18117-29-8
18117-29-8结构式
- 常用中文名：苯基三苯基磷氢硼化物
- 常用英文名：benzyl(triphenyl)phosphanium,boranuide
- CAS号：18117-29-8
- 分子式：C25H25BP
- 分子量：367.25100
- 发布时间：2018-08-02 08:13:57
- 更新时间：2024-01-09 19:58:53
| 中文名 | 苯基三苯基磷氢硼化物 |
|---|---|
| 英文名 | benzyl(triphenyl)phosphanium,boranuide |
| 中文别名 | 苄基三苯基磷硼氢化物 |
| 英文别名 |
MFCD00800636
BENZYLTRIPHENYLPHOSPHONIUM BOROHYDRIDE |
| 熔点 | 157-163ºC |
|---|---|
| 分子式 | C25H25BP |
| 分子量 | 367.25100 |
| 精确质量 | 367.17900 |
| PSA | 13.59000 |
| LogP | 3.99680 |
| 储存条件 | 密闭于阴凉干燥环境中 |
| 稳定性 | 遵照规定使用和储存则不会分解。 |
| 分子结构 | 1、摩尔折射率：无可用 2、 摩尔体积（cm3/mol）：无可用 3、 等张比容（90.2K）：无可用 4、 表面张力（dyne/cm）：无可用 5、 极化率：无可用 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:1 4.可旋转化学键数量:5 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:27 8.表面电荷:0 9.复杂度:347 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:2 |
| 更多 | 1. 性状：无可用 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：160-163 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 15 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Contact with water liberates extremely flammable gases. Causes burns.Moisture sensitive. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. May react with acids or moisture to form explosive hydrogen gas. Extinguishing Media: Use agent most appropriate to extinguish fire. DO NOT USE WATER! Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Do not allow contact with water. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Keep away from strong acids. Keep away from water. Water free area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 18117-29-8: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 160 - 163 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Insoluble. Specific Gravity/Density: Molecular Formula: C25H22P.BH4 Molecular Weight: 368.27 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, exposure to moist air or water. Incompatibilities with Other Materials: Water, acids. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, oxides of boron, phosphorous fumes. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 18117-29-8 unlisted. LD50/LC50: Not available. Carcinogenicity: Benzyltriphenylphosphonium borohydride - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S.* Hazard Class: 4.3 (8) UN Number: 3131 Packing Group: II IMO Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S. Hazard Class: 4.3 (8) UN Number: 3131 Packing Group: II RID/ADR Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S. Hazard Class: 4.3 UN Number: 3131 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 15 Contact with water liberates extremely flammable gases. R 34 Causes burns. Safety Phrases: S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 18117-29-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 18117-29-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 18117-29-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
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| 危害码 (欧洲) | C-F,C,F,Xn |
|---|---|
| 风险声明 (欧洲) | R34 |
| 安全声明 (欧洲) | S7/8 |
| 危险品运输编码 | UN 3131 4.3/PG 2 |