306-44-5

• 常用中文名：2-氧代丙醛肟
• 常用英文名：isonitrosoacetone
• CAS号：306-44-5
• 分子式：C₃H₅NO₂
• 分子量：87.07730
• 相关类别： 化学试剂 有机试剂 肟
• 发布时间：2018-09-25 17:56:14
• 更新时间：2024-01-10 18:29:59

名称

• 中文名: 2-氧代丙醛-1-肟
• 英文名: Propanal, 2-oxo-,1-oxime
• 中文别名: 丙酮醛醛肟; 2-氧代丙醛肟; 2-側氧-1-丙醛肟
• 英文别名: 3-hydroxyimino-aceton; 2-oxopropanal-1-oxime; PYRUVALDEHYDE 1-OXIME; PYRUVALDOXIME; monoisonitrosoacetone; pyruvic aldehyde 1-oxime; Acetone,isonitroso; pyruvic aldehyde oxime; monoizonitrozoacetone; 3-hydroxyiminoacetone; pyruvaldehydoxim; ISONITROSOACETONE; oximinoacetone

物化性质

• 密度: 1.1g/cm3
• 沸点: 193ºC at 760mmHg
• 熔点: 69°
• 分子式: C₃H₅NO₂
• 分子量: 87.07730
• 闪点: 70.6ºC
• 精确质量: 87.03200
• PSA: 49.66000
• LogP: 0.03540
• 折射率: 1.445
• 储存条件: 2-8°C

MSDS

Material Safety Data Sheet Section1. Identification of the substance Product Name: Isonitrosoacetone Synonyms: Section2. Hazards identification Harmful by inhalation, in contact with skin, and if swallowed. H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation P261:Avoid breathing dust/fume/gas/mist/vapours/spray P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing Section3. Composition/information on ingredients. Ingredient name:Isonitrosoacetone CAS number:306-44-5 Section4. First aid measures Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing contaminated clothing and shoes. If irritation persists, seek medical attention. Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate Eye contact: flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical attention. Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention. Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention. Section5. Fire fighting measures In the event of a fire involving this material, alone or in combination with other materials, use dry powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus should be worn. Section6. Accidental release measures Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national standards. Respiratory precaution:Wear approved mask/respirator Hand precaution:Wear suitable gloves/gauntlets Skin protection:Wear suitable protective clothing Eye protection:Wear suitable eye protection Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container for disposal. See section 12. Environmental precautions: Do not allow material to enter drains or water courses. Section7. Handling and storage Handling:This product should be handled only by, or under the close supervision of, those properly qualified in the handling and use of potentially hazardous chemicals, who should take into account the fire, health and chemical hazard data given on this sheet. Storage:Store in closed vessels, refrigerated. Section8. Exposure Controls / Personal protection Engineering Controls: Use only in a chemical fume hood. Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles. General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse. Section9. Physical and chemical properties Appearance:Not specified No data Boiling point: Melting point:No data Flash point:No data Density:No data Molecular formula: C3H5NO2 Molecular weight: 87.1 Section10. Stability and reactivity Conditions to avoid: Heat, flames and sparks. Materials to avoid: Oxidizing agents. Possible hazardous combustion products: Carbon monoxide, nitrogen oxides. Section11. Toxicological information No data. Section12. Ecological information No data. Section13. Disposal consideration Arrange disposal as special waste, by licensed disposal company, in consultation with local waste disposal authority, in accordance with national and regional regulations. Section14. Transportation information Non-harzardous for air and ground transportation. Section15. Regulatory information No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, or have known CAS numbers that exceed the threshold reporting levels established by SARA Title III, Section 313. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : UZ0750000 CHEMICAL NAME : Pyruvaldehyde, 1-oxime CAS REGISTRY NUMBER : 306-44-5 BEILSTEIN REFERENCE NO. : 0635802 LAST UPDATED : 199710 DATA ITEMS CITED : 3 MOLECULAR FORMULA : C3-H5-N-O2 MOLECULAR WEIGHT : 87.09 WISWESSER LINE NOTATION : QNU1V1 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Behavioral - altered sleep time (including change in righting reflex) Behavioral - somnolence (general depressed activity) Behavioral - tremor REFERENCE : BJPCAL British Journal of Pharmacology and Chemotherapy. (London, UK) V.1-33, 1946-68. For publisher information, see BJPCBM. Volume(issue)/page/year: 11,417,1956 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 148 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : EJTXAZ European Journal of Toxicology and Environmental Hygiene. (Paris, France) V.7-9, 1974-76. For publisher information, see TOERD9. Volume(issue)/page/year: 8,220,1975

安全

• 海关编码: 2928000090

合成路线

上下游产品

上游产品  9
141-97-9 78-98-8 67-64-1 29456-04-0
624-91-9 110-46-3 7601-90-3 7782-77-6
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17647-70-0 89844-84-8 78-98-8 24561-32-8
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海关

海关编码	2928000090
中文概述	2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%