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6946-90-3

6946-90-3结构式
6946-90-3结构式

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英文名 Ethylene glycol monohexanoate
英文别名 Capronsaeure-<2-hydroxy-aethylester>
2-Hydroxyethyl hexanoate
密度 0.991g/cm3
沸点 253.6ºC at 760 mmHg
分子式 C8H16O3
分子量 160.21100
闪点 102.4ºC
精确质量 160.11000
PSA 46.53000
LogP 1.10220
折射率 1.438
Name: Ethyl DL-2-Hydroxycaproate 97% Material Safety Data Sheet
Synonym:
CAS: 6946-90-3
Section 1 - Chemical Product MSDS Name:Ethyl DL-2-Hydroxycaproate 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
6946-90-3 Ethyl DL-2-Hydroxycaproate 97 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible liquid.
Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 6946-90-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: Clear
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 195.0 - 195.0 deg C @ 760.00m
Freezing/Melting Point: 0 deg C
Autoignition Temperature: Not available.
Flash Point: 81 deg C ( 177.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9670g/cm3
Molecular Formula: C8H16O3
Molecular Weight: 160.21

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 6946-90-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethyl DL-2-Hydroxycaproate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 6946-90-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 6946-90-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6946-90-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
海关编码 2915900090

~90%

6946-90-3结构式

6946-90-3

文献:Curini, Massimo; Epifano, Francesco; Marcotullio, Maria Carla; Rosati, Ornelio Synlett, 1999 , # 6 p. 777 - 779

~34%

6946-90-3结构式

6946-90-3

文献:Hashmi, A. Stephen K.; Lothschuetz, Christian; Ackermann, Martin; Doepp, Rene; Anantharaman, Sankaran; Marchetti, Benjamin; Bertagnolli, Helmut; Rominger, Frank Chemistry - A European Journal, 2010 , vol. 16, # 27 p. 8012 - 8019

~%

6946-90-3结构式

6946-90-3

文献:Chiou, Shyh-Ying; Cheng, Yu-Ru; Lu, Chun-Ping; Lin, Yan-Fu; Lin, Long-Yau; Lin, Gialih JAOCS, Journal of the American Oil Chemists' Society, 2006 , vol. 83, # 3 p. 201 - 207

~%

6946-90-3结构式

6946-90-3

文献:Drake; Melamed Patent: US2627489 , 1949 ;

~0%

6946-90-3结构式

6946-90-3

文献:Mella, Mariella; Freccero, Mauro; Albini, Angelo Journal of Organic Chemistry, 1994 , vol. 59, # 5 p. 1047 - 1052

~%

6946-90-3结构式

6946-90-3

文献:Chiou, Shyh-Ying; Cheng, Yu-Ru; Lu, Chun-Ping; Lin, Yan-Fu; Lin, Long-Yau; Lin, Gialih JAOCS, Journal of the American Oil Chemists' Society, 2006 , vol. 83, # 3 p. 201 - 207

~%

6946-90-3结构式

6946-90-3

文献:Etlis,V.S. et al. Journal of Organic Chemistry USSR (English Translation), 1970 , vol. 6, p. 460 - 462 Zhurnal Organicheskoi Khimii, 1970 , vol. 6, # 3 p. 459 - 462
海关编码 2915900090
中文概述 2915900090. 其他饱和无环一元羧酸及其酸酐(酰卤、过氧)化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%
申报要素 品名, 成分含量, 用途
监管条件 A.入境货物通关单 B.出境货物通关单
检验检疫 R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%