phenatol S-[[(2,5-Dichlorophenyl)thio]methyl] O,O-diethyl phosphorodithioate S-(2,5-Dichlorophenylthiomethyl) diethyl phosphorothiolothionate (2,5-dichlorophenyl)sulfanylmethylsulfanyl-diethoxy-sulfanylidene-λ<sup>5</sup>-phosphane Phenudin Phosphorodithioic acid, S-[[(2,5-dichlorophenyl)thio]methyl] O,O-diethyl ester EINECS 218-892-7 S-{[(2,5-Dichlorphenyl)sulfanyl]methyl}-O,O-diethyldithiophosphat S-2,5-dichlorophenylthiomethyl O,O-diethyl phosphorodithioate O,O-Diethyl S-(2,5-dichlorophenylthiomethyl) phosphorodithioate Phenkaptone Phenkapton Phencapton

密度	1.4±0.1 g/cm3
沸点	409.7±55.0 °C at 760 mmHg
分子式	C₁₁H₁₅Cl₂O₂PS₃
分子量	377.310
闪点	201.6±31.5 °C
精确质量	375.934875
PSA	110.96000
LogP	5.85
蒸汽压	0.0±0.9 mmHg at 25°C
折射率	1.607
储存条件	库房通风低温干燥; 与食品原料分开储运
稳定性	受热分解有毒氧化磷、氧化硫、氯化物气体
分子结构	五、分子性质数据： 1、摩尔折射率：92.80 2、摩尔体积（cm³/mol）：268.8 3、等张比容（90.2K）：736.5 4、表面张力（dyne/cm）：56.3 5、介电常数（F/m）： 6、偶极距（D）： 7、极化率（10^-24cm³）：36.79
计算化学	1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:5 4.可旋转化学键数量:8 5.互变异构体数量:无 6.拓扑分子极性表面积101 7.重原子数量:19 8.表面电荷:0 9.复杂度:300 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1

毒理学数据:

口服-大鼠 LD50: 44 毫克/公斤; 口服-小鼠 LD50: 220 毫克/公斤

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TD5775000

CHEMICAL NAME :: Phosphorodithioic acid, S-(((2,5-dichlorophenyl)thio)methyl) O,O-diethyl ester

CAS REGISTRY NUMBER :: 2275-14-1

BEILSTEIN REFERENCE NO. :: 2473741

LAST UPDATED :: 199703

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C11-H15-Cl2-O2-P-S3

MOLECULAR WEIGHT :: 377.31

WISWESSER LINE NOTATION :: GR DG BS1SPS&O2&O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 44 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Behavioral - coma Gastrointestinal - hypermotility, diarrhea

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 2,532,1960

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 652 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976 Volume(issue)/page/year: -,-,1971/1976

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 220 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ARSIM* Agricultural Research Service, USDA Information Memorandum. (Beltsville, MD 20705) Volume(issue)/page/year: 20,10,1966

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - chicken

DOSE/DURATION :: 5 gm/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Behavioral - somnolence (general depressed activity)

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 11,49,1967

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 200 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971 Volume(issue)/page/year: -,366,1971 *** REVIEWS *** TOXICOLOGY REVIEW DTTIAF Deutsche Tieraerztliche Wochenschrift. (Hanover, Fed. Rep. Ger.) V.1-77, 1893-1970. Volume(issue)/page/year: 80,485,1973

危害码 (欧洲)	T: Toxic;N: Dangerous for the environment;
风险声明 (欧洲)	23/24/25-50/53
安全声明 (欧洲)	S13;S45;S60;S61
危险品运输编码	UN 3018
包装等级	II
危险类别	6.1(a)
海关编码	2930909065

5858-18-4

2275-14-1

文献：Geigy A.G. Patent: DE957213 , 1955 ; Full Text Show Details Geigy A.G. Patent: US2891984 , 1955 ;

54583-12-9

3338-24-7

2275-14-1

文献：Geigy A.G. Patent: DE957213 , 1955 ; Full Text Show Details Geigy A.G. Patent: US2891984 , 1955 ;

上游产品 3
5858-18-4 54583-12-9 3338-24-7
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海关编码	2930909065
中文概述	2930909065 硫线磷、氯甲硫磷、杀虫磺等〔包括砜吸磷、砜拌磷、异拌磷、三硫磷、芬硫磷〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%
申报要素	品名, 成分含量, 用途
监管条件	S.进出口农药登记证明
Summary	2930909065 s-(2-(isopropylthio)ethyl) o,o-dimethyl phosphorodithioate

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