6485-39-8

• 常用中文名：葡萄糖酸锰
• 常用英文名：Manganese(2+) di(D-gluconate)
• CAS号：6485-39-8
• 分子式：C₁₂H₂₂MnO₁₄
• 分子量：445.233
• 相关类别： 食品添加剂 营养强化剂 无机盐类
• 发布时间：2018-09-23 09:51:00
• 更新时间：2024-01-02 00:45:48
• 【用途一】
  营养增补剂(锰强化剂)。
  【用途二】
  葡萄糖酸锰是一种很好的营养强化剂，我国规定可用于婴幼儿配方食品，使用量为1.32～5.26mg/kg(以锰计，下同)；在乳制品中为1.08～4.32mg/kg。
  【用途三】
  可用作营养强化剂作用。

名称

• 中文名: 葡萄糖酸锰
• 英文名: manganese(2+),2,3,4,5,6-pentahydroxyhexanoate
• 英文别名: MANGANESE GLUCONATE; D-Gluconic acid, manganese(2+) salt (2:1); D-Gluconic acid,manganese complex; EINECS 229-350-4; MFCD00867656; Manganese(2+) bis[(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanoate] (non-preferred name); Manganese(2+) di(D-gluconate)

物化性质

• 沸点: 673.6ºC at 760 mmHg
• 熔点: 131ºC
• 分子式: C₁₂H₂₂MnO₁₄
• 分子量: 445.233
• 闪点: 375.2ºC
• 精确质量: 445.039001
• PSA: 254.90000
• 外观性状: 淡粉红色粉末
• 储存条件: 库房低温,通风,干燥
• 水溶解性: soluable in hot water

MSDS

Section 1. Chemical Product and Company Identification Manganese gluconate Common Name/ Trade Name Manganese gluconate Section 4. First Aid Measures Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least Eye Contact 15 minutes. Cold water may be used. Get medical attention if irritation occurs. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Skin Contact Cold water may be used. Serious Skin ContactNot available. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get Inhalation medical attention. Not available. Serious Inhalation Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an Ingestion unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. Not available. Serious Ingestion Section 5. Fire and Explosion Data Flammability of the Product May be combustible at high temperature. Auto-Ignition Temperature Not available. Not available. Flash Points Not available. Flammable Limits These products are carbon oxides (CO, CO2). Some metallic oxides. Products of Combustion Fire Hazards in Presence of Slightly flammable to flammable in presence of heat. Non-flammable in presence of shocks. Various Substances Slightly explosive in presence of open flames and sparks. Explosion Hazards in Non-explosive in presence of shocks. Presence of Various Substances SMALL FIRE: Use DRY chemical powder. Fire Fighting Media LARGE FIRE: Use water spray, fog or foam. Do not use water jet. and Instructions As with most organic solids, fire is possible at elevated temperatures Special Remarks on Fire Hazards Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust Special Remarks on explosion hazard. Explosion Hazards Section 6. Accidental Release Measures Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading Small Spill water on the contaminated surface and dispose of according to local and regional authority requirements. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on Large Spill the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Manganese gluconate Section 7. Handling and Storage Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not Precautions ingest. Do not breathe dust. If ingested, seek medical advice immediately and show the container or the label. Keep container tightly closed. Keep container in a cool, well-ventilated area. Storage Section 8. Exposure Controls/Personal Protection Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below Engineering Controls recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal ProtectionSafety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Personal Protection in Case Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE of a Large Spill handling this product. Exposure LimitsTWA: 5 (mg(Mn)/m3) from ACGIH (TLV) [United States] Inhalation (as Mn, Dust and Compounds) TWA: 1 STEL: 3 (mg(Mn)/m3) from ACGIH (TLV) [United States] Inhalation(as Mn, Fume) Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Solid. (Powdered solid.)Not available. Physical state andO dor appearance Not available. Taste 445.23 g/mole Molecular Weight White to very light pink (Light.) Color Not available. pH (1% soln/water) Not available. Boiling Point Not available. Melting Point Not available. Critical Temperature Not available. Specific Gravity Not applicable. Vapor Pressure Not available. Vapor Density Not available. Volatility Not available. Odor Threshold Not available. Water/Oil Dist. Coeff. Not available. Ionicity (in Water) See solubility in water. Dispersion Properties Easily soluble in cold water. Solubility Insoluble in alcohol, benzene. Manganese gluconate Section 10. Stability and Reactivity Data The product is stable. Stability Not available. Instability Temperature Conditions of Instability Excess heat, incompatible materials Incompatibility with various Not available. substances Non-corrosive in presence of glass. Corrosivity No information found at this time. Special Remarks on Reactivity Not available. Special Remarks on Corrosivity Will not occur. Polymerization Section 11. Toxicological Information Inhalation. Ingestion. Routes of Entry Toxicity to AnimalsAcute oral toxicity (LD50): 5850 mg/kg [Rat]. Chronic Effects on Humans Not available. Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. Other Toxic Effects on Humans Not available. Special Remarks on Toxicity to Animals Not available. Special Remarks on Chronic Effects on Humans Acute Potential Health Effects: Special Remarks on other Skin: May cause skin irritation. Toxic Effects on Humans Eyes: Dust may cause eye irritation. Inhalation: Dust may cause respiratory tract irritation. Ingestion: Ingestion of small amounts during normal handling is not likely to be harmful. Section 12. Ecological Information Not available. Ecotoxicity Not available. BOD5 and COD Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation Manganese gluconate Section 13. Disposal Considerations Waste must be disposed of in accordance with federal, state and local environmental control Waste Disposal regulations. Section 14. Transport Information Not a DOT controlled material (United States). DO T Cl assi fi cati on Not applicable. Identification Not applicable. Special Provisions for Transport DO T (Pi ctograms) Section 15. Other Regulatory Information and Pictograms FDA: Direct Food Additives GRAS list (21CFR 184.1452). This CFR section should always be consulted for the Federal and State complete context before any conclusion is made as to the allowed regulated use. Regulations FDA: Everything Added to Food in the United States (EAFUS) list (21 CFR: 184.1452, and 582.80). These CFR sections should always be consulted for the complete context before any conclusion is made as to the allowed regulated use. California prop. 65: This product contains the following ingredients for which the State of California has found to California cause cancer which would require a warning under the statute: No products were found. Proposition 65 Warnings California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No. Other Regulations 229-350-4). Canada: Listed on Canadian Domestic Substance List (DSL). China: Not listed on National Inventory. Japan: Not listed on National Inventory (ENCS). Korea: Not listed on National Inventory (KECI). Philippines: Not listed on National Inventory (PICCS). Australia: Listed on AICS. WHMIS (Canada) Not controlled under WHMIS (Canada). Other Classifications DSCL (EEC)This product is not classified according Not applicable. to the EU regulations. Health Hazard HMIS (U.S.A.)1 National Fire Protection 1 Flammability 1 Association (U.S.A.) Fire Hazard 1 0 Reactivity Health Reactivity 0 Specific hazard Personal Protection E WHMIS (Canada) (Pictograms) Manganese gluconate DSCL (Europe) (Pictograms) TDG(Canada) (Pictograms) ADR (Europe) (Pictograms) Protective Equipment Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 海关编码: 2918160000

制备

【方法一】
由葡萄糖酸与氢氧化锰反应而得。
【方法二】
限于酶法生产的产品。葡萄糖经黑曲霉菌转化为葡萄糖酸内酯，再与硫酸锰反应制得成品。

海关

海关编码	2918160000
中文概述	2918160000. 葡糖酸及其盐和酯. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2918160000. gluconic acid, its salts and esters. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%