17250-25-8

• 常用中文名：羰基三(三苯基磷)氢化铱
• 常用英文名：Carbonylhydridotris(triphenylphosphine)iridium(I)
• CAS号：17250-25-8
• 分子式：C₅₅H₄₅IrOP₃
• 分子量：1007.08000
• 发布时间：2018-07-14 12:36:07
• 更新时间：2024-01-14 07:56:56

名称

• 中文名: 羰酰二氢三(三苯基膦)铱(I)
• 英文名: Carbonylhydridotris(triphenylphosphine)iridium(I)
• 中文别名: 羰基三(三苯基膦)氢化铱(I); 三(三苯基膦)羰基氢化铱(I); 羰基三(三苯基磷)氢化铱; 羰基氢化三(三苯基膦)铱(I); 羰基三(三苯基膦)氢化銥(I)
• 英文别名: HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I); Hydridocarbonyltris(triphenylphosphine)iridium(I); Carbonyltris(triphenylphosphine)iridium(I) hydride; Tris(triphenylphosphine)iridium(I) Carbonyl Hydride; EINECS 241-282-7; MFCD00015525

物化性质

• 沸点: 360ºC at 760mmHg
• 熔点: 170ºC (dec.)
• 分子式: C₅₅H₄₅IrOP₃
• 分子量: 1007.08000
• 闪点: 181.7ºC
• 精确质量: 1007.23000
• PSA: 40.77000
• LogP: 10.12640
• 外观性状: 淡黄色粉末
• 蒸汽压: 4.74E-05mmHg at 25°C
• 储存条件:

  常温密闭避光，通风干燥惰性气体下

• 稳定性:

  常温常压下稳定

  避免的物料：水分/潮湿 氧化物 酸 空气

• 计算化学:

  1.疏水参数计算参考值（XlogP）:2.8

  2.氢键供体数量:1

  3.氢键受体数量:3

  4.可旋转化学键数量:1

  5.互变异构体数量:无

  6.拓扑分子极性表面积47.6

  7.重原子数量:18

  8.表面电荷:0

  9.复杂度:310

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:1

  13.确定化学键立构中心数量:1

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：不确定

  2. 密度（g/mL,25/4℃）：不确定

  3. 相对蒸汽密度（g/mL,空气=1）：不确定

  4. 熔点（ºC）：170

  5. 沸点（ºC,常压）：不确定

  6. 沸点（ºC, 5.2kPa）：不确定

  7. 折射率：不确定

  8. 闪点（ºC）：不确定

  9. 比旋光度（º）：不确定

  10. 自燃点或引燃温度（ºC）：不确定

  11. 蒸气压（kPa,25ºC）：不确定

  12. 饱和蒸气压（kPa,60ºC）：不确定

  13. 燃烧热（KJ/mol）：不确定

  14. 临界温度（ºC）：不确定

  15. 临界压力（KPa）：不确定

  16. 油水（辛醇/水）分配系数的对数值：不确定

  17. 爆炸上限（%,V/V）：不确定

  18. 爆炸下限（%,V/V）：不确定

  19. 溶解性：不确定

MSDS

Section 1: Product Identification Chemical Name:Hydridocarbonyltris(triphenylphosphine)iridium (I), 99% CAS Registry Number:17250-25-8 Formula:IrH(CO)[(C6H5)3P]3 EINECS Number:none Chemical Family:metal carbonyl complexes Synonym:none Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound17250-25-8100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes Eye Contact:Causes slight or mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a tightly sealed container. Keep away from heat and direct sunlight. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:light yellow pwdr. Molecular Weight:1008.12 Melting Point:170° dec. Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:prolonged contact with air. Incompatibility:oxidizing agents Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, phosphorous pentoxide, and iridium compounds. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

安全

• 危害码 (欧洲): Xn
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): 26-36/37/39
• 危险品运输编码: UN2813
• 包装等级: III
• 危险类别: 4.3